Fragrance compositions and uses thereof

ABSTRACT

According to various embodiments, a composition includes a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition. The fragrance component includes at least one low volatile fragrance material present in an amount greater than 30 wt %, relative to the total weight of the fragrance component. This can be defined as a bottom-heavy fragrance. The fragrance component further includes at least one moderate volatile fragrance material present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component. The fragrance component further includes at least one high volatile fragrance material present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 62/627,437 entitled “FRAGRANCE COMPOSITIONS AND USES THEREOF,” filed Feb. 7, 2018, the disclosure of which is incorporated herein in its entirety by reference.

FIELD OF THE INVENTION

Inventive subject matter herein relates to the field of perfumery. In particular, it provides compositions comprising fragrance materials in a bottom-heavy construction and at least one substantially non-odorous fragrance modulator for creating a bottom-heavy driven fragrance profile that are over-dosed with respect to the base note character without a harsh perception by a panel of experts or professional evaluators or individual experts or professional evaluators. The invention also relates to methods of making and using said compositions.

BACKGROUND OF THE DISCLOSURE

Fragrances can include fragrance components that can be classified, in part, by their volatility. Accordingly, these fragrance components may be referred to as a high-, moderate-, or low-volatility fragrance components. Different fragrances may be dominated by any one or more of these component such that the fragrance may be associated with different perceptions by a user. Furthermore, although the low-volatility fragrance may be present for a comparatively longer period of time, compositions including a relatively high amount of specific low and moderate-volatility fragrance materials (e.g., an over-dose) may be perceived as having a harsh and unpleasant perception by a panel of experts or professional evaluators or individual experts or professional evaluators. This may be especially true in cases where the low and moderate-volatility fragrance materials are, or include, natural materials.

SUMMARY OF THE DISCLOSURE

According to various embodiments, a composition includes a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition. The fragrance component includes at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component. This can be defined as a bottom-heavy fragrance. The fragrance component further includes at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component. The fragrance component further includes at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component. The composition further includes at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

According to various further embodiments, a composition includes a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition. The fragrance component includes at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component. This can be defined as a bottom-heavy fragrance. The fragrance component further includes at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component. The fragrance component further includes at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component. The composition further includes at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, and polypropylene glycol-20 methyl glucose ether, present in the amount of from about 0.1 wt % c to about 20 wt %, relative to the total weight of the composition.

According to various further embodiments, a composition includes a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition. The fragrance component includes at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component. This can be defined as a bottom-heavy fragrance. The fragrance component further includes at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component. The fragrance component further includes at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component. The fragrance component further includes at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition. According to some embodiments, the perception of the low-volatile fragrance can dominate with respect to the other fragrance materials yet the composition as a whole may not be perceived as harsh to a panel of experts or professional evaluators or individual experts or professional evaluators.

According to some embodiments, at least one of the low volatile fragrance material, the moderate volatile fragrance material, and the high volatile fragrance material is present in the fragrance component for a period of time that is longer than a corresponding fragrance component that is free of the substantially non-odorous fragrance modulator.

There, are many non-limiting reasons for using the compositions of the instant disclosure. For example, according to various embodiments, the characteristics of the composition can provide rules for objectively classifying fragrance materials according to their volatility using their vapor pressures defined at suitable temperature, instead of their characters. The objective rules operate irrespective of perfumers performing the classification. In particular, the rules classify the fragrance materials into low, moderate or high volatile fragrance materials for formulating into fragrance mixtures. Furthermore, according to some embodiments, the presence of the modulator can allow for compositions where the perception of the panel of experts or professional evaluators or individual experts or professional evaluators is driven by the moderate and low-volatility fragrance materials. According to some embodiments, the modulator allows for overdosing of at least one of the low and moderate volatility fragrance materials. By “overdosing” it is meant that either or both of the moderate volatile or low volatile materials can account for greater than 30 wt % of the fragrance component. Alternatively, the fragrance component can include multiple high or moderate volatile materials. In those instances, an individual high or low volatile material may be present in an amount greater than a corresponding material in a traditional fragrance-thus constituting an overdose. Notably, according to some embodiments, the typical harshness, as perceived by a panel of experts or professional evaluators or individual experts or professional evaluators panel of experts or professional evaluators or individual experts or professional evaluators, of large levels of low-volatility fragrance materials can be minimized at least in part by the presence of the modulator. This can be especially true, in some embodiments, in which the low-volatility fragrance material is a natural material and is over-dosed, which absent the modulator, produces a harshness that is not acceptable to a panel of experts or professional evaluators or individual experts or professional evaluators.

BRIEF DESCRIPTION OF THE FIGURES

The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present document.

FIG. 1 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 2 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 3 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 4 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 5 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 6 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 7 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 8 shows a profile of fragrance materials in a fragrance construction according to the instant disclosure.

FIG. 9 shows a profile of a perceived harshness in a fragrance construction according to the instant disclosure.

FIG. 10 shows a profile of a perceived harshness in a fragrance construction according to the instant disclosure.

DETAILED DESCRIPTION OF THE INVENTION Definitions

As used herein, articles such as “a” and “an” when used in a claim, are understood to mean one or more of what is claimed or described.

As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.

As used herein, the term “body splash” means a body care formulation that is applied to the body. Typically, the body splash is applied to the body after bathing and provides a subtle hint of scent to the body. Body splashes are commonly used by consumers who prefer less strong fragrance compositions. A body splash may comprise an ethanol-free composition according to the present invention which comprises from 0.2-8 wt %, relative to the total weight of the composition, of a fragrance component. The body splash may further comprise alkyl polyglucosides as non-ionic surfactants.

As used herein, the term “body spray” means a formulation comprising fragrance materials intended to be applied to the body to prevent or mask body odor caused by the bacterial breakdown of perspiration on the body (e.g., armpits, feet, and other areas of the body). The body spray may also provide a fragrance expression to the consumers. Typically, body spray compositions are applied as an aerosol spray in an effective amount on the skin of a consumer.

As used herein, the term “composition” includes a fine fragrance composition intended for application to a body surface, such as for example, skin or hair, e.g., to impart a pleasant odor thereto, or cover a malodour thereof. They are generally in the form of perfume concentrates, perfumes, eau de parfums, eau de toilettes, aftershaves, or colognes. The fine fragrance compositions may be an ethanol-based composition. The term “composition” may also include a cosmetic composition, which comprises a fragrance material for the purposes of delivering a pleasant smell to drive consumer acceptance of the cosmetic composition. The term “composition” may also include body splashes or body sprays. The term “composition” may also include cleaning compositions, such as fabric care composition or home care compositions, including air care compositions (e.g., air fresheners), for use on clothing or other substrates such as hard surfaces (e.g., dishes, floors, countertops). Additional non-limiting examples of “composition” may also include facial or body powder, deodorant, foundation, body/facial oil, mousse, creams (e.g., cold creams), waxes, sunscreens and blocks, bath and shower gels, lip balms, self-tanning compositions, masks and patches.

As used herein, the term “consumer” means both the user of the composition and the observer nearby or around the user.

As used herein, the term “fragrance material” and “fragrance materials” relates to a perfume raw material (“PRM”), or a mixture of perfume raw materials (“PRMs”), that are used to impart an overall pleasant odor or fragrance profile to a composition. “Fragrance materials” can encompass any suitable perfume raw materials for fragrance uses, including materials such as, for example, alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpene hydrocarbons, nitrogenous or sulfurous heterocyclic compounds and essential oils. However, naturally occurring plant and animal oils and exudates comprising complex mixtures of various chemical components are also known for use as “fragrance materials”. The individual perfume raw materials which comprise a known natural oil can be found by reference to Journals commonly used by those skilled in the art such as “Perfume and Flavourist” or “Journal of Essential Oil Research”, or listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, New Jersey, USA and more recently re-published by Allured Publishing Corporation Illinois (1994). Additionally, some perfume raw materials are supplied by the fragrance houses (Firmenich, International Flavors & Fragrances, Givaudan, Symrise) as mixtures in the form of proprietary specialty accords. Non-limiting examples of the fragrance materials useful herein include pro-fragrances such as acetal pro-fragrances, ketal pro-fragrances, ester pro-fragrances, hydrolyzable inorganic-organic pro-fragrances, and mixtures thereof. The fragrance materials may be released from the pro-fragrances in a number of ways. For example, 0 the fragrance may be released as a result of simple hydrolysis, or by a shift in an equilibrium reaction, or by a pH-change, or by enzymatic release.

As used herein, the term “fragrance profile” means the description of how the fragrance is perceived by the human nose at any moment in time. The fragrance profile may change over time. It is a result of the combination of the low, moderate and high volatile fragrance materials, if present, of a fragrance. A fragrance profile is composed of 2 characteristics: ‘intensity’ and ‘character’. The ‘intensity’ relates to the perceived strength whilst ‘character’ refers to the odor impression or quality of the perfume, e.g., fruity, floral, woody, etc.

As used herein, the terms “modulator”, and “fragrance modulator” are used interchangeably to designate an agent having the capacity to affect the fragrance profile, such as for example, by impacting the fragrance materials' evaporation rate. The modulator may mediate its effect by lowering the vapor pressure of the fragrance materials and increasing their adherence to the substrate (skin and/or hair) thus ensuring a less harsh impression of the overdosed fragrance. By incorporating the modulator, it is desired that the fragrance profile, preferably the fragrance components composition attributable to the moderate and low volatile fragrance materials, alone or individually, of the composition can be perceived by a panel of experts or professional evaluators or individual experts or professional evaluators, without the perceived harshness of overdosing (e.g., greater than about 30 wt % of the composition) of the low and moderate fragrance materials is mitigated or absent, as compared to the same perception in the absence of the modulator. Suitable examples of the modulator are provided herein below. However, as discovered by the inventors, simply adding modulators to a traditionally constructed fragrance composition (e.g., classical fragrance pyramid construction without overdose) will only decrease the overall intensity of the fragrance which is undesireable. It is necessary to overdose the key-character-giving moderate and low volatility materials, above what they would be used at in a traditional fragrance construction, in order to achieve the desired panel of experts or professional evaluators or individual experts or professional evaluators experience.

As used herein, the term “substantially non-odorous” means an agent that does not impart an odor of its own when added into a composition of the present invention. For example, a “substantially non-odorous fragrance modulator” does not impart a new odor that alters the character of the fragrance profile of the composition to which it is added. The term “substantially non-odorous” also encompasses an agent that may impart a minimal or slight odor of its own when added into a composition of the present invention. However, the odor imparted by the “substantially non-odorous fragrance modulator” is generally undetectable or tends to not substantively alter the character of the fragrance profile of the composition to which it is added initially or preferably over time. Furthermore, the term “substantially non-odorous” also includes materials that are perceivable only by a minority of people or those materials deemed “anosmic” to the majority of people. Furthermore, the term “substantially non-odorous” also includes materials that may, from particular suppliers, contain an odor due to impurities, such as when the materials contain the impurities at not more than about 5 wt %, preferably not more than 1 wt %, often even not more than 1 part per million (ppm). These impurities maybe removed by purification techniques known in the art as required to make them suitable for use in fragrance compositions of the present invention.

As used herein, the term “vapor pressure” means the partial pressure in air at a defined temperature (e.g., 25° C.) and standard atmospheric pressure (760 mmHg) for a given chemical species. It defines a chemical species' desire to be in the gas phase rather than the liquid or solid state. The higher the vapor pressure the greater the proportion of the material that will, at equilibrium, be found in a closed headspace. It is also related to the rate of evaporation of a fragrance material which is defined in an open environment where material is leaving the system. The vapor pressure is determined according to the reference program Advanced Chemistry Development (ACD/Labs) Software Version 14.02, or preferably the latest version update).

It is understood that the test methods that are disclosed in the Test Methods Section of the present application must be used to determine the respective values of the parameters of Applicants' inventions as described and claimed herein.

In all embodiments of the present invention, all percentages are by weight of the total composition, as evident by the context, unless specifically stated otherwise. All ratios are weight ratios, unless specifically stated otherwise, and all measurements are made at 25° C., unless otherwise designated.

Compositions

The inventive subject matter herein is directed towards fragrance compositions or mixtures having a bottom-heavy construction and displaying little to no perceived harshness that would be unacceptable to a panel of experts or professional evaluators or individual experts or professional evaluators. Disclosed fragrance compositions can include at least a fragrance component and modulator. The fragrance component can include a wide variety of fragrance materials. The fragrance materials can be grouped in terms of their volatility. Generally, the materials can be grouped as low volatile fragrance materials, moderate volatile fragrance materials, and high volatile fragrance materials. Each group of materials can be associated with various perceptions by a panel of experts or professional evaluators or individual experts or professional evaluators. While not so limited, a high volatile fragrance may be associated with a citrus character; a moderate voile fragrance may be associated with a spicy character; and a low volatile fragrance may be associated with a woody character. Each group of fragrance materials can include synthetic materials or natural materials. The volatility of the fragrance materials can be in reference to an individual fragrance material. Alternatively, in cases where a combination of materials produce a fragrance the volatility may be in reference to that aggregation.

With respect to the composition, the fragrance component can be present in an amount of from about 0.04 wt %/o to 30 wt %, 1 wt % to about 30 wt %, about 5 wt %/o to about 30 wt %, or less than, equal to, or greater than about 0.04 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.5, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt % relative to the composition.

Additionally with respect to the composition, the modulator can be present in an amount of from about 0.1 wt %/o to about 20 wt %, about 0.5 wt % to about 20 wt %/o, or less than, equal to, or greater than about 0.1 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, or about 20 wt % relative to the composition.

As described herein, the “fragrance materials” have been classified as low, moderate or high volatile fragrance materials according to their volatility by their vapor pressure. This method of classifying fragrance materials by their vapor pressure avoids the problem of different classifications for the same fragrance material according to the traditional approach that relies on their subjective characteristic character. In the case that the fragrance materials are a natural oil, extract or absolute, which comprises a mixture of several compounds, the vapor pressure of the complete oil should be treated a mixture of the individual perfume raw material components using the reference program cited above. The individual components and their level, in any given natural oil or extract, can be determined by direct injection of the oil into a GC-MS column for analysis as known by one skilled in the art. In the scenario that the fragrance materials are a proprietary specialty accord, so called ‘bases’, the vapor pressure, using the reference program cited above, should preferably be obtained from the supplier. However, it is understood by one skilled in the art that they can physically analyze the composition of a full fragrance oil available commercially to identity the fragrance raw materials and their levels using standard GC-MS techniques. This would be irrespective of whether they had been added to the fragrance oil as individual chemicals, as components of naturals or from proprietary bases. Although proprietary bases and naturals are included in our examples, when analyzing a commercially available fragrance via GC-MS one could simply identify the components of the base or natural oil as part of the overall fragrance mixture and their levels, without being able to identify which proprietary base or natural oil the fragrance had come from.

(i) Low Volatile Fragrance Materials

The fragrance component comprises at least one low volatile fragrance material. Individual low volatile fragrance materials or aggregate low volatile fragrance materials are those having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. According to some examples, the composition can include at least 3 low volatile fragrance materials, or at least 4 low volatile fragrance materials, or at least 5 low volatile fragrance materials, or at least 7 low volatile fragrance materials. The amount of the low fragrance material present in the fragrance component can vary depending on the specific application. For example, the low volatile fragrance material can be greater than about 30 wt % of the fragrance component, greater than about 40 wt %, greater than about 50 wt %, greater than about 60 wt %, about 31 wt % to about 60 wt %, about 40 wt % to about 50 wt %, or less than, equal to, or greater than about 30 wt %, 31, 35, 40, 45, 50, 55, 60, 65, 70, or 75 wt %.

If there are more than one low volatile fragrance materials, then the ranges provided hereinabove cover the total of all the low volatile fragrance materials. Examples of suitable low volatile fragrances materials are provided in Table 1A and 1B below.

Preferably, the low volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7, at least 8, at least 10, or at least 12 low volatile fragrance materials as disclosed in Table 1A. Natural fragrance materials or oils having an aggregrate vapour pressure less than 0.001 Torr (0.000133 kPa) at 25° C. are provided in Table 1B. Low Volatile Natural Oils.

TABLE 1A Low Volatile Fragrance Materials Vapor CAS Common Pressure (Torr No. Number IUPAC Name Name** at 25° C.)* 1. 1211-29-6 Cyclopentaneacetic acid, Methyl 0.00096500 3-oxo-2-(2Z)-2-penten-1- jasmonate yl-, methyl ester, (1R, 2R)- 2. 28219-60-5 2-Buten-1-ol, 2-methyl- Hindinol 0.00096100 4-(2,2,3-trimethyl-3- cyclopenten-1 -yl)- 3. 93-08-3 Ethanone, 142- Methyl beta- 0.00095700 naphthalenyI)- naphthyl ketone 4. 67633-95-8 3-Decanone, 1-hydroxy- Methyl 0.00095100 Lavender Ketone 5. 198404-98-7 Cyclopropanemethanol, Javanol ® 0.00090200 1-methyl-2-[(1,2,2- trimethylbicyclo[3.1.0] [hex-3-yl)methyl]- 6. 121-32-4 Benzaldehyde, 3-ethoxy- Ethyl vanillin 0.00088400 4-hydroxy- 7. 72403-67-9 3-Cyclohexene-1- Myraldylacetate 0.00087900 methanol, 4-(4-methyl-3- penten-1-yl)-, 1-acetate 8. 28940-11-6 2H-1,5-Benzodioxepin- Calone 0.00083100 3(4H)-one, 7-methyl- 9. 139504-68-0 2-Butanol, -1[[2-(1,1- Amber core 0.00080300 dimethylethyl) cyclohexyl]oxy]- 10. 502847-01-0 Spiro[5.5]undec-8-en-1- Spiro[5.5]undec- 0.00073100 one, 2,2,7,9-tetramethyl- 8-en-i-one, 2,2,7,9- tetramethyl- 11. 2570-03-8 Cyclopentaneacetic acid, trans-Hedione 0.00071000 3-oxo-2-pentyl-, methyl ester, (1R, 2R)-rel- 12. 24851-98-7 Cyclopentaneacetic acid, Methyl 0.00071000 3-oxo-2-pentyl-, dihydrojasmo methyl ester nate or alternatives ¹ 13. 101-86-0 Octanal, 2- Flexyl 0.00069700 (phenylmethylene)- cinnamic aldehyde 14. 365411-50-3 Indeno[4,5-d]-1,3-dioxin, Nebulone 0.00069200 4,4a,5,6,7,8,9,9b- octahydro-7,7,8,9,9- pentamethyl- 15. 37172-53-5 Cyclopentanecarboxylic Dihydro Iso 0.00067500 acid, 2-hexyl-3-oxo-, Jasmonate methyl ester 16. 65113-99-7 3-Cyclopentene-1- Sandalore ® 0.00062500 butanol, α,β,2,2,3- pentamethyl- 17. 68133-79-9 Cyclopentanone, 2- Apritone 0.00062000 (3,7-dimethyl-2,6- octadien-1-yl)- 18. 7212-44-4 1,6,10-Dodecatrien-3-ol, Nerolidol 0.00061600 3,7,11-trimethyl- 19. 53243-59-7 2-Pentenenitrile, 3- Citronitril 0.00061500 methyl-5-phenyl-, (2Z)- 20. 134123-93-6 Benzenepropanenitrile, Fleuranil 0.00057600 4-ethyl-α,α-dimethyl- 21. 77-53-2 1H-3a,7-Methanoazulen- Cedrol Crude 0.00056900 6-ol, octahydro-3,6,8,8- tetramethyl-, (3R, 3aS, 6R, 7R, 8aS)- 22. 68155-66-8 Ethanone, 1- Iso Gamma 0.00056500 (1,2,3,5,6,7,8,8a- Super octahydro-2,3,8,8- tetramethyl-2- naphthalenyl)- 23. 54464-57-2 Ethanone, 1- Iso-E Super ® 0.00053800 (1,2,3,4,5,6,7,8- octahydro-2,3,8,8- tetramethyl-2- naphthalenyl)- 24. 774-55-0 Ethanone, 1-(5,6,7,8- Florantone 0.00053000 tetrahydro-2-, naphthalenyl)- 25. 141-92-4 2-Octanol, Hydroxycitro 0.00052000 8,8-dimethoxy- nellal 2,6-dimethyl- Dimethyl Acetal 26 20665-85-4 Propanoic acid, 2- Vanillin 0.00051200 methyl-, 4-formyl-2- isobutyrate methoxyphenyl ester 27. 79-78-7 1,6-Heptadien-3-one, 1- Hexalon 0.00049800 (2,6,6-trimethyl-2- cyclohexen-l-yl)- 28. 6259-76-3 Benzoic acid, 2- Hexyl 0.00049100 hydroxy-, hexyl ester Salicylate 29. 93-99-2 Benzoic acid, Phenyl 0.00047900 phenyl ester Benzoate 30. 153859-23-5 Cyclohexanepropanol, Norlimbanol 0.00046900 2,2,6-trimethyl-α-propyl-, (1R, 6S)- 31. 70788-30-6 Cyclohexanepropanol, Timberol/ 0.00046900 2,2,6-trimethyl-α-propyl- Norlimbanol 32. 68555-58-8 Benzoic acid, Prenyl 0.00045700 2-hydroxy-, 3-methyl- Salicylate 2-buten-1-ylester 33. 950919-28-5 2H-1,5-Benzodioxepin- Cascal one 0.00045500 3(4H)-one, 7- (1-methylethyl)- 34. 30168-23-1 Butanal, 44octahydro- Dupical 0.00044100 4,7-methano-5H- inden-5-ylidene)- 35. 1222-05-5 Cyclopenta[g]-2- Galaxolide ® 0.00041400 benzopyran, 1,3,4,6,7,8- hexahydro-4,6,6,7,8,8- hexamethyl- 36. 4602-84-0 2,6,10-Dodecatrien-1-ol, Farnesol 0.00037000 3,7,11-trimethyl- 37. 95962-14-4 Cyclopentanone, 2-[2-(4- Nectaryl 0.00036700 methyl-3-cyclohexen-1- yl)propyl]- 38. 4674-50-4 2 (3H)-Naphthalenone, Nootkatone 0.00035800 4,4a,5,6,7,8-hexahydro- 4,4a-dimethyl-6-(1- methylethenyl)-, (4R, 4aS, 6R)- 39. 3487-99-8 2-Propenoic acid, 3- Amyl 0.00035200 phenyl-, pentyl ester Cinnamate 40. 10522-41-5 2-hydroxy-2-phenylethyl Styrolyl 0.00033900 acetate Acetate 41. 118-71-8 4H-Pyran-4-one, 3- Maltol 0.00033700 hydroxy-2-methyl- 42. 128119-70-0 1-Propanol, 2-methyl-3- Bornafix 0.00033400 [(1,7,7- trimethylbicyclo[2.2.l] hept-2-yl)oxy]- 43. 103614-86-4 1-Naphthalenol, Octalynol 0.00033200 1,2,3,4,4a,5,8,8a- octahydro-2,2,6,8- tetramethyl- 44. 7785-33-3 2-Butenoic acid, 2- Geranyl 0.00033200 methyl-, (2E)-3,7- Tiglate dimethyl-2,6-octadien- 1-yl ester, (2E)- 45. 117933-89-8 1,3-Dioxane, 2-(2,4- Karanal 0.00033100 dimethyl-3-cyclohexen- 1-yl)-5-methyl-5-(1- methylpropyl)- 46. 629-92-5 Nonadecane Nonadecane 0.00032500 47. 67801-20-1 4-Penten-2-ol, 3-methyl- Ebanol 0.00028100 5-(2,2,3-trimethyl-3- cyclopenten-1-yl)- 48. 65416-14-0 Propanoic acid, 2- Maltol 0.00028000 methyl-, 2-methyl-4-oxo- Isobutyrate 4H-pyran-3-yl ester 49. 28219-61-6 2-Buten-1-ol, 2-ethyl-4- Laevo 0.00028000 (2,2,3-tdmethyl-3- Trisandol cyclopenten-1-yl)- 50. 5986-55-0 1,6-Methanonaphthalen- Healingwood 0.00027800 1 (2H)-ol, octahydro- 4,8a,9,9-tetramethyl-, (1R, 4S, 4aS, 6R, 8aS)- 51. 195251-91-3 2H-1,5-Benzodioxepin- Transluzone 0.00026500 3 (4H)-one, 7-(1,1- dimethylethyl)- 52. 3100-36-5 8-Cyclohexadecen-1-one Cyclohexadec 0.00025300 enone 53. 65405-77-8 Benzoic acid, 2-hydroxy-, cis-3-Hexenyl 0.00024600 (3Z)-3-hexen-1-yl ester salicylate 54. 4940-11-8 4H-Pyran-4-one, Ethyl Maltol 0.00022800 2-ethyl-3-hydroxy- 55. 541-91-3 Cyclopentadecanone, Muskone 0.00017600 3-methyl- 56. 118-58-4 Benzoic acid, 2-hydroxy-, Benzyl 0.00017500 phenylmethyl ester salicylate 57. 81783-01-9 6,8-Nonadien-3-one, Labienoxime 0.00017300 2,4,4,7-tetramethyl-, oxime 58. 25485-88-5 Benzoic acid, 2-hydroxy-, Cyclohexyl 0.00017300 cyclohexyl ester Salicylate 59. 91-87-2 Benzene, [2- Amyl 0.00016300 (dimethoxymethyl)-1- Cinnamic hepten-1-yl]- Aldehyde Dimethyl Acetal 60. 104864-90-6 3-Cyclopentene-1- Firsantol 0.00016000 butanol, β,2,2,3- tetramethyl-δ-methylene- 61 224031-70-3 4-Penten-1-one, 1- Spirogalbanone 0.00015300 spiro[4.5]dec-7-en-7-yl- 62. 134-28-1 5-Azulenemethanol Guaiyl 0.00013400 1,2,3,4,5,6,7,8- Acetate octahydro-α,α,3,8- tetramethyl-, 5-acetate, (3S, 5R, 8S)- 63. 236391-76-7 Acetic acid, 2-(1- Romandolide ® 0.00012400 oxopropoxy)-, 1-(3,3- dimethylcyclohexyl) ethyl ester 64. 115-71-9 2-Penten-l-ol, 5- cis-alpha- 0.00011800 [(1R, 3R, 6S)-2,3- Santalol dimethyltricyclo [2.2.102, 6]hept-3-yl]- 2-methyl-, (2Z)- 65. 107898-54-4 4-Penten-2-ol, 3,3- Polysantol ® 0.00011700 dimethyl-5-(2,2,3- trimethyl-3- cyclopenten-1-yl)- 66. 69486-14-2 5,8-Methano-2H-1- Florex ® 0.00011000 benzopyran-2-one, 6- ethylideneoctahydro- 67. 84697-09-6 Heptanal, 2-[(4- Acalea 0.00010100 methylphenyl)methylene]- 68. 14595-54-1 4-Cyclopentadecen-1- Exaltenone 0.00009640 one, (4Z)- 69. 32388-55-9 Ethanone, 1- Vertofix ® 0.00008490 [(3R,3aR,7R,8aS)- 2,3,4,7,8,8a- hexahydro-3,6,828- tetramethyl-1H-3a,7- methanoazulen-5-yl]- 70. 131812-67-4 1,3-Dioxolane, 2,4- Okoumal ® 0.00007600 dimethyl-2-(5,6,7,8- tetrahydro-5,5,8,8- tetramethyl-2- naphthalenyl)- 71. 106-02-5 Oxacyclohexadecan- Exaltolide ® 0.00006430 2-one 72. 141773-73-1 1-Propanol, 2-[1-(3,3- Helvetolide ® 0.00005790 dimethylcyclohexyl) ethoxy]-2-methyl-, 1- propanoate 73. 63314-79-4 5-Cyclopentadecen-1- Delta 0.00005650 one, 3-methyl- Muscenone 74. 77-42-9 2-Penten-1-ol, 2-methyl- cis-beta- 0.00004810 5-[(1S, 2R, 4R)- Santalol 2-methyl-3- methylenebicyclo [2.2.1]hept-2-yl]-, (2Z)- 75. 362467-67-2 2H-1,5-Benzodioxepin- Azurone 0.00004770 3 (4H)-one, 7-(3- methylbutyl)- 76. 28371-99-5 Ethanone, 1-(2,6,10- Trimofix O 0.00004580 trimethyl-2,5,9- cyclododecatrien-1-yl)- 77. 16223-63-5 1H-3a,6- Khusimol 0.00004400 Methanoazulene-3- methanol, octahydro-7,7- dimethyl-8-methylene-, (3S, 3aR, 6R, 8aS)- 78. 10461-98-0 Benzeneacetonitrile, α- Peonile 0.00004290 cyclohexylidene- 79. 90-17-5 Benzenemethanol, α- Rosacetol 0.00004240 (trichloromethyl)-, 1-acetate 80. 50607-64-2 Benzoic acid, 2-[(2- Mevantraal 0.00004070 methylpentylidene) amino]-, methyl ester 81. 29895-73-6 5-Hydroxy-2-benzyl- Acetal CD 0.00004050 1,3-dioxane 82. 94-47-3 Benzoic acid, 2- Phenyl Ethyl 0.00003480 phenylethyl ester Benzoate 83. 3100-36-5 Cyclohexadec- Globanone ® 0.00003310 8-en-1-one 84. 37609-25-9 5-Cyclohexadecen-1-One Ambretone 0.00003310 85. 66072-32-0 Cyclohexanol, 4-(1,7,7- Iso Bornyl 0.00003010 trimethylbicyclo Cyclohexanol [2.2.1]hept-2-yl)- 86. 31906-04-4 3-Cyclohexene-1- Lyral ® 0.00002940 carboxaldehyde, 4-(4-hydroxy-4- methylpentyl)- 87. 21145-77-7 Ethanone, 1-(5,6,7,8- Musk Plus 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyl-2- naphthalenyl)- 88. 21145-77-7 Ethanone, 1-(5,6,7,8- Fixolide 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyl-2- naphthalenyl)- 89. 22442-01-9 2-Cyclopentadecen-1- Muscenone 0.00002770 one, 3-methyl- 90. 109-29-5 Oxacycloheptadecan- Silvanone Ci 0.00002600 2-one 91. 101-94-0 Benzeneacetic acid, 4- Para Cresyl 0.00002330 methylphenyl ester Phenyl Acetate 92. 102-20-5 Benzeneacetic acid, 2- Phenyl Ethyl 0.00002300 phenylethyl ester Phenyl Acetate 93. 118562-73-5 Cyclododecaneethanol, Hydroxyambran 0.00001800 β-methyl- 94. 103-41-3 2-Propenoic acid, 3- Benzyl 0.00001050 phenyl-, phenylmethyl Cinnamate ester 95. 4707-47-5 Benzoic acid, 2,4- Veramoss/ 0.00001050 dihydroxy-3,6-dimethyl-, LRG201/ methyl ester Evernyl 96. 183551-83-9 Naphtho[2,1-b]furan-6 Myrrhone 0.00000977 (7H)-one, 8,9-dihydro- 1,5,8-trimethyl-, (8R)- 97. 102-17-0 Benzeneacetic acid, Para Anisyl 0.00000813 (4-methoxyphenyl) Phenyl methyl ester Acetate 98. 120-11-6 Benzene, 2-methoxy-1- Benzyl Iso 0.00000676 (phenyltnethoxy)-4-(1- Eugenol propen-l-yl)- 99. 102-22-7 Benzeneacetic acid, (2E)- Geranyl 0.00000645 3,7-dimethyl-2,6- Phenyl acetate octadien-1-yl ester 100. 111879-80-2 Oxacyclohexadec-12- Habanolide 0.00000431 en-2-one, (12E)- 100% 101. 87-22-9 Benzoic acid, 2-hydroxy-, Phenyl Ethyl 0.00000299 2-phenylethyl ester Salicylate 102. 78-37-5 2-Propenoic acid, 3- Linalyl 0.00000174 phenyl-, 1-ethenyl-1,5- Cinnamate dimethyl-4-hexen- l-yl ester 103. 28645-51-4 Oxacycloheptadec- Ambrettolide 0.00000139 10-en-2-one 104. 123-69-3 Oxacycloheptadec- Ambrettollide 0.00000136 8-en-2-one, (8Z)- 105. 3391-83-1 1,7- Musk RI 0.00000057 Dioxacycloheptadecan- 8-one 106. 68527-79-7 7-Octen-2-ol, 8-(1H- Indolene 0.000000445 indo1-1-yl)-2,6-dimethyl- 107. 89-43-0 Methyl 2-[(7- Aurantinol 0.0000000100 hydroxy-3,7- dimethyloctylidene) amino] benzoate 108. 54982-83-1 1,4- Zenolide 0.00000000834 Dioxacyclohexadecane- 5,16-dione 109. 105-95-3 1,4- Ethylene 0.00000000313 Dioxacycloheptadecane- Brassylate 5,17-dione 110. 3681-73-0 Hexadecanoic acid, (2E)- Hexarose 0.00000000300 3,7-dimethyl-2,6- octadien-1-yl ester 111. 4159-29-9 Phenol, 4-[3- Coniferyl 0.00000000170 benzoyloxy)-1-propen- benzoate 1-yl]-2-methoxy- 112. 144761-91-1 Benzoic acid, 2-[(1- Trifone DIPG 0.00000000093 hydroxy-3- phenylbutyl)amino]-, methyl ester ¹ Non-limiting examples of alternative qualities from various suppliers can be purchased under the following tradenames: Kharismal ® Super (IFF), Kharismal ® (IFF), Hedione ® (Firmenich), Hedione ® HC (Firmenich), Paradisone (Firmenich), Cepionate (Zenon), Super cepionate (Zenon), Claigeon ® (Zenon). *Vapor Pressures are acquired as described in the Test Methods Section, **Origin: The low volatile fragrance materials may be obtained from one or more of the following companies: Firmenich (Geneva, Switzerland); Symrise AG (Holzminden, Germany), Givaudan (Argenteuil, France), IFF (Hazlet, New Jersey), Bedoukian (Danbury, Connecticut), Sigma Aldrich (St. Louis, Missouri), Millennium Specialty Chemicals (Olympia Fields, Illinois), Polarone International (Jersey City, New Jersey), and Aroma & Flavor Specialties (Danbury; Connecticut).

TABLE 1B Low Volatile Natural Oils. No. Natural oil Supplier  1. Beeswax Absolute Robertet  2. Cedarwood Sawdust SFE Firmenich  3. Cedarwood Oil Rect Firmenich  4. Cedarwood Texas Light H. Reynaud & Fils  5. Ciste Absolute IFF  6. Cocoa Colorless Oil Robertet  7. Cypriol Coeur Essence Robertet  8. Guaiacwood Oil Global Essence Inc  9. Incense Wood Natural Robertet 10. Orris CO2 Extract Mane 11. Patchouli Oil IFF 12. Tolu Baume Res Robertet 13. Vanilla Absolute Robertet 14. Vanilla CO2 Absolute Robertet 15. Vetivert Oil IFF 16. Vetyvert Acetate Robertet

Suppliers: Firmenich, Geneva, Switzerland Global Essence Inc, New Jersey, USA H. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, New Jersey, USA Mane, Le Bar-sur-Loup, France Robertet, Grasse, France

Exemplary low volatile fragrance materials selected from the group of Tables 1A or 1B Low Volatile Fragrance Materials are preferred. However, it is understood by one skilled in the art that other low volatile fragrance materials, not recited in Tables 1A or 1B, would also fall within the scope of the present invention, so long as they have a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C.

(ii) Moderate Volatile Fragrance Materials

The fragrance component includes at least one moderate volatile fragrance material or aggregate of volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. In some examples, the composition according to the present disclosure can include at least 3 moderate volatile fragrance materials, or at least 5 moderate volatile fragrance materials, or at least 7 moderate volatile fragrance materials. Compositions of the present invention can include high levels of the moderate volatile fragrance materials present in an amount of from about 30 wt % to about 70 wt %, about 35 wt % to about 60 wt %, or less than equal to, or greater than about 30 wt %, 35, 40, 45, 50, 55, 60, 65, or 70 wt % of the fragrance component. If there are more than one moderate volatile fragrance materials, then the ranges provided hereinabove cover the total of all of the moderate volatile fragrance materials. Suitable examples of moderate volatile fragrances materials are provided in Table 2A and 2B below.

Preferable examples of moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. are provided in Table 2 Moderate Volatile Fragrance Materials. Preferably, the moderate volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, or at least 7 moderate volatile fragrance materials as disclosed in Table 2A. Natural fragrance materials or oils having an aggregrate vapour pressure between 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. are provided in Table 2B. Moderate Volatile Natural Oils.

TABLE 2A Moderate Volatile Fragrance Materials Vapor Common Pressure (Torr No. CAS Number IUPAC Name Name** at 25° C.)* 1. 24168-70-5 Pyrazine, 2- Methoxyiso 0.09950000 methoxy-3-(1- butylpyrazine methylpropyl)- 2. 89-79-2 Cyclohexanol, 5- Iso-Pulegol 0.09930000 methyl-2-(1- methylethenyl)-, (1R, 2S, 5R)- 3. 112-12-9 2-Undecanone Methyl Nonyl 0.09780000 Ketone 4. 103-05-9 Benzenepropanol, Phenyl Ethyl 0.09770000 α,α-dimethyl- Dimethyl Carbinol 5. 125-12-2 Bicyclo[2.2.1]heptan- Iso Bornyl 0.09590000 2-ol, 1,7,7- Acetate trimethyl-, 2-acetate, (1R, 2R, 4R)-rel- 6. 78-70-6 1,6-Octadien-3-ol, Linalool 0.09050000 3,7-dimethyl- 7. 101-97-3 Benzeneacetic acid, Ethyl Phenyl 0.08970000 ethyl ester Acetate 8. 100-86-7 Benzeneethanoll, Dimethyl Benzyl 0.08880000 α,α-dimethyl- Carbinol 9. 188570-78-7 Cyclopropanecarboxyllic Montaverdi 0.08640000 acid, (3Z)-3- hexen-1-yl ester 10. 67634-25-7 3-Cyclohexene-1- Floralate 0.08500000 methanol, 3,5- dimethyl-, 1-acetate 11. 112-44-7 Undecanal Undecyl 0.08320000 Aldehyde 12. 32669-00-4 Ethanone, 1-(3- Tanaisone ® 0.08150000 cycloocten-l-yl)- 13. 98-53-3 Cyclohexanone, 4- Patchi 0.07780000 (1,1-dimethylethyl)- 14. 35854-86-5 6-Nonen-1-ol, (6Z)- cis-6-None-1-ol 0.07770000 15. 5331-14-6 Benzene, Butyl phenethyl 0.07760000 (2-butoxyethyl)- ether 16. 80-57-9 Bicyclo[3.1.1]hept- Verbenone 0.07730000 3-en-2-one, 4,6,6- trimethyl- 17. 22471-55-2 Cyclohexanecarboxylic Thesaron 0.07670000 acid, 2,2,6- trimethyl-, ethyl ester, (1R, 6S)-rel- 18. 60-12-8 Benzeneethanol Phenethyl alcohol 0.07410000 19. 106-26-3 2,6-Octadienal, 3,7- Neral 0.07120000 dimethyl-, (2Z)- 20. 5392-40-5 2,6-Octadienal 3,7- Citral 0.07120000 dimethyl- 21. 89-48-5 Cyclohexanol, Menthyl 0.07070000 5-methyl-2-(1- Acetate methylethyl)-, 1-acetate, (1R, 2S, 5R)-rel- 22. 119-36-8 Benzoic acid, Methyl 0.07000000 2-hydroxy-, salicylate methyl ester 23. 104-46-1 Benzene, 1- Anethol 0.06870000 methoxy-4-(1E)-1- propen-1-yl- 24. 7549-37-3 2,6-Octadiene 1,1- Citral Dimethyl 0.06780000 dimethoxy-3,7- Acetal dimethyl- 25. 25225-08-5 Cyclohexanemethanol, Aphermate 0.06780000 α,3,3-trimethyl-, 1-formate 26. 3913-81-3 2-Decenal (2E)- 2-Decene-1-al 0.06740000 27. 15373-31-6 3-Cyclopentene-1- Cantryl ® 0.06700000 acetonitrile, 2,2,3- trimethyl- 28. 6485-40-1 2-Cyclohexen-l-one, Laevo carvone 0.06560000 2-methyl-5-(1- methylethenyl)-, (5R)- 29. 16587-71-6 Cyclohexa.none, 4- Orivone 0.06490000 (1,1-dimethytpropyl)- 30. 62406-73-9 6,10-Dioxaspiro Opalal CI 0.06290000 [4.5]decane, 8,8-dimethyl-7- (1-methylethyl)- 31. 3720-16-9 2-Cyclohexen-1-one, Livescone 0.06270000 3-methyl-5-propyl- 32. 13816-33-6 Benzonitrile, 4- Cumin Nitrile 0.06230000 (1-methylethyl)- 33. 67019-89-0 2,6-Nonadienenitrile Violet -Nitrile 0.06200000 34. 53398-85-9 Butanoic acid, 2- cis-3-Hexenyl 0.06130000 methyl-, (3Z)-3- Alpha Methyl hexen-l-yl ester Butyrate 35. 208041-98-9 n/a Jasmonitrile 0.05920000 36. 16510-27-3 Benzene, 1- Toscanol 0.05870000 (cyclopropylmethyl)- 4-methoxy- 37. 111-80-8 2-Nonynoic acid, Methyl Octine 0.05680000 methyl ester Carbonate 38. 103-45-7 Acetic acid, 2- Phenyl Ethyl 0.05640000 phenyl ethyl ester Acetate 39. 2550-26-7 2-Butanone, Benzyl Acetone 0.05570000 4-phenyl- 40. 13491-79-7 Cyclohexanol, 2- Verdol 0.05430000 (1,1-dimethylethyl)- 41. 7786-44-9 2,6-Nonadien- 2,6-Nonadien- 0.05370000 1-ol 1-ol 42. 103-28-6 Propanoic acid, Benzyl Iso 0.05130000 2-methyl-, Butyrate phenylmethyl ester 43. 104-62-1 Formic acid, 2- Phenyl Ethyl 0.05050000 phenylethyl ester Formate 44. 28462-85-3 Bicyclo[2.2.1] Humus Ether 0.04870000 heptan-2-ol, 1,2,3,3- tetramethyl-, (1R, 2R, 4S)-rel- 45. 122-03-2 Benzaldehyde, 4- Cuminic 0.04820000 (1-methylethyl)- Aldehyde 46. 358331-95-0 2,5-Octadien-4-one, Pomarose 0.04810000 5,6,7-trimethyl-, (2E)- 47. 562-74-3 3-Cyclohexen-l-ol, Terpinenol-4 0.04780000 4-methyl-1- (1-methyl ethyl)- 48. 68527-77-5 3-Cyclohexene-1- Isocyclogeraniol 0.04640000 methanol, 2,4,6- trimethyl- 49. 35852-46-1 Pentanoic acid, (3Z)- Cis-3-Hexenyl 0.04580000 3-hexen-1-yl ester Valerate 50. 2756-56-1 Bicyclo[2.2.1] Iso Bornyl 0.04540000 heptan-2-ol, 1,7,7- Propionate trimethyl-, 2- propanoate, (1R, 2R, 4R)-rel- 51. 14374-92-6 Benzene, 1-methyl- Verdoracine 0.04460000 4-(1-methylethyl)-2- (1-propen-1-yl)- 52. 6784-13-0 3-Cyclohexene-1- Umonenal 0.04380000 propanal, β,4- dimethyl- 53. 8000-41-7 2-(4-methyl-1- Alpha Terpineol 0.04320000 cyclohex-3- enyl)propan-2-ol 54. 41884-28-0 1-Hexanol, 5- Tetrahydro 0.04230000 methyl-2-(1- Lavandulol methylethyl)-, (2R)- 55. 22457-23-4 3-Heptanone, 5- Stemone ® 0.04140000 methyl-, oxime 56. 104-50-7 2 (3H)-Furanone, Gamma 0.04080000 5-butyldihydro- Octal actone 57. 143-08-8 1-Nonanol Nonyl Alcohol 0.04070000 58. 3613-30-7 Octanal, 7-methoxy- Methoxycitronellal 0.04020000 3,7-dimethyl- 59. 67634-00-8 Acetic acid, -(3- Allyl Amyl 0.04000000 methylbutoxy)-, 2- Glycolate propen-1-yl ester 60. 464-45-9 Bicyclo[2.2.1] 1-Borneol 0.03980000 heptan-2-ol, 1,7,7- trimethyl-, (1S, 2R, 4S)- 61. 124-76-5 Bicyclo[2.2.1] 1.7.7-Trimethyl- 0.03980000 heptan-2-ol, 1,7,7- Bicyclo-1.2.2- trimethyl-, Heptanol-2 (1R, 2R, 4R)-rel- 62. 67874-72-0 Cyclohexanol, 2- Coniferan 0.03980000 (1,1-dimethylpropyl)-, 1-acetate 63. 80-26-2. 3-Cyclohexene-1- Terpinyl Acetate 0.03920000 methanol, α,α,4- trimethyl-, 1-acetate 64. 498-81-7 Cyclohexanemethanol, Dihydro 0.03920000 α,α,4-trimethyl- Terpineol 65. 112-45-8 10-Undecenal Undecylenic 0.03900000 aldehyde 66. 35044-57-6 2,4-Cyclohexadiene- Ethyl Safranate 0.03880000 1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester 67. 106-21-8 1-Octanol, 3,7- Dimethyl Octanol 0.03860000 dimethyl- 68. 84560-00-9 Cyclopentanol, Cyclopentol 0.03790000 2-pentyl- 69. 82461-14-1 Furan, tetrahydro- Rhubafuran ® 0.03780000 2,4-dimethyl-4- phenyl- 70. 56011-02-0 Benzene, [2-(3- Phenyl Ethyl 0.03690000 methylbutoxy)ethyl]- Isoamyl Ether 71. 103-37-7 Butanoic acid, Benzyl Butyrate 0.03660000 phenylmethyl ester 72. 6378-65-0 Hexyl hexanoate Hexyl hexanoate 0.03490000 73. 118-61-6 Benzoic acid, 2- Ethyl salicylate 0.03480000 hydroxy-, ethyl ester 74. 98-52-2 Cyclohexanol, 4- Patchon 0.03480000 (1,1-dimethylethyl)- 75. 115-99-1 1,6-Octadien-3-ol, Linalyl Formate 0.03440000 3,7-dimethyl-, 3-formate 76. 112-54-9 Dodecanal Lauric Aldehyde 0.03440000 77. 53046-97-2 3,6-Nonadien-1-ol, 3,6 Nonadien- 0.03360000 (3Z, 6Z)- 1-ol 78. 76649-25-7 3,6-Nonadien- 3,6-Nonadien- 0.03360000 1-ol 1-ol 79. 141-25-3 3,7-Dimethyloct- Rhodinol 0.03290000 6-en-ol 80. 1975-78-6 Decanenitrile Decanonitdle 0.03250000 81. 2216-51-5 Cyclohexanol, L-Menthol 0.03230000 5-methyl-2-(1- methylethyl)-, (1R, 2S, 5R)- 82. 3658-77-3 4-hydroxy-2,5- Pineapple Ketone 0.03200000 dimethylfuran-3-one 83. 103-93-5 Propanoic acid, 2- Para Cresyl 0.03120000 methyl-, 4- iso-Butyrate methylphenyl ester 84. 24717-86-0 Propanoic acid, Abierate 0.03110000 2-methyl-, (1R, 2S, 4R)-1,7,7- trimethylbicyclo[2.2.1] hept-2-yl ester, rel- 85. 67845-46-9 Acetaldehyde, 2-(4- Aldehyde XI 0.03090000 methylphenoxy)- 86. 67883-79-8 2-Butenoic acid, 2- Cis-3-Hexenyl 0.03060000 methyl-, (3Z)-3- Tiglate hexen-l-yl ester, (2E)- 87. 33885-51-7 Bicyclo[3.1.1]hept- Pino 0.03040000 2-ene-2-propanal, Acetaldehyde 6,6-dimethyl- 88. 105-85-1 6-Octen-1-ol, 3,7- Citronellyl 0.03000000 dimethyl-, 1-formate Formate 89. 70214-77-6 2-Nonanol, 6,8- Nonadyl 0.03010000 dimethyl- 90. 215231-33-7 Cyclohexanol, Rossitol 0.02990000 1-methyl-3-(2- methylpropyl)- 91. 120-72-9 1H-Indole Indole 0.02980000 92. 2463-77-6 2-Undecenal 2-Undecene-l-al 0.02970000 93. 675-09-2 2H-Pyran-2-one, Levistamel 0.02940000 4,6-dimethyl- 94. 98-55-5 3-Cyclohexene-1- Alpha-Terpineol 0.02830000 methanol, α,α,4- trimethyl- 95. 81786-73-4 3-Hepten-2-one, Koavone 0.02750000 3,4,5,6,6- pentamethyl-, (3Z)- 96. 122-97-4 Benzenepropanol Phenyl Propyl 0.02710000 Alcohol 97. 39212-23-2 2 (3H)-Furanone, 5- Methyl 0.02700000 butyldihydro- Octalactone 4-methyl- 98. 53767-93-4 7-Octen-2-ol, 2,6- Dihydro Terpinyl 0.02690000 dimethyl-, 2-acetate Acetate 99. 35044-59-8 1,3-Cyclohexadiene- Ethyl Safranate 0.02660000 1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester 100. 104-55-2 2-Propenal, 3- Cinnamic 0.02650000 phenyl- Aldehyde 101. 144-39-8 1,6-Octadien-3-ol, Linatyl 0.02630000 3,7-dimethyl-, 3- Propionate propanoate 102. 61931-80-4 1,6-Nonadien-3-ol, 3,7-Dimethyl-1,6- 0.02630000 3,7-dimethyl-, nonadien-3-yl 3-acetate acetate 103. 102-13-6 Benzeneacetic acid, Iso Butyl 0.02630000 2-methylpropyl ester Phenylacetae 104. 65443-14-3 Cyclopentanone, Veloutone 0.02610000 2,2,5-trimethyl- 5-pentyl- 105. 141-12-8 2,6-Octadien-1-ol, Neryl Acetate 0.02560000 3,7-dimethyl-, 1-acetate, (2Z)- 106. 105-87-3 2,6-Octadien-1-o1, Geranyl acetate 0.02560000 3,7-dimethyl-, 1-acetate, (2E)- 107. 68141-17-3 Undecane, 1,1- Methyl Nonyl 0.02550000 dimethoxy- Acetaldehyde 2-methyl- Dimethyl Acetal 108. 2206-94-2 Benzenemethanol, Indocolore 0.02550000 α-methylene-, 1-acetate 109. 10528-67-3 Cyclohexanepropanol, Cyclohexylmagnol 0.02550000 α-methyl- 110. 123-11-5 Benzaldehyde, Anisic Aldehyde 0.02490000 4-methoxy- 111. 57576-09-7 Cyclohexanol, Iso Pulegol 0.02480000 5-methyl-2-(1- Acetate methylethenyl)-, 1- acetate, (1R, 2S, 5R)- 112. 51566-62-2 6-Octenenitrile, Citronellyl Nitrile 0.02470000 3,7-dimethyl- 113. 60335-71-9 2H-Pyran, 3,6- Rosyrane Super 0.02470000 dihydro-4-methyl- 2-phenyl- 114. 30385-25-2 6-Octen-2-ol, Dihydromyrcenol 0.02440000 2,6-dimethyl- 115. 101-84-8 Benzene, 1,1′- Diphenyl Oxide 0.02230000 oxybis- 116. 136-60-7 Benzoic acid, Butyl Benzoate 0.02170000 butylester 117. 93939-86-7 5,8-Methano-2H-1- Rhuboflor 0.02120000 benzopyran, 6- ethylideneoctahydro- 118. 83926-73-2 Cyclohexanepropanol, Coranol 0.02100000 α,α-dimethyl- 119. 125109-85-5 Benzenepropanal, β- Florhydral 0.02070000 methyl-3-(1- methylethyl)- 120. 104-21-2 Benzenemethanol, Anisyl Acetate 0.02050000 4-methoxy-, 1-acetate 121. 1365-19-1 2-Furanmethanol, Linalool Oxide 0.02050000 5-ethenyltetrahydro- α,α,5-trimethyl- 122. 137-03-1 Cyclopentanone, Frutal one 0.02040000 2-heptyl- 123. 2563-07-7 Phenol, 2-ethoxy- Ultravanil 0.02030000 4-methyl- 124. 1128-08-1 2-Cyclopenten- Dihydrojasmone 0.02020000 1-one, 3-methyl- 2-pentyl- 125. 7493-57-4 Benzene, [2-(1- Acetaldehyde 0.01990000 propoxyethoxy)ethyl]- 126. 141-25-3 7-Octen-1-ol, Rhodinol 0.01970000 3,7-dimethyl- 127. 216970-21-7 Bicyclo[4.3.1]decane, 3-Methoxy-7,7- 0.01960000 3-methoxy-7,7- dimethyl-10- dimethyl-10- methylenebicyclo methylene- [4.3.1]decane 128. 319002-92-1 Propanoic acid, Sclareolate ® 0.01960000 2-(1,1- dimethylpropoxy)-, propyl ester, (2S)- 129. 85-91-6 Benzoic acid, 2-Dimethyl 0.01930000 (methylamino)-, anthranilate methyl 130. 13828-37-0 Cyclohexanemethanol, Mayol 0.01920000 4-(1-methylethyl)-, cis- 131. 26330-65-4 (E)-6-ethyl-3- Super Muguet 0.01850000 methyloct-6-en-1-ol 132. 7540-51-4 6-Octen-1-ol, 3,7- L-Citronellol 0.01830000 dimethyl-, (3S)- 133. 106-22-9 6-Octen-1-ol, Citronellol 0.01830000 3,7-dimethyl- 134. 543-39-5 7-Octen-2-ol, 2- Myrcenol 0.01820000 methyl-6-methylene- 135. 7775-00-0 Benzenepropanal, Cyclemax 0.01820000 4-(1-methyl ethyl)- 136. 18479-54-4 4,6-Octadien-3-ol, Muguol 0.01800000 3,7-dimethyl- 137. 29214-60-6 Octanoic acid, 2- Gelsone 0.01790000 acetyl-, ethyl ester 138. 1209-61-6 5-Oxatricyclo Tobacarol 0.01730000 [8.2.0.04, 6] dodecane, 4,9,12,12- tetramethyl- 139. 57934-97-1 2-Cyclohexene-1- Givescone 0.01710000 carboxylic acid, 2- ethyl-6,6-dimethyl-, ethyl ester 140. 14901-07-6 3-Buten-2-one, 4- Beta-Inone 0.01690000 (2,676-trimethyl-1- cyclohexen-l- yl)-, (3E)- 141. 64001-15-6 4,7-Methano-1H- Dihydro Cyclacet 0.01630000 inden-5-ol, octahydro-, 5-acetate 142. 95-41-0 2-Cyclopenten-1- Iso Jasmone T 0.01600000 one, 2-hexyl- 143. 134-20-3 Benzoic acid, 2- Methyl 0.01580000 amino-, methyl ester Anthranilate 144. 100-06-1 Ethanone, 1-(4- Para Methoxy 0.01550000 methoxyphenyl)- Acetophenone 145. 105-86-2 2,6-Octadien-1-ol, Geranyl Formate 0.01540000 3,7-dimethyl-, 1- formate, (2E)- 146. 154171-77-4 Spiro[1,3-dioxolane- Ysamber K ® 0.01470000 2,8′(5′H)-[2H- 2,4a]methanonaphth alene], hexahydro- 1′,1′,5′,5′- tetramethyl-, (2′S, 4′aS, 8′aS)- (9C1) 147. 154171-76-3 Spiro[1,3-dioxolane- Ysamber 0.01470000 2,8′(5′H)-[2H-2,4a] methanonaphthalene], 148. 127-41-3 3-Buten-2-one, 4- Alpha-Ionone 0.01440000 (2,6,6-trimethyl-2- cyclohexen-1-yl)-, (3E)- 149. 151-05-3 Benzeneethanol, Dimethyl Benzyl 0.01390000 α,α-dimethyl-, Carbinyl Acetate 1-acetate 150. 2500-83-6 4,7-Methano-1H- Flor Acetate 0.01370000 inden-5-ol, 3a,4,5,6,7,7a- hexahydro-, 5-acetate 151. 150-84-5 6-Octen-1-ol, 3,7- Citronellyl 0.01370000 dimethyl-, 1-acetate acetate 152. 30310-41-9 2H-Pyran, Pelargene 0.01350000 tetrahydro-2- methyl-4- methylene-6-phenyl- 153. 68845-00-1 Bicyclo[3.3.1]nonane, Boisiris 0.01350000 2-ethoxy-2,6,6- trimethyl-9- methylene- 154. 106-24-1 2,6-Octadien-1-ol, Geraniol 0.01330000 3,7-dimethyl-, (2E)- 155. 106-25-2 2,6-Octadien-1-ol, Nerol 0.01330000 3,7-dimethyl-, (2Z)- 156. 75975-83-6 Bicyclo[7.2.0]undec- Vetyvenal 0.01280000 4-ene, 4,11 ,11- trimethyl-8- methylene-, (1R, 4E, 9S)- 157. 19870-74-7 1H-3a,7- Cedryl methyl 0.01280000 Methanoazulene, ether octahydro-6- methoxy-3,6,8,8- tetramethyl-, (3R, 3aS, 6S, 7R, 8aS)- 158. 87-44-5 Bicyclo[7.1.0]undec- Caryophyllene 0.01280000 4-ene, 4,11,11- Extra trimethyl-8- methylene-, (1R, 4E, 9S)- 159. 54440-17-4 1H-Inden-1-one, Safraleine 0.01260000 2,3-dihydro-2,3,3- trimethyl- 160. 110-98-5 2-Propanol, Dipropylene 0.01250000 1,1′-oxybis- Glycol 161. 41890-92-0 2-Octanol, Osyrol ® 0.01250000 7-methoxy- 3,7-dimethyl- 162. 71077-31-1 4,9-Decadienal, Floral Super 0.01230000 4,8-dimethyl- 163. 65-85-0 Benzoic Acid Benzoic Acid 0.01220000 164. 61444-38-0 3-Hexenoic acid, cis-3-hexenyl-cis- 0.01220000 (3Z)-3-hexen-1-yl 3-hexenoate ester, (3Z)- 165. 116044-44-1 Bicyclo[2.2.1]hept- Herbanate 0.01210000 5-ene-2-carboxylic acid, 3-(1- 166. 104-54-1 2-Propen-1-ol, Cinnamic 0.01170000 3-phenyl- Alcohol 167. 78-35-3 Propanoic acid, 2- Linalyl 0.01170000 methyl-, 1-ethenyl- Isobutyrate 1,5-dimethyl-4- hexen-1-yl ester 168. 23495-12-7 Ethanol, 2-phenoxy-, Phenoxy Ethyl 0.01130000 1-propanoate Propionate 169. 103-26-4 2-Propenoic acid, 3- Methyl 0.01120000 phenyl-, methyl ester Cinnamate 170. 67634-14-4 Benzenepropanal, 2- Florazon 0.01110000 ethyl-α,α-dimethyl- (ortho-isomer) 171. 5454-19-3 Propanoic acid, N-Decyl 0.01100000 decyl ester Propionate 172. 93-16-3 Benzene, 1,2- Methyl Iso 0.01100000 dimethoxy-4-(1- Eugenol propen-1-yl)- 173. 81782-77-6 3-Decen-5-ol, 4-Methyl-3- 0.01070000 4-methyl- decen-5-ol 174. 67845-30-1 Bicyclo[2.2.2]oct- Maceal 0.01060000 5-ene-2- carboxaldehyde, 6-methyl-8-(1- methylethyl)- 175. 97-53-0 Phenol, 2-methoxy- Eugenol 0.01040000 4-(2-propen-1-yl)- 176. 120-57-0 1,3-Benzodioxole-5- Heliotropin 0.01040000 carboxaldehyde 177. 93-04-9 Naphthalene, Beta Naphthyl 0.01040000 2-methoxy- Methyl Ether Extra 99 178. 4826-62-4 2-Dodecenal 2 Dodecene-l-al 0.01020000 179. 20407-84-5 2-Dodecenal, (2E)- Aldehyde 0.01020000 Mandarin 180. 5462-06-6 Benzenepropanall, 4- Canthoxal 0.01020000 methoxy-α-methyl- 181. 94-60-0 1,4- Dimethyl 1,4- 0.01020000 Cyclohexanedicarbo cyclohexanedicar xylic acid, 1,4- boxylate dimethyl ester 182. 57378-68-4 2-Buten-1-one, 1- delta-Damascone 0.01020000 (2,6,6-trimethyl-3- cyclohexen-1-yl)- 183. 17283-81-7 2-Butanone, 4- Dihydro Beta 0.01020000 (2,6,6-trimethyl-1- Ionone cyclohexen-1-yl)- 184. 1885-38-7 2-Propenenitrile, 3- Cinnamalva 0.01010000 phenyl-, (2E)- 185. 103-48-0 Propanoic acid, 2- Phenyl Ethyl 0.00994000 methyl-, 2- Iso Butyrate phenylethyl ester 186. 488-10-8 2-Cyclopenten-1- Cis Jasmone 0.00982000 one, 3-methyl-2- (2Z)-2-penten-1-yl- 187. 7492-67-3 Acetaldehyde, 2- Citronellyloxyace 0.00967000 [(3,7-dimethyl-6- taldehyde octen-1-yl)oxy]- 188. 68683-20-5 1-Cyclohexene-1- Iso Bergamate 0.00965000 ethanol, 4-(1- methylethyl)-, 1-formate 189. 3025-30-7 2,4-Decadienoic Ethyl 2,4- 0.00954000 acid, ethyl ester, Decadienoate (2E, 4Z)- 190. 103-54-8 2-Propen-1-ol, 3- Cinnamyl Acetate 0.00940000 phenyl-, 1-acetate 191. 18127-01-0 Benzenepropanal, 4- Bourgeonal 0.00934000 (1,1-dimethylethyl)- 192. 3738-00-9 Naphtho[2,1-b] Ambrox ® or 0.00934000 furan, dodecahydro- Cetalox ® or 3a,6,6,9a-tetramethyl- Synambran 193. 51519-65-4 1,4- Tamisone 0.00932000 Methanonaphthalen- 5 (1H)-one, 4,4a,6,7,8,8a- hexahydro- 194. 148-05-1 Dodecanoic acid, Dodecalactone 0.00931000 12-hydroxy-, λ-lactone (6C1, 7CI); 1,12- 195. 6790-58-5 (3aR, 5aS, 9aS, 9bR)- Ambronat ® or 0.00930000 3a,6,6,9a- Ambroxan ® tetramethyl- 2,4,5,5a,7,8,9,9b- octahydro-1H- benzo[e][1]henzofuran 196. 86-26-0 1-1′-Biphenyl, Methyl Diphenyl 0.00928000 2-methoxy- Ether 197. 68738-94-3 2- Cyclomyral ® 0.00920000 Naphthalenecarboxa ldehyde, octahydro- 8,8-dimethyl 198. 2705-87-5 Cyclohexanepropanoic Allyl 0.00925000 acid, 2-propen-1- Cyclohexane yl ester Propionate 199. 7011-83-8 2 (3H)-Furanone, Lactojasmone ® 0.00885000 5-hexyldihydro- 5-methyl- 200. 61792-11-8 2,6- Lemonile ® 0.00884000 Nonadienenitrile, 3,7-dimethyl- 201. 692-86-4 10-Undecenoic acid, Ethyl 0.00882000 ethyl ester Undecylenate 202. 103-95-7 Benzenepropanal, Cymal 0.00881000 α-methyl-4- (1-methylethyl)- 203. 13019-22-2 9-Decen-1-ol Rosalva 0.00879000 204. 94201-19-1 1-Oxaspiro Methyl Laitone 0.00872000 [4.5]decan- 10% TEC 2-one, 8-methyl- 205. 104-61-0 2 (3H)-Furanone, γ-Nonalactone 0.00858000 dihydro-5-pentyl- 206. 706-14-9 2 (3H)-Furanone, γ-Decalactone 0.00852000 5-hexyldihydro- 207. 24720-09-0 2-Buten-1-one, 1- α-Damascone 0.00830000 (2,6,6-trimethyl-2- cyclohexen-1-yl)-, (2E)- 208. 39872-57-6 2-Buten-1-one, 1- Isodamascone 0.00830000 (2,4,4-trimethyl-2- cyclohexen-1-yl)-, (2E)- 209. 705-86-2 2H-Pyran-2-one, Decalactone 0.00825000 tetrahydro-6-pentyl- 210. 67634-15-5 Benzenepropanall, 4- Floralozone 0.00808000 ethyl-α,α-dimethyl- 211. 40527-42-2 1,3-Benzodioxole, 5- Heliotropin 0.00796000 (diethoxymeth3,4)- Diethyl Acetal 212. 56973-85-4 4-Penten-l-one, 1- Neobutenone α 0.00763000 (5,5-dimethyl-1- cyclohexen-1-yl)- 213. 128-51-8 Bicyclo[3.1.1]hept- Nopyl Acetate 0.00751000 2-ene-2-ethanol, 6,6- dimethyl-, 2-acetate 214. 103-36-6 2-Propenoic acid, 3- Ethyl Cinnamate 0.00729000 phenyl-, ethyl ester 215. 5182-36-5 1,3-Dioxane, 2,4,6- Floropal ® 0.00709000 trimethyl-4-phenyl- 216. 42604-12-6 Cyclododecane, Boisambrene 0.00686000 methoxymethoxy)- 217. 33885-52-8 Bicyclo[3.1.1]hept- Pinyl Iso 0.00685000 2-ene-2-propanal, Butyrate Alpha α,α,6,6-tetramethyl- 218. 92015-65-1 2 (3H)- Natactone 0.00680000 Benzofuranone, hexahydro-3, 6-dimethyl- 219. 63767-86-2 Cyclohexanemethanol, Mugetanol 0.00678000 α,-methyl-4-(1- methylethyl)- 220. 3288-99-1 Benzeneacetonitrile, Marenil 0.00665000 4-(1,1-dimethylethyl)- CI 221. 35044-68-9 2-Buten-1-one, 1- beta-Damascone 0.00655000 (2,6,6-trimethyl-1- cyclohexen-1-yl)- 222. 41724-19-0 1,4- Plicatone 0.00652000 Methanonaphthalen- 6 (2H)-one, octahydro-7-methyl 223. 75147-23-8 Bicyclo[3.2.1]octan- Buccoxime ® 0.00647000 8-one, 1,5- dimethyl-, omime 224. 25634-93-9 2-Methyl 4-5- Rosaphen ® 0.00637000 phenylpentan-1-ol 600064 225. 55066-48-3 3-Methyl-5- Phenyl 0.00637000 phenylpentanol Hexanol 226. 495-62-5 Cyclohexene, 4-(1,5- Bisabolene 0.00630000 dimethyl-4-hexen-1- ylidene)-1-methyl- 227. 2785-87-7 Phenol, 2-methoxy- Dihydro 0.00624000 4-propyl- Eugenol 228. 7-19-4 Benzoic acid, 2- Iso Butyl 0.00613000 hydroxy-, 2- Salicylate methylpropyl ester 229. 4430-31-3 2H-1-Benzopyran- Octahydro 0.00586000 2-one, octahydro- Coumarin 230. 38462-22-5 Cyclohexanone, 2- Ringonol 0.00585000 (1-mercapto-l- 50 TEC methylethyl)-5- methyl- 231. 77-83-8 2-Oxiranecarboxylic Ethyl Methyl 0.00571000 acid, 3-methyl-3- Phenyl Glycidate phenyl-, ethyl ester 232. 37677-14-8 3-Cyclohexene-1- Iso Hexenyl 0.00565000 carboxaldehyde, 4- Cyclohexenyl (4-methyl-3-penten- Carboxaldehyde 1-yl)- 233. 103-60-6 Propanoic acid, 2- Phenoxy Ethyl 0.00562000 methyl-, 2- iso-Butyrate phenoxvethyl ester 234. 18096-62-3 Indeno[1,2-d]-1,3- Indoflor ® 0.00557000 dioxin, 4,4a,5,9b- tetrahydro- 235. 63500-71-0 2H-Pyran-4-ol, Florosa Q/Florol 0.00557000 tetrahydro-4-methyl- 2-(2-methylpropyl)- 236. 65405-84-7 Cyclohexanebutanal, Cetonal ® 0.00533000 α,2,6,6-tetramethyl- 237. 171102-41-3 4,7-Methano-1H- Flor Acetate 0.00530000 inden-6-ol, 3a,4,5,6,7,7a- hexahydro-8,8- dimethyl-, 6-acetate 238. 10339-55-6 1,6-Nonadien-3-61, Ethyl linalool 0.00520000 3,7-dimethyl- 239. 23267-57-4 3-Buten-2-one, 4- Ionone Epoxide 0.00520000 (2,2,6-trimethyl-7- Beta oxabicyclo[4.1.0] hept-1-yl)- 240. 97-54-1 Phenol, 2-methoxy- Isoeugenol 0.00519000 4-(1-propen-l-yl)- 241. 67663-01-8 2 (3H)-Furanone, 5- Peacholide 0.00512000 hexyldihydro- 4-methyl- 242. 33885-52-8 Bicyclo[3.1.1]hept- Pinyl Iso 0.00512000 2-ene-2-propanal, Butyrate Alpha α,α,6,6-tetramethyl- 243. 23696-85-7 2-Buten-1-one, 1- Damascenone 0.00503000 (2,6,6-trimethyl-1,3- cyclohexadien-1-yl)- 244. 80-71-7 2-Cyclopenten-1- Maple Lactone 0.00484000 one, 2-hydroxy- 3-methyl- 245. 67662-96-8 Propanoic acid, 2,2- Pivarose Q 0.00484000 dimethyl-, 2- phenylethyl ester 246. 2437-25-4 Dodecanenitrile Clonal 0.00480000 247. 141-14-0 6-Octen-1-ol, 3,7- Citronelllyl 0.00469000 dimethyl-, Propionate 1-propanoate 248. 54992-90-4 3-Buten-2-one, 4- Myrrhone 0.00460000 (2,2,3,6- tetramethylcyclohexyl)- 249. 55066-49-4 Benzenepentanal, Mefranal 0.00455000 β-methyl- 250. 7493-74-5 Acetic acid, 2- Allyl Phenoxy 0.00454000 phenoxy-, 2-propen- Acetate 1-yl ester 251. 80-54-6 Benzenepropanal, 4- Lilial ® 0.00444000 (1,1-ditnethylethyl)- α-methyl- 252. 86803-90-9 4,7-Methano-1H- Scentenal ® 0.00439000 indene-2- carboxaldehyde, octahydro-5-methoxy- 253. 68991-97-9 2- Melafleur 0.00436000 Naphthalenecarboxal dehyde, 1,2,3,4,5,6,7,8- octahydro-8,8- dimethyl- 254. 1887'1-14-2 Pentitol, 1,5- Jasmal 0.00434000 anhydro-2,4- dideoxy-2-pentyl-, 3-acetate 255. 58567-11-6 Cyclododecane, Boisambren 0.00433000 (ethoxymethoxy)- Forte 256. 94400-98-3 Naphth[2,3-b] Molaxone 0.00425000 oxirene, 1a,2,3,4,5,6,6,7,7a- octahydro- 1a,3,3,4,6,6- hexamethyl-, (1aR, 4S, 7aS)-rel- 257. 79-69-6 3-Buten-2-one, 4- alpha-Irone 0.00419000 (2,5,6,6-tetramethyl- 2-cyclohexen-l-yl)- 258. 65442-31-1 Quinoline, 6-(1- Iso Butyl 0.00408000 methylpropyl)- Quinoline 259. 87731-18-8 Carbonic acid, 4- Violiff 0.00401000 cycloocten-l-yl methyl ester 260. 173445-65-3 1H-Indene-5- Hivernal 0.00392000 propanal, 2,3- (A-isomer) dihydro-3,3-dimethyl- 261. 23911-56-0 Ethanone, 1-(3- Nerolione 0.00383000 methyl-2- benzofuranyl)- 262. 52474-60-9 3-Cyclohexene-1- Precyclemone B 0.00381000 carboxaldehyde, 1- methyl-3-(4-methyl- 3-penten-1-yl)- 263. 139539-66-5 6-Oxabicyclo Cassifix 0.00381000 [3.2.1]octane, 5-methyl-1-(2,2,3- trimethyl-3- cyclopenten-1-yl)- 264. 80858-47-5 Benzene, [2- Phenafleur 0.00380000 (cyclohexyloxy)ethyl]- 265. 32764-98-0 2H-Pyran-2-one, Jasmolactone 0.00355000 tetrahydro-6-(3- penten-1-yl)- 266. 78417-28-4 2,4,7-Decatrienoic Ethyl 2,4,7- 0.00353000 acid, ethyl ester decatrienoate 267. 140-26-1 Butanoic acid, 3- Beta Phenyl 0.00347000 methyl-, 2- Ethyl phenylethyl ester Isovalerate 268. 105-90-8 2,6-Octadien-1-ol, Geranyl 0.003360000 3,7-dimethyl-, 1- Propionate propanoate, (2E)- 269. 41816-03-9 Spiro[1,4- Rhubofix ® 0.00332000 methanonaphthalene- 2(1H),2′-oxirane], 3,4,4a,5,8,8a- hexahydro-3',7- dimethyl- 270. 7070-15-7 Ethanol, 2- Arbanol 0.00326000 [[(1R, 2R, 4R)-1,7,7- trimethylbicyclo[2.2.1] hept-2-yl]oxy]-, rel- 271. 93-29-8 Phenol, 2-methoxy- Iso Eugenol 0.00324000 4-(1-propen-1-yl)-, Acetate 1-acetate 272. 476332-65-7 2H-Indeno[4,5-b] Amber Xtreme 0.00323000 furan, decahydro- Compound 1 2,2,6,6,7,8,8- heptamethyl- 273. 68901-15-5 Acetic acid, 2- Cyclogalbanate 0.00323000 (cyclohexyloxy)-, 2- propen-1-yl ester 274. 107-75-5 Octanal, 7-hydroxy- Hydroxycitronellal 0.00318000 3,7-dimethyl- 275. 68611-23-4 Naphtho[2,1-b] Grisalva 0.00305000 furan, 9b- ethyldodecahydro- 3a,7,7-trimethyl- 276. 313973-37-4 1,6-Heptadien-3- Pharaone 0.00298000 one, 2-cyclohexyl- 277. 137-00-8 5-Thiazoleethanol, SuIfurol 0.00297000 4-methyl- 278. 7779-30-8 1-Penten-3-one, 1- Methyl Ionone 0.00286000 (2,6,6-trimethyl-2- cyclohexen-1-yl)- 279. 127-51-5 3-Buten-2-one, Isoraldeine Pure 0.00282000 3-methyl-4-(2,6,6- trimethyl-2- cyclohexen-1-yl)- 280. 72903-27-6 1,4- Fructalate ™ 0.00274000 Cyclohexanedicarboxylic acid, 1,4- diethyl ester 281. 7388-22-9 3-Buten-2-one, 4- Ionone Gamma 0.00272000 (2,2-dimethyl-6- Methyl methylenecyclohexyl)- 3-methyl- 282. 104-67-6 2(3H)-Furanone, 5- gamma- 0.00271000 heptyldihydro- Undecalactone (racemic) 283. 1205-17-0 1,3-Benzodioxole-5- Helional 0.00270000 propanal, α-methyl- 284. 33704-61-9 4H-Inden-4-one, Cashmeran 0.00269000 1,2,3,5,6,7- hexahydro-1,1,2,3,3- pentatnethyl- 285. 36306-87-3 Cyclohexanone, 4- Kephalis 0.00269000 (1-ethoxyethenyl)- 3,3,5,5-tetramethyl- 286. 97384-48-0 Benzenepropanenitrile, Citrowane ® B 0.00265000 α-ethenyl-α-methyl- 287. 141-13-9 9-Undecenal, 2,6,10- Adoxal 0.00257000 trimethyl- 288. 2110-18-1 Pyridine, 2-(3- Corps 0.00257000 phenylpropyl)- Racine VS 289. 27606-09-3 Indeno[1,2-d]-1,3- Magnolan 0.00251000 dioxin, 4,4a,5,9b- tetrahydro-2,4- dimethyl- 290. 67634-20-2 Propanoic acid, Cyclabute 0.00244000 2-methyl-, 3a,4,5,6,7,7a- hexahydro-4,7- methano-1H-inden- 5-yl ester 291. 65405-72-3 1-Naphthalenol, Oxyoctaline 0.00236000 1,2,3,4,4a,7,8,8a- Formate octahydro-2,4a,5,8a- tetramethyl-, 1-formate 292. 122-40-7 Heptanal, 2- Amyl Cinnamic 0.00233000 (phenylmethylene)- Aldehyde 293. 103694-68-4 Benzenepropanol, Majantol ® 0.00224000 β,β,3-trimethyl- 294. 13215-88-8 2-Cyclohexen-1-one, Tabanone 0.00223000 4-(2-buten-1- Coeur ylidene)-3,5,5- trimethyl- 295. 25152-85-6 3-Bexen-l-ol, 1- Cis-3-Bexenyl 0.00203000 benzoate, (3Z)- Benzoate 296. 406488-30-0 2-Ethyl-N-methyl-N- Paradisamide 0.00200000 (m-tolyl) butanamide 297. 121-33-5 Benzaldehyde, 4- Vanillin 0.00194000 hydroxy-3-methoxy- 298. 77-54-3 1H-3a,7- Cedac 0.00192000 Methanoazulen-6-ol, octahydro-3,6,8,8- tetramethyl-, 6-acetate, (3R, 3aS, 6R, 7R, 8aS)- 299. 76842-49-4 4,7-Methano-1H- Frutene 0.00184000 inden-6-ol, 3a,4,5,6,7,7a- hexahydro-8,8- dimethyl-, 6-propanoate 300. 121-39-1 2-Oxiranecarboxylic Ethyl Phenyl 0.00184000 acid, 3-phenyl-, Citycidate ethyl ester 301. 11299-54-6 4H-4a,9- Ambrocenide ® 0.00182000 Methanoazuleno [5,6-d]-1,3-dioxole octahydro- 2,2,5,8,8,9a- hexatnethyl-, (4aR, 5R, 7aS, 9R)- 302. 285977-85-7 (2,5-Dimethyl-1,3- Lilyflore 0.00180000 dihydroinden-2- yl)methanol 303. 10094-34-5 Butanoic acid, 1,1- Diniethyl Benzyl 0.00168000 dimethyl-2- Carbinyl Butyrate phenylethyl ester 304. 40785-62-4 Cyclododeca[c] Muscogene 0.00163000 furan, 1,3,3a,4,5,6,7 8,9,10,11,13a- dodecahydro- 305. 75490-39-0 Benzenebutanenitrile, Khusinil 0.00162000 α,α,γ-trimethyl- 306. 55418-52-5 2-Butanone, 4-(1,3- Dulcinyl 0.00161000 benzodioxo1-5-yl)- 307. 3943-74-6 Benzoic acid, 4- Carnaline 0.00157000 hydroxy-3-methoxy-, methyl ester 308. 72089-08-8 3-Cyclopentene-1- Brahmanol ® 0.00154000 butanol, β,2,2,3- tetramethyl- 2- Methyl-4-(2,2,3- trimethyl-3- cyclopenten-1- yl)butanol 309. 3155-71-3 2-Butenal, 2-methyl- Boronal 0.00147000 4-(2,6,6-trimethyl-1- cyclohexen-1-yl)- 310. 2050-08-0 Benzoic acid, Amyl Salicylate 0.00144000 2-hydroxy-, pentyl ester 311. 41199-20-6 2-Naphthalenol, Ambrinol 0.00140000 decahydro-2,5, 5-trimethyl- 312. 12262-03-2 ndecanoic acid, 3- Iso Amyl 0.00140000 methylbutyl ester Undecylenate 313. 107-74-4 1,7-Octanediol, 3, Hydroxyol 0.00139000 7-dimethyl- 314. 91-64-5 2H-1-Benzopyran- Coumarin 0.00130000 2-one 315. 68901-32-6 1,3-Dioxolane, 2-[6- Glycolierral 0.00121000 methyl-8-(1- methylethyl)bicyclo [2.2.2]oct-5-en-2-yl]- 316. 68039-44-1 Propanoic acid, 2,2- Piyacyclene 0.00119000 dimethyl-, 3a,4,5,6, 7,7a-hexahydro-4,7- methano-1H-inden- 6-yl ester 317. 106-29-6 Butanoic acid, (2E)- Geranyl Butyrate 0.00116000 3,7-dimethyl-2,6- octadien-1-yl ester 318. 5471-51-2 2-Butanone, 4-(4- Raspberry ketone 0.00106000 hydroxyphenyl)- 319. 109-42-2 10-Undecenoic acid, Butyl 0.00104000 butyl ester Undecylenate 320. 2785-89-9 4-Ethyl-2- 4-Ethylguaiacol 0.02000000 methoxyphenol 321. 27538-10-9 2-ethyl-4-hydroxy- Homofuronol 0.01210000 5-methylfuran-3-one *Vapor Pressures are acquired as described in the Test Methods Section. **Origin: Same as for Table 1 hereinabove.

TABLE 2B Moderate Volatile Natural Oils. No. Natural oil Supplier  1. Bay Oil Terpeneless IFF  2. Cade Oil H. Reynaud & Fils  3. Cedar Atlas Oil Robertet  4. Cinnamon Bark Oil Robertet  5. Cinnamon Oleoresin Citrus & Allied Essences  6. Clove Bud Oil Robertet  7. Clove Leaf Oil Rectified H. Reynaud & Fils  8. Clove Stem Oil H. Reynaud & Fils  9. Davana Oil Robertet 10. Geranium Bourbon Robertet 11. Ginger Oil Fresh Madagascar IFF 12. Hay Absolute MD 50 PCT IFF 13. Juniperberry Oil T′less Robertet 14. Papyrus Oil Robertet 15. Rose Absolute Oil Robertet 16. Tonka Bean Absolute Robertet 17. Wormwood Oil Robertet

Suppliers: Citrus & Allied Essences, New York, USAH. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, New Jersey, USA Robertet, Grasse, France

Moderate volatile fragrance materials can be selected from the group of Tables 2A or 2B. However, it is understood by one skilled in the art that other moderate volatile fragrance materials, not recited in Tables 2A or 2B, would also fall within the scope of the present invention, so long as they have a vapor pressure of 0.1 to 0.001 Torr at 25° C.

(iii) High Volatile Fragrance Materials

The fragrance component includes at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. In some examples, the high volatile fragrance material can include at least 2 high volatile fragrance materials, 3 high volatile fragrance materials, or at least 5 high volatile fragrance materials, or at least 7 high volatile fragrance materials. In some examples, the high volatile fragrance material can be present in an amount ranging from about 0.1 wt % to about 30 wt % of the fragrance component, about 1 wt % to about 30 wt %, about 5 wt % to about 30 wt %, or less than, equal to, or greater than about 0.1 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.25, 27, 27.5, 28, 28.5, 29, 29.5, or about 30 wt %. If there are more than one high volatile fragrance materials, then the ranges provided hereinabove cover the total of all of the high volatile fragrance materials. Suitable examples of high volatile fragrances materials are provided in Tables 3A and 3B below.

Preferably, the high volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7 materials, or at least 9 high volatile fragrance materials as disclosed in Table 3A. Natural fragrance materials or oils having an aggregrate vapour pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. are provided in Table 3B. Moderate Volatile Natural Oils.

TABLE 3A High Volatile Fragrance Materials Vapor CAS IUPAC Common Pressure (Torr No. Number Name Name** at 25° C.)* 1. 107-31-3 Formic acid, Methyl Formate 732.00000000 methyl ester 2. 75-18-3 Methane, Dimethyl Sulfide 647.00000000 1,1′-thiobis- 1.0% In DEP 3. 141-7-6 Acetic acid Ethyl Acetate 112.00000000 ethyl ester 4. 105-37-3 Propanoic acid, Ethyl Propionate 44.50000000 ethyl ester 5. 110-19-0 Acetic acid, 2- Isobutyl Acetate 18.00000000 methylpropyl ester 6. 105-54-4 Butanoic acid, Ethyl Butyrate 13.90000000 ethyl ester 7. 14765-30-1 1-Butanol Butyl Alcohol 8.52000000 8. 7452-79-1 Butanoic acid, Ethyl-2-Methyl 7.85000000 2-methyl-, Butyrate ethyl ester 9. 123-97-2 1-Butanol, 3- Iso Amyl Acetate 5.68000000 methyl-, 1-acetate 10. 66576-71-4 Butanoic acid, Iso Propyl 2- 5.10000000 2-methyl-, 1- Methylbutyrate methylethyl ester 11. 110-43-0 2-Heptanone Methyl Amyl 4.73000000 Ketone 12. 6728-26-3 2-Hexenal, (2E)- Trans-2 Hexenal 4.62000000 13. 123-51-3 1-Butanol, 3- Isoamyl Alcohol 4.16000000 methyl- 14. 1191-16-8 2-Buten-1-ol, Prenyl acetate 3.99000000 3-methyl-, 1-acetate 15. 57366-77-5 1,3-Dioxolane-2- Methyl Dioxolan 3.88000000 methanamine, N-methyl- 16. 7785-70-8 Bicyclo[3.1.1] Alpha Pinene 3.49000000 hept-2-ene, 2,6,6- trimethyl-, (1R, 5R)- 17. 79-92-5 Bicyclo[2.2.1] Camphene 3.38000000 heptane, 2,2- dimethyl-3- methylene- 18. 94087-83-9 2-Butanethiol, 4- 4-Methoxy-2- 3.31000000 methoxy-2- Methyl-2- methyl- Butanenthiol 19. 39255-32-8 Pentanoic acid, Manzanate 2.91000000 2-methyl-, ethyl ester 20. 3387-41-5 Bicyclo[3.1.0] Sabinene 2.63000000 hexane, 4- methylene-1- (1-methylethyl)- 21. 127-91-3 Bicyclo[3.1.1] Beta Pinene 2.40000000 heptane, 6,6- dimethyl-2- methylene- 22. 105-68-0 1-Butanol, 3- Amyl Propionate 2.36000000 methyl-, 1-propanoate 23. 123-35-3 1,6-Octadiene, Myrcene 2.29000000 7-methyl-3- methylene- 24. 124-13-0 Octa,nal Octyl Aldehyde 2.07000000 25. 7392-19-0 2H-Pyran, 2- Limetol 1.90000000 ethenyltetrahydro- 2,6,6- trimethyl- 26. 111-13-7 2-Octanone Methyl Hexyl 1.72000000 Ketone 27. 123-66-0 Hexanoic acid, Ethyl Caproate 1.66000000 ethyl ester 28. 470-82-6 2-Oxabicyclo Eucalyptol 1.65000000 [2.2.2] octane, 1,3,3- trimethyl- 29. 99-87-6 Benzene, Para Cymene 1.65000000 1-methyl-4- (1-methylethyl)- 30. 104-93-8 Benzene, 1- Para Cresyl 1.65000000 methoxy-4- Methyl Ether methyl- 31. 13877-91-3 1,3,6-Octatriene, Ocimene 1.56000000 3,7-dimethyl- 32. 138-86-3 Cyclohexene, 1- dl-Limonene 1.54000000 methyl-4- (1-methylethenyl)- 33. 5989-27-5 Cyclohexene, 1- d-limonene 1.54000000 methyl-4- (1-methylethenyl)-, (4R)- 34. 106-68-3 3-Octanone Ethyl Amyl Ketone 1.50000000 35. 110-41-8 Undecanall, 2- Methyl Nonyl 1.43000000 methyl- Acetaldehyde 36. 142-92-7 Acetic acid, Hexyl acetate 1.39000000 hexyl ester 37. 110-93-0 5-Hepten-2-one, Methyl Heptenone 1.28000000 6-methyl- 38. 81925-81-7 2-Hepten-4-one, Filbertone 1% 1.25000000 5-methyl- in TEC 39. 3681-71-8 3-Hexen-1-ol, cis-3-Hexenyl 1.22000000 1-acetate, (3Z)- acetate 40. 97-64-3 .Propanoic acid, Ethyl Lactate 1.16000000 2-hydroxy-, ethyl ester 41. 586-62-9 Cyclohexene, 1- Terpineolene 1.13000000 methyl-4- (1-methylethylidene)- 42. 5115-64-1 Butanoic acid, 2- Amyl butyrate 1.09000000 methylbutyl ester 43. 106-27-4 Butanoic acid, 3- Amyl Butyrate 1.09000000 methylbutyl ester 44. 99-85-4 1,4- Gamma Terpinene 1.08000000 Cyclohexadiene, 1-methyl-4- (1-methylethyl)- 45. 18640-74-9 Thiazole, 2-(2- 2-Isobutylthiazole 1.07000000 methylpropyl)- 46. 928-96-1 3-Hexen-l-ol, cis-3-Hexenol 1.04000000 (3Z)- 47. 100-52-7 Benzaldehyde Benzaldehyde 0.97400000 48. 141-97-9 Butanoic acid, 3- Ethyl Acetoacetate 0.89000000 oxo-, ethyl ester 49. 928-95-0 2-Hexen-1-o1, Trans-2-Hexenol 0.87300000 (2E)- 50. 928-94-9 2-Hexen-1-ol, Beta Gamma 0.87300000 (2Z)- Hexenol 51. 24691-15-4 Cyclohexane, Herbavert 0.85200000 3-ethoxy-1,1,5- trimethyl-, cis- (9CI) 52. 19872-52-7 2-Penta.none, 4-Methyl-4- 0.84300000 4-mercapto- Mercaptopentan-2- 4-methyl- one 1 ppm TEC 53. 3016-19-1 2,4,6-Octatriene, Allo-Ocimene 0.81600000 2,6-dimethyl-, (4E, 6E)- 54. 69103-20-4 Oxirane, 2,2- Myroxide 0.80600000 dimethyl-343- methyl-2,4- pentadien-l-yl)- 55. 189440-77-5 4,7-Octadienoic Anapear 0.77700000 acid, methyl ester, (4E)- 56. 67633-96-9 Carbonic acid, Liffarom ™ 0.72100000 (3Z)-3-hexen-1- yl methyl ester 57. 123-68-2. Hexanoic acid, Allyl Caproate 0.67800000 2-propen-1-yl ester 58. 106-72-9 5-Heptenal, 2,6- Melonal 0.62200000 dimethyl- 59. 106-30-9 Heptanoic acid, Ethyl Oenanthate 0.60200000 ethyl ester 60. 68039-49-6 3-Cyclohexene-1- Ligustral or Triplal 0.57800000 carboxaldehyde, 4-dimethyl- 61. 101-48-4 Benzene, (2,2- Phenyl 0.55600000 dimethoxyethyl)- Acetaldehyde Dimethyl Acetal 62. 16409-43-1 2H-Pyran, Rose Oxide 0.55100000 tetrahydro-4- methyl-2-(2- methyl-1- propen-l-yl)- 63. 925-78-0 3-Nonanone Ethyl Hexyl Ketone 0.55100000 64. 100-47-0 Benzonitrile Benzyl Nitrile 0.52400000 65. 589-98-0 3-Octanol Octanol-3 0.51200000 66. 58430-94-7 1-Hexanol, Iso Nonyl Acetate 0.47000000 3,5,5-trimethyl-, 1-acetate 67. 10250-45-0 4-Heptanol, Alicate 0.45400000 2,6-dimethyl-, 4-acetate 68. 105-79-3 Hexanoic acid, Iso Butyl Caproate 0.41300000 2-methylpropyl ester 69. 2349-07-7 Propanoic acid, Hexyl isobutyrate 0.41300000 2-methyl-, hexyl ester 70. 23250-42-2 Cyclohexanecarb Cyprissate 0.40500000 oxylic acid, 1,4-dimethyl-, methyl ester, trans- 71. 122-78-1 Benzeneacetalde Phenyl 0.36800000 hyde acetaldehyde 72. 5405-41-4 Butanoic acid, Ethyl-3-Hydroxy 0.36200000 3-hydroxy-, Butyrate ethyl ester 73. 105-51-3 Propanedioic Diethyl Malonate 0.34400000 acid, 1,3-diethyl ester 74. 93-58-3 Benzoic acid, Methyl Benzoate 0.34000000 methyl ester 75. 16356-11-9 1,3,5- Undecatriene 0.33600000 Undecatriene 76. 65405-70-1 4-Decenal, (4E)- Decenal (Trans-4) 0.33100000 77. 54546-26-8 1,3-Dioxane, 2- Herboxane 0.33000000 butyl-4,4,6- trimethyl- 78. 13254-34-7 2-Heptanol,2,6- Dimethyl-2 0.33000000 dimethyl- 6-Heptan-2-ol 79. 98-86-2. Ethanone, Acetophenone 0.29900000 1-phenyl- 80. 93-53-8 Benzeneacetalde Hydratropic 0.29400000 hyde, α-methyl- aldehyde 81. 80118-06-5 Propanoic acid, Iso Pentyrate 0.28500000 2-methyl-, 1,3- dimethyl-3- buten-1-yl ester 82. 557-48-2 2,6-Nonadienal, E Z-2,6- 0.28000000 (2E, 6Z)- Nonadien-1-al 83. 24683-00-9 Pyrazine, 2- 2-Methoxy-3- 0.27300000 methoxy-3-(2- Isobutyl Pyrazine methylpropyl)- 84. 104-57-4 Formic acid, Benzyl Formate 0.27300000 phenylmethyl ester 85. 104-45-0 Benzene, 1- Dihydroanethole 0.26600000 methoxy-4- propyl- 86. 491-07-6 Cyclohexanone, Iso Menthone 0.25600000 5-methyl-2- (1-methylethyl)-, (2R,5R)-rel- 87. 89-80-5 Cyclohexanone, Menthone Racemic 0.25600000 5-methyl-2- (1-methylethyl)-, (2R, 5S)-rel- 88. 2463-53-8 2-Nonenal 2 Nonen-1-al 0.25600000 89. 55739-89-4 Cyclohexanone, Thuyacetone 0.25000000 2-ethyl-4, 4-dimethyl- 90. 150-78-7 Benzene, 1,4- Hydroquinone 0.25000000 dimethoxy- Dimethyl Ether 91. 64988-06-3 Benzene, 1- Rosacene 0.24600000 (ethoxymethyl)- 2-methoxy- 92. 76-27-7 Bicyclo[2,2.1] Camphor gum 0.22500000 heptan-2-one, 1,7,7-trimethyl- 93. 67674-46-8 2-Hexene, 6, Methyl 0.21400000 6-dimethoxy-2.5, Pamplemousse 5-trimethyl- 94. 112-31-2 Decanal Decyl Aldehyde 0.20700000 95. 16251-77-7 Benzenepropanal, Trifernal 0.20600000 β-methyl- 96 93-92-5 Benzenemethanol, Methylphenylcarbinol 0.20300000 α-methyl-, Acetate 1-acetate 97. 143-13-5 Acetic acid, Nonyl Acetate 0.19700000 nonyl ester 98. 122-00-9 Ethanone, Para Methyl 0.18700000 1-(4-methylphenyl)- Acetophenone 99. 24237-00-1 2H-Pyran, Gyrane 0.18600000 6-butyl-3, 6-dihydro-2, 4-dimethyl- 100. 41519-23-7 Propanoic acid, Hexenyl 0.18200000 2-methyl-, (3Z)- Isobutyrate 3-hexen-1-yl ester 101. 93-89-0 Benzoic acid, Ethyl Benzoate 0.18000000 ethyl ester 102. 20780-48-7 3-Octanol, 3,7- Tetrahydro Linalyl 0.18000000 dimethyl-, Acetate 3-acetate 103. 101-41-7 Methyl 2- Methylphenyl 0.17600000 phenylacetate acetate 104. 40853-55-2 1-Hexanol, 5- Tetrahydro 0.17300000 methyl-2- Lavandulyl Acetate (1-methylethyl)-, 1-acetate 105. 933-48-2. Cyclohexanol, Trimethylcyclohexanol 0.17300000 3,3,5-trimethyl-, (1R, 5R)-rel- 106. 35158-25-9 2-Hexenal, 5- Lactone of Cis 0.17200000 methyl-2- Jasmone (1-methylethyl)- 107. 18479-58-8 7-Octen-2-ol, Dihydromyrcenol 0.16600000 2,6-dimethyl- 108. 140-11-4 Acetic acid, Benzyl acetate 0.16400000 phenylmethyl ester 109. 14765-30-1 Cyclohexanone; 2-sec-Butyl Cyclo 0.16300000 2-(1-methylpropyl)- Hexanone 110. 20125-84-2 3-Octen- Octenol 0.16000000 1-ol, (3Z)- 111. 142-19-8 Heptanoic acid, Allyl Heptoate 0.16000000 2-propen-1-yl ester 112. 100-51-6 Benzenemethanol Benzyl Alcohol 0.15800000 113. 10032-15-2 Butanoic acid, Hexyl-2-Methyl 0.15800000 2-methyl-, Butyrate hexyl ester 114. 695-06-7 2(3H)-Furanone, Gamma 0.15200000 5-ethyldihydro- Hexalactone 115. 21722-83-8 Cyclohexaneetha Cyclohexyl Ethyl 0.15200000 nol, 1-acetate Acetate 116. 111-79-5 2-Nonenoic acid, Methyl-2- 0.14600000 methyl ester Nonenoate 117. 16491-36-4 Butanoic acid, Cis 3 Hexenyl 0.13500000 (3Z)-3-hexen- Butyrate 1-yl ester 118. 111-12-6 2-Octynoic acid, Methyl Heptine 0.12500000 methyl ester Carbonate 119. 59323-76-1 1,3-Oxathiane, Oxane 0.12300000 2-methyl-4- propyl-, (2R, 4S)- rel- 120. 62439-41-2 Heptanal, 6- Methoxy Melonal 0.11900000 methoxy-2,6- dimethyl- 121. 13851-11-1 Bicyclo+2,2.1+ Fenchyl Acetate 0.11700000 heptan-2-ol, 1,3,3- trime hyl-, 2-acetate 122. 115-95-7 1,6-Octadien-3- Linalyl acetate 0.11600000 ol, 3,7-dimethyl-, 3-acetate 123. 18479-57-7 2-Octanol, Tetra-Hydro 0.11500000 2,6-dimethyl- Myrcenol 124. 78-69-3 3,7- Tetra-Hydro 0.11500000 dimethyloctan- Linalool 3-ol 125. 111-87-5 1-Octanol Octyl Alcohol 0.11400000 126. 71159-90-5 3-Cyclohexene- Grapefruit 0.10500000 1-methanethiol, mercaptan α,α,4-trimethyl- 127. 80-25-1 Cyclohexanernet Menthanyl Acetate 0.10300000 hanol, α,α,4-trimethyl-, 1-acetate 128. 88-41-5 Cyclohexanol, 2- Verdox ™ 0.10300000 (1,1- dimethylethyl)-, 1-acetate 129. 32210-23-4 Cyclohexanol, 4- Vertenex 0.10300000 (1,1-dimethylethyl)-, 1-acetate 130. 112-44-7 Undecanal n-Undecanal 0.10200000 131. 124-19-6 Nonanal Nonanal Aldehyde 0.53200000 C-9 132. 929253-05-4 6-methoxy-2,6- 6-methoxy-2,6- 0.04020000 dimethyloctanal dimethyl octanal 133. 68039-47-4 2-propan-2- Phenethyl Isopropyl 0.24900000 yloxyethylbenzene Ether 134. 6413-10-1 ethyl 2-(2- Apple Ketal 0.21900000 methyl-1,3- dioxolan-2-yl) acetate 135. 106-23-0 3,7-dimethyloct- citronellal 0.21500000 6-enal 136. 14667-55-1 Trimethyl Trimethyl 1.72400000 Pyrazine-2,3,5 Pyrazine-2,3,5 *Vapor Pressures are acquired as described in the Test Methods Section. **Origin: Same as for Table 1 hereinabove.

TABLE 3B High Volatile Fragrance Materials No. Natural oil Supplier  1. Angelica Seeds Oil Robertet  2. Basil Oil Grand Vert IFF  3. Bergamot Oil Reggio Early New Crop Capua  4. Black Pepper Oil Robertet  5. Blackcurrant Buds Absolute Robertet  6. Cardamom Guatamala Extract CO2 IFF  7. Cardamom Oil Guatemala IFF  8. Cedarleaf Oil Kerry  9. citronella oil H. Reynaud & Fils 10. Claiy Sage Oil French IFF 11. Coffee Extract CO2 Firmenich 12. Cucumber Extract Firmenich 13. Cumin Oil Robertet 14. Cypress Oil DT 15. Elemi Coeur Oil Robertet 16. Ginger oil India IFF 17. Grapefruit Zest Citrus & Allied Essences 18. It. Bergamot Oil Capua 19. Labdanum Cistus Absolute Biolandes 20. Lavandin Grosso Oil H. Reynaud & Fils 21. Lemon Oil Winter Capua 22. Green Mandarin Oil Simone Gatto 23. Nutmeg Oil Robertet 24. Oil Orange Sinensal Citrus & Allied Essences 25. Olibanum Oil Pyrogenous Firmenich 76. Pepper Black CO2 Oil Firmenich 27. Petitgrain Mandarinier Oil Misitano & Stracuzzi 28. Pink Pepper CO2 OIL Firmenich 29. Rum CO2 Oil Firmenich 30. Sichuan Pepper CO2 oil Firmenich 31. Styrax Resoid IFF 32. Tangerine Oil Robertet 33. Thym Oil IFF 34. Violet Leaves Absolute Robertet

Suppliers Biolandes, Le Sen, France Capua, Campo Calabro, Italy Citrus & Allied Essences, New York, USA Firmenich, Geneva, Switzerland Global Essence Inc, New Jersey, USA H. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, New Jersey, USA

Kerry, Co. Kerry, Ireland

Mane, Le Bar-sur-Loup, France Misitano & Stracuzzi, Messina, Italy Robertet, Grasse, France Simone Gatto, San Pierre Niceto, Italy

Exemplary high volatile fragrance materials selected from the group of Tables 3A or 3B are preferred. However, it is understood by one skilled in the art that other high volatile fragrance materials, not recited in Tables 3A or 3B, would also fall within the scope of the present invention, so long as they have a vapor pressure of greater than 0.1 Torr (0.0133 kPa) at 25° C.

(iv) Fragrance Modulators

The composition further comprises at least one substantially non-odorous fragrance modulator as described herein below. Suitable examples of the substantially non-odorous fragrance modulators are provided in Table 4 below.

The substantially non-odorous fragrance modulator can be present in an amount of from about 0.1 wt % to about 20 wt % relative to the total weight of the composition of the composition, about 0.5 wt % to about 18 wt %, about 2.5 wt % to about 15 wt %, or less than, equal to, or greater than about 0.1 wt %, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20 wt %. If there are more than one substantially non-odorous fragrance modulators, then the ranges provided hereinabove cover the total of all of the substantially non-odorous fragrance modulators.

The substantially non-odorous fragrance modulator can be a liquid at temperatures lower than 100° C., such as at ambient temperature. The substantially non-odorous fragrance modulators may be fully miscible with the fragrance materials to form a single phase liquid. However, if the fragrance materials are not entirely miscible, or are immiscible, then co-solvents (e.g., dipropylene glycol (DPG), triethyl citrate, or others well known to those skilled in the art) can be added to aid in the solubility of the fragrance materials.

According to various examples, the effect of the substantially non-odorous fragrance modulator on the fragrance profile, particularly the characters of the fragrance profile which is attributable to the low and high volatile fragrance materials, can be improved. By “improved” it is meant that the fragrance profile of the composition, particular the components contributed by at least one of the low and high volatile fragrance materials, can be perceived by the panel of experts or professional evaluators or individual experts or professional evaluators at later time points such as, for example, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 6 hours, 7 hours, 8 hours, 10 hours, and possibly all the way up to 24 hrs after application as compared to controls, e.g., lacking any of the disclosed non-odorous fragrance modulators such as Glucam.

By “improved” it can mean that the perception by the panel of experts or professional evaluators or individual experts or professional evaluators, of a harshness of the composition being loaded with greater than 30 wt % of the low-fragrance material is reduced or eliminated.

Suitable examples of non-odorous modulators can include methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof. Further examples can include from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl/capryl glucoside, undecyl glucoside, and mixtures thereof. In some examples, the composition can be substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof, although the composition can optionally include these.

Further examples of non-odorous modulators include:

a compound of formula (I):

wherein:

-   -   R¹ is hydrogen, alkyl, alkenyl or alkynyl;     -   R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl,         (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)0]_(w)R⁹, wherein w is from 1 to 10,         preferably 2 to 9;     -   R³ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]_(y)R⁹, wherein y is         from 1 to 10 or 2 to 9;     -   R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;     -   R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶0 R⁹,         —R⁶0 [R⁶R⁷(R⁸)0]zR⁹,     -   wherein z is from 1 to 10, preferably 2 to 9;     -   each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene,         (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and     -   each R⁸ and R⁹ is independently selected from hydrogen or alkyl,         a compound of formula (II):

wherein:

-   -   R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or         (C₂-C₂₀)alkynyl;     -   each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;     -   each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene,         or (C₂-C₂₀)alkynylene; and     -   R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)         alkynyl; wherein tis 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and         -   is a saturated or unsaturated carbon-carbon bond:

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   R^(1b) is hydrogen or methyl; and         R^(2b) is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)—(OR^(1c))_(n)  (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from         6 to 9, and m is     -   an integer from 1 to 4:     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂O—CH₂CH₂—O—R^(1e))_(e)  (VII).

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is     -   an integer from 1 to 5;     -   z is an integer from 1 to 5; and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8,     -   and d is an integer from 1 to 3;     -   e is an integer from 2 to 4;     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4;     -   h is an integer from 2 to 5;     -   and R^(1f) is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)NCOOR^(3i)  (X).

wherein:

-   -   R^(1g) is selected from the group consisting of: (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)  (XII).

wherein:

-   -   R^(1i) is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and         Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H  (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons;

N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures;

Tricyclodecane Amide derivatives selected from the group consisting of:

-   -   the compounds of formula (XIV):

-   -   wherein:         -   X is selected from:

t is 1 to 8;

-   -   Y is hydrogen, or a halogen; and     -   each R^(1j) is independently selected from a hydrogen, or C₁-C₄         alkyl; the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈     -   alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that         both R^(2e) groups are not hydrogen; and         mixtures of the compounds of formulae (XII) and (XIII); and         mixtures thereof.

Tables 4(a) and 4(b) provide lists of suitable non-odorous fragrance modulators.

TABLE 4(a) Substantially Non-Odorous Fragrance Modulators CAS No. Group Chemical Name Number Supplier 1. (a) PPG-10 Methyl 61849-72-7 Lubrizol Glucose Ether 2. PPG-20 Methyl 61849-72-7 Glucose Ether ¹ 3. Ethoxylated Methyl 68239-42-9 Glucose Ether ² 4. Caprylyl/Capryl 68515-73-1 BASF Glucoside ³ 5. Undecyl Glucoside ^(3a) — SEPPIC (France) 6. (b) Isocetyl Alcohol ⁴ 36653-82-4 Ashland Speciality Ingredients 7. (c) PPG-3 Myristyl Ether ⁵ — Evonik 8. Neopentyl Glycol 28510-23-8 Lubrizol Diethylhexanoate ⁶ 9. (d) Sucrose Laurate 25339-99-5 Alfa Chemicals Ltd. (UK) 10. Sucrose dilaurate 25915-57-5 Alfa Chemicals Ltd. (UK) 11. Sucrose Myristate 27216-47-3 Mitsubishi Chemicals 12. Sucrose Palmitate 26446-38-8 Alfa 13. Sucrose Stearate 25168-73-4 Chemicals Ltd. (UK) 14. Sucrose Distearate 27195-16-0 Mitsubishi Chemicals (JP) 15. Sucrose Tristearate 27923063-3 Mitsubishi Chemicals (JP) 16. (e) (E)-1-(2,2,6- — Takasago trimethylcyclohexyl) (Japan) oct-l-en-3-one ⁸ 17. (f) 2-(1-menthoxy) — Takasago ethhane-l-ol ⁹ 18. 1-(1-menthoxy) — (Japan) propane-2-ol ⁹ 19. 3-(1-menthoxy) — propane-l-ol ⁹ 20. 3-(1-menthoxy) — propane-1, 2-diol ⁹ 21. 2-methyl-3-(1-menthoxy) — propane-1,2-diol ⁹ 22. 4-(1-menthoxy) — butane-1-ol ⁹ 23. (g) 1,1,4,4-tetramethyl- — Givaudan 6-acetyl- (Switzerland) 7-formyl-1,2,3,4- tetrahydronaphthalene ¹⁰ 24. 1,1,4,4-pentamethyl- — 6-acetyl 7-formyl-1,2,3,4- tetrahydronaphthalene ¹⁰ 25. (h) Hyaluronic 9004-61-9 Sigma acid disaccharide Aldrich sodium salt 11 26. Sodium Hyaluronate ¹¹ 9067-32-7 (UK) 27. (i) Mono-o-(linalyl)- — Kanebo glucopyranose ¹² (Japan) 28. Di-o-(lialyl)- — glucopyranose ¹² 29. Tri-o-(linalyl)- — glucopyranose ¹² 30. Tetra-o-(linalyl)- — glucopyranose ¹² 31. Penta-o-(linayl)- — glucopyranose ¹² 32. Mono-o-(cis-3-hexenyl)- — glactopyranose ¹² 33. Di-o-(cis-3-hexenyl)- — glactopyranose ¹² 34. Tri-o-(cis-3-hexenyl)- — glactopyranose ¹² 35. Tetra-o-(cis-3-hexenyl)- — glactopyranose ¹² 36. Penta-o-(cis-3-hexenyl)- — glactopyranose ¹² 37. (j) Bis-O- — (3,6-dioxadecanyl)- glucopyranose ¹³ 38. Tris-O- — (3,6-dioadecanyl)- glucopyranose ¹³ 39. Tetrakis-O- — (3,6-dioxadecanyl)- glucopyranose ¹³ 40. Petrakis-O- — (3,6-dioxadecanyl)- glucopyranose ¹³ 41. Bis-O- — (3,6-dioxaoctanyl)- galactopyranose ¹³ 42. Tris-O- — (3,6-dioxaoctanyl)- galactopyranose ¹³ 43. Tetrakis-O- — (3,6-dioxaoctanyl)- galactopyranose ¹³ 44. Pentakis-O- — (3,6-dioxaoctanyl)- glucopyranose ¹³ 45. Bis-O- — (3,6-dioxaheptanyl)- xylopyranose ¹³ 46. Tris-O- — (3,6-dioxaheptanyl)- xylopyranose ¹³ 47. Tetrakis-O- — (3,6-dioxaheptanyl)- xylopyranose ¹³ 48. Bis-O- — (3,6-dioxadodecanyl)- glucopyranose ¹³ 49. Tris-O- — (3,6-dioxadodecanyl)- glucopyranose ¹³ 50. Tetrakis-O- — (3,6-dioxadodecanyl)- glucopyranose ¹³ 51. Pentakis-O- — (3,6-dioxadodecanyl)- glucopyranose ¹³ 52. (k) Hydroquinone 497-76-7 Shiseido beta-D-glycoside ¹⁴ 53. (l) Propylene Glycol 1569-01-3 Sigma Propyl Ether Aldrich 54. Dicetyl Ether 4113-12-6 (UK) 55. Poly-glycerin-4 Ethers 25618-55-7 Solvay Chemicals 56. Isoceteth-5  69364-63-2 Nihon 57. Isoceteth-7  69364-63-2 Emulsion 58. Isoceteth-10 69364-63-2 Company 59. Isoceteth-12 69364-63-2 Ltd. 60. Isoceteth-15 69364-63-2 61. Isoceteth-20 69364-63-2 62. Isoceteth-25 69364-63-2 63. Isoceteth-30 69364-63-2 64. Disodium 68929-04-4 Rhodia Lauroamphodipropionate 65. Hexaethylene glycol 3055-96-7 Sigma monododecyl ether ^(14b) Aldrich (UK) 66. (m) Neopentyl Glycol 27841-07-2 Symrise Diisononanoate ¹⁵ (Germany) 67. Cetearyl Ethylhexnoate ¹⁶ 90411-68-0 68. (n) 2-ethylhexyloxypropanediol ¹⁷ 70455-33-9 Takasago (JP) 69. (o) Panthenol Ethyl Ether ¹⁸ 667-83-4 DSM Nutritional Products, Inc. (USA) 70. DL-Panthenol 16485-10-2 Roche Inc. (USA) 71. (p) Diisobutyl Adipate ¹⁹ 141-04-8 Sigma 72. Diisoamyl Adipate ¹⁹ 6624-70-0 Aldrich (UK) 73. PPG-11 Stearyl Ether ^(19a) 25231-21-4 Kao (JP) 74. (r) N-hexadecyl n-nonanoate ^(19b) 72934-15-7 Symnse (e.g., cetyl nonanoate) (Germany) 75. Noctadecyl n-nonanoate ^(19b) 107647-13-2 (e.g., stearyl nonanoate) 76. (s) methanone, (morphonyl) — Unilever tricyclo[3.3.1.1^(3,7)] (UK) dec-1-yl- ²⁰ 77. methanone, (piperidinyl) — tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 78. methanone, (pyrrolidinyl) — tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 79. methanone, (azetidinyl) — tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 80. methanone, — (hexahydroazepinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 81. methanone, 4-cyano- — piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 82. methanone, (4-amido- — piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 83. methanone, — (Tricyclo[3.3.1.1^(3,7)] decanyl)-N- tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 84. methanone, — (decahydroisoquinolinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 85. methanone, — (decahydroisoquinolinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 86. methanone, — (decahydroquinolinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 87. methanone, — (3,3-dimethyl-1- piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 88. methanone, — (2-methyl-1- piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 89. methanone, — (4-methyl-1- piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 90. methanone, — (3-methyl-1 piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 91. methanone, — (3,5-ditnethyl-l- piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 92. methanone, — (4-methyl-4-ethy- piperidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 93. methanone, — (3,3-diethyl-l- pyrrolidinyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 94. methanone, — (N,N-diisopropyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 95. methanone, (3,3- — dimethylbutylaminyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 96. methanone, (2,2- — dimethylpropylaminyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 97. methanone, — 1,1-dimethyl-3,3- dimethylbutylaminyl) tricyclo[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 98. methanone, — (1,3-dimethyl- butylaminyl) tricycle[3.3.1.1^(3,7)] dec-1-yl- ²⁰ 99. (t) Bis-methoxy 936645-35-1 Polymer PEG-13 PEG- Expert 438/PPG-110 S.A. SMD1 Copolymer ²¹ (Pessac, France 100. (u) propyl {4-[2- 61791-12-6 Sigma (diethylamino)- Aldrich 2-oxoethoxy]-3- methoxyphenyl} (US) acetate ²² 101. (v) 3-((2-ethylhexy)oxy) 70445-33-9 — propane-1,2-diol ²³ 102. 3-((2-propylheptyl) — — oxy)propane- 1,2-diol ²³ 103. 1-amino-3- 99509-00-9 — ((2-ethylhexyl)oxy) propan-2-ol ²³ ¹ available as GLUCAM ™ P-20. ² available as Glucam ™ E-20. ³ available as Plantacare ® 810 UP. ^(3a) available as Simulsol ® SL 11W. ⁴ available as CERAPHYL ® ICA. ⁵ available as Tegosoft  ®APM. ⁶ available as Schercemol ™ NGDO. ⁷ disclosed in U.S. Pat. No. 6,737,396B2 (Firmenich), column 1, lines 43-47. ⁸ diclosed as compound 1’i in U.S. Pat. No. 6,440,400131 (Takasago Int. Corp.), col. 5. ^(8a) diclosed in U.S. Pat. No. 4,313,855 (Dragoco Gerberding, & Co. GmbH), col. 1, lines 12-13. ⁹ disclosed in U.S. Pat. No. 7,538,081B2 (Takasago Int. Corp.), column 7, lines 50-53. ¹⁰ disclosed in U.S. Pat. No. 6,147,049 (Givaudan Roure), col. 5, line 24, to col. 6, line 17. ¹¹ disclosed in PCT Publication No. WO85/04803 (Diagnostic), pg. 2, line 1 to pg. 4, line 2. ¹² disclosed in JP Patent No. 61-083114 (Kanebo). ¹³ disclosed in JP Patent No. 61-063612 (Kanebo). ¹⁴ disclosed in JP Patent No. 6-2-084010 (Shiseido). ^(14b) available as: Laureth-6. ¹⁵ disclosed in U.S. Patent Publication No. 2011/0104089A1 (Symrise), para. [0001]. ¹⁶ available as PCL-Liquid ® 100. ¹⁷ disclosed in U.S. Pat. No. 7,196,052 (Takasago Int, Corp.), col, 4, lines 34-35. ¹⁸ disclosed in EP Patent Publication No. 616800A2 (Givaudan), pg. 2, lines 12-25. ¹⁹ disclosed in U.S. Pat. No. 4,110,626 (Shiseido), column 3, lines 54-56. ^(19a) disclosed in PCT Publication No. WO2014/155019 (LVMH). ^(19b) disclosed in U.S. Pat. No. 9,050,261 (Symrise). ²⁰ disclosed as compounds C1-C22 in WO2014/139952 (Unilever). ²¹ available as Expert Gel ® EG56. ²² available as Kolliphor ® EL. ²³ disclosed in U.S. Pat. No. 9,050,261 (Symrise).

Further examples of non-odorous fragrance modulator is selected from the group of materials disclosed in Table 4(b).

TABLE 4(b) Substantially Non-Odorous Fragrance Modulators Chemical or No. INCI Name Trade Name CAS Number Supplier 1. C12-14 Sec-Pareth-3 Tergitol ® 15-S-7 68131-40-8 Sigma Aldrich (UK) 2. Poly(ethylene glycol- PPG-7-Buteth-10 9038-95-3 Sigma Aldrich ran-propylene glycol) (UK) monobutyl ether 3. PPG-4-Ceteth-1.0 Nikkol PBC-33 37311-01-6 Chemical Navi 4. Deceth-4 Ethal DA-4 5703-94-6 Ethox Chemicals, Inc. 5. PPG-5-Ceteth-20 AEC PPG-5- 9087-53-0 A & E Connock Ceteth-20 (Perfumery & Cosmetics) Ltd. 6. C14-15 Pareth-7 Neodol 45-7 68951-67-7 Shell alcohol Chemical ethoxylate Company 7. Linear alcohol (C12- Bio-soft N25-7 68131-39-5 Stephan 15) Pareth-3ethoxylate; Company POE-7 (USA) 8. Linear alcohol (C12- Bio-soft 66455-14-9 13) Pareth- N23-6.5 3ethoxylated, POE-6.5) 9. Polyethylene glycol Cremophor ® 68439-49-6 Sigma Aldrich 1100 A 25 (UK) mon (hexadecyl/ octadecyl) ether 10. Linear alcohol (C9-11) Bio-soft 68439-46-3 Stephan ethoxylated POE -8 N91-8 Company Pareth-3 (USA) 11. Coceth-10 or Genapol ® 61791-13-7 Sigma Aldrich Polyoxyethylene (10) C-100 (UK) dodecyl ether 12. Alcohols, C12-14, Rhodasurf ® 68439-50-9 Solvay ethoxylated LA 30 Solutions Italia S.p.A. 13. Poly(ethylene glycol) Poly(ethylene 9004-74-4 Sigma Aldrich methyl ether glycol) methyl (UK) ether 14. C10-16 Pareth-1 Neodol ® 68002-97-1 Shell PC 110 Chemical Company 15. PPG-11 Stearyl Ether Arlamol ™ 25231-21-4 Croda (UK) PS11E 16. Steareth-100 Brij ® 9005-00-9 Sigma Aldrich S100 (UK) 17. Polyethylene glycol Brij ® 9004-95-9 Sigma Aldrich hexadecyl ether C-58 (UK) 18. Pluronic ® Pluronic ® 9003-11-6 Sigma Aldrich F-127 F-127 (UK) 19. Linear Alcohol (C11) Bio-soft 34398-01-1 Stepan Ethoxylate, POE-5 N1-5 Canada Inc. 20. Laureth-10 Intrasol FA 6540-99-4 Evonik Dec. 18, 2010 Industries AG 21. Decaethylene glycol Polyoxyethylene 9002-92-0 Sigma Aldrich mono-dodecyl (10) lauryl (UK) ether ether 22. Ethylene glycol 2- 109-86-4 Sigma Aldrich monomethyl ether Methoxyethanol (UK) 23. Myreth-4 Homulgator 27306-79-2 Grau Aromatics 920 G GmbH & Company KG 24. Oleth-16 Pegnol O-16A 25190-05-0 Toho Chemical Alkoxylated Industry Alcohols Co., Ltd. 25. Isosteareth-5 Emalex 1805 52292-17-8 Nihon Emulsion Company, Ltd. 26. PPG-10 Cetyl Ether Arlamol ™ 9035-85-2 Croda (UK) PC10 27. Polyoxy(ethylene Poly(ethylene 24938-91-8 Sigma-Aldrich glycol) (18) tridecyl glycol) (18) (UK) ether tridecyl ether 28. Poly(oxy-1,2- ALFONIC ® 26183-52-8 Sasol Chemicals ethanediyl), a- 10-8 Ethoxylate (USA) LLC decyl-w-hydroxy- 29. Laurel-1 Mackam ™ 4536-30-5 Rhodia (DE) 2LSF 30. PEG-5 Hydrogenated Ethox 61791-26-2 Ethox Chemicals, Tallow Amine HTAM-5 Inc. 31. PEG-15 Oleamine Nikkol 26635-93-8 Nikko Chemicals TAMNO-15 Co., Ltd. 32. Polyoxyethylene (20) Brij ® 9004-98-2 Sigma Aldrich oleyl ether O20-SS (UK) 33. Cetoleth-10 Brij ® CO10 8065-81-4 Croda, Inc. 34. Talloweth-7 Emulmin 70 61791-28-4 Sanyo Chemical Industries Ltd. 35. Isobutoxypropanol Isobutoxypropanol 34150-35-1 MolPort Alcohols 36. Isobutoxypropanol Isobutoxypropanol 23436-19-3 AKos Consulting Alcohols & Solutions 37. Diethylene Glycol Twincide EDG 111-46-6 Roda 38. Methoxyethanol Hisolve MC 109-86-4 Toho Chemical Industry Co., Ltd. 39. Ethoxyethanol 2- 110-80-5 Sigma-Aldrich Alcohols Ethoxyethanol (UK) 40. Methoxyisopropanol Dowanol ™ PM 107-98-2 The Dow Alcohols Chemical Cornpany 41. Methoxyethanol Hisolve MC 32718-54-0 Toho Chemical Industry Co., Ltd. 42. Methylal Dimethoxymethane 109-87-5 Sigma-Aldrich Ethers (UK) 43. 3-Methoxyhutanol Methoxybutanol 2517-43-3 Hans Schwarzkopf GmbH/ Co. KG 44. Butoxyethanol Butyl OXITOL 111-76-2 Shell Chemical Company 45. Propylene Glycol Dowanol ™ 5131-66- The Dow n-Butyl Ether PnB 8/29387-86-8 Chemical Company 46. Propylene Glycol Butyl Propylene 15821-83-7 Sigma Aldrich Ether Glycol Butyl (UK) Ether 47. 2-(2- Diethylene 112-34-5 Sigma Aldrich butoxyethoxy)ethanol glycol butyl (UK) ether 48. Deceth-4 Phosphate Crodafos ™ 52019-36-0 Croda, Inc. D4A 49. 2- Ethylene glycol 2136-71-2 Sigma-Aldrich (Hexadecyloxy)ethanol monohexadecyl (UK) ether 50. Poly(propylene glycol) Poly(propylene 9003-13-8 Sigma-Aldrich monobutyl ether glycol) (UK) monobutyl ether 51. Propylene Glycol Dowanol ™ 30136-13-1 The Dow Propyl Ether PnP Chemical Cornpany 52. Propylene Glycol n- Dowanol ™ 29387-86- The Dow Butyl Ether PnB 8/5131-66-8 Chemical Company 53. Dipropylene glycol Di(prorylene 34590-94-8 Sigma Aldrich monomethyl ether glycol) methyl (UK) ether, mixture of isomers 54. Dipropylene Glycol Proglyde ™ 111109-77-4 The Dow Dimethyl Ether DMM Chemical Company 55. PPG-2 Methyl Ether Dowanol ™ 13429-07-7 The Dow DPM Chemical Company 56. Methoxydiglycol OriStar 111-77-3 Orient Stars LLC Ethers DEGME 57. Diethylene glycol ethyl Di(ethylene 111-90-0 Sigma Aldrich ether glycol) ethyl (UK) ether 58. Dimethoxydiglycol Dimethyldiglycol 111-96-6 H & V Chemicals Ethers 59. PPG-3 Methyl Ether Dowanol ™ 37286-64-9 The Dow TPM Chemical Company 60. Methyl Motpholine 224286 7529-22-8 Sigma-Aldrich Oxide ALDRICH (UK) Amine Oxides 4- Methylmorpholine N-oxide 61. Oleth-3 Brij ® O3 5274-66-8 Croda Europe, Ltd. 62. Tri(propylene glycol) Dowanol ™ 55934-93-5 Sigma-Aldrich n-butyl ether TPnB (UK) 63. Tripropylene Glycol Tripropylene 24800-44-0 Sigma-Aldrich Glycol (UK) 64. PPG-3 Methyl Ether Dowanol ™ 25498-49-1 The Dow Alkoxylated Alcohols TPM Chemical Company 65. Triethylene glycol Triglycol 112-27-6 Sigma Aldrich (UK) 66. PEG-3 Methyl Ether Hymol ™ 112-35-6 Toho Chemical Industry Co., Ltd. 67. Laureth-3 AEC Laureth-3 3055-94-5 A & E Connock (Perfumery & Cosmetics) Ltd. 68. Ethylhex glycerin AG-G-75008 70445-33-9 Angene Chemical 69. Tetra(ethylene glycol) Tetraethylene 112-60-7 Sigma Aldrich glycol (UK) 70. Steareth-3 Isoxal 5 4439-32-1 Vevy Europe SpA 71. Ceteth-3 Emalex 103 4484-59-7 Nihon Emulsion Company, Ltd. 72. Myreth-3 Isoxal 5 26826-30-2 Vevy Europe SpA 73. Trideceth-3 Alfonic ® TDA- — Sasol North 3 Ethoxylate America, Inc. 74. Ceteth-2 Brij ® C2 5274-61-3 Croda Europe, Ltd. 75. Oleth-2 Brij ® O2 5274-65-7 Croda, Inc. 76. Steareth-2 Brij ® S2 16057-43-5 Croda, Inc. 77. Cetoleth-10 Brij ® CO10 8065-81-4 Croda, Inc. 78. Trimethyl Pentanol Trimethyl 68959-25-1 Angene Chemical Hydroxyethyl Ether Pentanol Alcohols Hydroxyethyl Ether 79. Steareth-10 Allyl Ether Salcare ® SC80 109292-17-3 BASF 80. TEA-Lauryl Ether material ID- 1733-93-3 Angene Chemical AG-J-99109 81. Polyglyceryl-2 Oleyl Chimexane NB 71032-90-1 Chimex Ether 82. Batyl Alcohol B402 544-62-7 Sigma-Aldrich ALDRICH (UK) 83. Octaethylene Glycol 15879 5117-19-1 Sigma-Aldrich AIDRICH (UK) 84. Triglycerol Cithrol ™ 66082-42-6 Croda (UK) diisostearate 85. Diglycerin Diglycerin 59113-36-9 Sakamoto 801 Yakuhin Kogyo Co., Ltd. 86. Polyglycerin Polyglycetin 25618-55-7 Sakamoto #310 #310 Yakuhin Kogyo Co., Ltd. 87. Distearyl Ether Cosmacol ® 6297-03-6 Sasol Germany SE GmbH 88. Caprylyl Glyceryl Caprylyl 10438-94-5 AKos Consulting Ether Glyceryl Ether & Solutions 89. Chimyl Alcohol Chimyl Alcohol 506-03-6 Nikko Chemicals Co., Ltd. Dipentaerythrityl 90. Hexacaprylate/ Liponate ® 68130-24-5 Lipo Chemicals, Hexacaprate DPC-6 Inc. 91. Morpholine 394467 110-91-8 Sigma-Aldrich ALDRICH (UK) 92. Dimethyl Oxazolidine OXABAN ™ -A 51200-87-4 The Dow Chemical Company 93. Ethyl Hydroxymethyl 4- 68140-98-7 Angene Chemical Oleyl Oxazoline Oxazolemethanol 94. Methyl Hydroxymethyl Adeka Nol 14408-42-5 Adeka Oleyl Oxazoline GE-RF Corporation 95. Pramoxine HCl OriStar 637-58-1 Orient Stars LLC PMHCL 96. Allantoin Ascorbate Allantoin 57448-83-6 ABI Chem Ascorbate 97. Stearamidopropyl Mackalene ™ 55852-14-7 Rhodia Inc. Morpholine Lactate 326 98. Dioxolane Elcotal DX 646-06-0 Lambiotte & CM, S.A. 99. Glycerol Formal Glycerol 5464-28-8 Sigma Aldrich Formal (UK) 100. Stearamidopropyl Mackine 321 55852-13-6 Rhodia Inc. Morpholine 101. 2,4,6- Poly(melamine- 68002-20-0 Sigma-Aldrich Tris[bis co-formaldehyde) (UK) (methoxymethyl) methylated amino]- 1,3,5-triazine 102. Poloxamine 1307 Pluracare ® 1307 11111-34-5 BASF 103. Nonoxyno1-8 Igepal ® CO-610 27177-05-5 Rhodia Inc. 104. Nonoxynol-10 Igepal ® CO-710 27177-08-8 Rhodia Inc, 105. Octoxynol-10 Nikkol OP-10 2315-66-4 Nikko Chemicals Co., Ltd. 106. Nonoxynol-9 Igepal ® CO-630 68987-90-6 Rhodia Inc, 107. Nonoxynol-9 Nonoxynol-9 94349-40-3 Angene Chemical Iodine iodine 108. Octylphenoxy Igepal ® 68987-90-6 Rhodia Inc. poly(ethyleneoxy) CA-630 ethanol, branched 109. Sodium Octoxynol-2 Triton ™ 55837-16-6 The Dow Ethane Sulfonate X-200 Chemical Company 110. Benzylhemiformal Preventol D2 14548-60-8 Lanxess Corporation 111. Nonoxynol-2 Igepal ® CO-210 27176-93-8 Rhodia Inc, 112. Octoxynol-3 Igepal ® CA-420 2315-62-0 The Dow Chemical Company 113. Nonoxynol-3 Marlophen NP 3 27176-95-0 Sasol Germany GmbH 114. Alkoxylated Alcohols Alkasurf NP-4 7311-27-5 Rhodia Inc. 115. Nonoxynol-3 Triethylene 51437-95-7 Santa Cruz Glycol Mono Biotechnology (p-nonylphenyl) Ether 116. Nonoxynol-7 Lowenol 2689 27177-03-3 Jos. H. Lowenstein & Sons, Inc. 117. Nonoxynol-6 Igepal ® CO-530 27177-01-1 Rhodia Inc. 118. Nonoxynol-5 Igepal ® CO-520 20636-48-0 Rhodia Inc. 119. Nonoxynol-5 Igepal ® CO-520 26264-02-8 Rhodia Inc. 120. Nonoxynol-4 Alkasurf NP-4 27176-97-2 Rhodia Inc. 121. Polyglyceryl-10 Nikkol 102051-00-3 Nikko Chemicals Trioleate Decaglyn 3-OV Co., Ltd. 122. Polyglyceryl-10 Nikkol 33940-99-7 Nikko Chemicals Dioleate Decaglyn 2-O Co., Ltd. 123. Polyglyceryl-10 Caprol 10G40 34424-98-1 Abitec Tetraoleate Corporation 124. Polyglyceryl-10 Nikkol 79777-30-3 Nikko Chemicals Stearate Decaglyn 1-SV Co., Ltd. EX 125. Polyglyceryl-10 S-Face 79665-93-3 Sakamoto Oleate O-1001 P Yakuhin Kogyo Co., Ltd. 126. Polyglyceryl-10 Nikkol 87390-32-7 Nikko Chemicals Myristate Decaglyn 1-MV Co., Ltd. EX 127. Dermofeel ® Dermofeel ® 34406-66-1 Dr. Straetmans G 10 L G 10 L 128. Polyglyceryl-6 Laurate NIKKOL 51033-38-6 Chemical Navi Hexaglyn 1-L 129. Polyglyceryl-6 S-Face 126928-07-2 Sakamoto Isostearate IS-601 P Yakuhin Kogyo Co., Ltd. 130. Choleth-10 Emalex 27321-96-6 Nihon Emulsion CS-10 Company, Ltd. 131. Steareth-10 Allyl Salcare ® 109292-17-3 BASF Ether/Acrylates SC80 Copolymer 132. Polyvinyl Giovarez ® 1800 9003-96-7 Phoenix Stearyl Ether Chemical, Inc. 133. Dicetyl Ether Cosmacol — Sosol Germany Ether 16 GmbH 134. PPG-23- Unisafe 9038-43-1 Pola Chemical Steareth-34 34S-23 Industries, Inc. 135. Stearoxypropyl Farmin 17517-01-0 Kao Corp. Dimethylamine DM E-80 136. Distearyl Ether Cosmacol SE 6297-03-6 Sasol Germany GmbH 137. Polyquatemium-10 AEC 55353-19-0 A & E Connock Polyquaternium-10 (Perfumery Cosmetics) Ltd. 138. Octyl ether Dioctyl ether 629-82-3 Sigma Adlrich (UK) 139. Ethyl Ether Diethyl Ether 60-29-7 EMD Chemicals 140. Methyl Hexyl methyl hexyl 4747-07-3 TCI AMERICA Ether Ethers ether 141. Ceteth-12 Emalex 112 94159-75-8 Nihon Emulsion Company, Ltd. 142. Ceteth-10 or cetyl Jeecol CA-10 14529-40-9 Jeen International alcohol POE-10 143. Steareth-10 Jeecol SA-10 13149-86-5 Jeen International 144. Nonaethylene glycol Nonaethylene 3055-99-0 Sigma Aldrich monododecyl ether glycol (UK) monododecyl ether 145. Oleth-10 Brij ® O10 71976-00-6 Croda, Inc. 146. Oleth-10 Brij ® O10 24871-34-9 Croda, Inc. 147. PEG-12 Carbowax ™ 6790-09-6 The Dow PEG 600 Chemical Company 148. PEG-9 Sabopeg 400 3386-18-3 Sabo s.p.a. 149. PEG-10 DECAETHYLENE 5579-66-8 MolPort GLYCOL 150. PEG-6 Carbowax ™ 2615-15-8 The Dow PEG 300 Chemical Company 151. Glycerol propoxylate Glycerol 25791-96-2 Sigma Aldrich propoxylate (UK) 152. Glycerol ethoxylate Glycerol 31694-55-0 Sigma Aldrich ethoxylate (UK) 153. Laureth-8 AFC Laureth-8 3055-98-9 A & E Connock (Perfumery & Cosmetics) Ltd. 154. Oleth-8 Emalex 508 27040-03-5 Nihon Emulsion Company, Ltd. 155. Laureth-7 Alfonic 3055-97-8 Sasol North 1216CO-7 America, Inc. Ethoxylate 156. Steareth-7 Polyoxyethylene 66146-84-7 Sigma Aldrich (7) stearyl ether 157. Deceth-6 Alfonic 1012- 5168-89-8 Sasol North 6.0 Ethoxylate America, Inc. 158. Steareth-6 Emalex 606 2420-29-3 Nihon Emulsion Company, Ltd. 159. Hexaethylene glycol Hexaethylene 3055-96-7 Sigma-Aldrich monododecyl ether glycol (UK) monododecyl ether 160. Hexaethylene glycol Hexaethylene 5168-91-2 Sigma-Aldrich monohexadecyl ether glycol (UK) monohexadecyl ether 161. Beheneth-5 Nikkol BB-5 136207-49-3 Nikko Chemicals Co. Ltd, 162. Myreth-5 Isoxal 12 92669-01-7 Vevy Europe SpA 163. Steareth-5 Jeecol SA-5 71093-13-5 Jeen International Corporation 164. Ceteth-5 Emalex 105 4478-97-1 Nihon Emulsion Company, Ltd. 165. Oleth-5 Brij ® O5 53 53-27-5 Croda, Inc. 166. Laureth-5 Safol ® 23E5 3055-95-6 Sasol North Ethoxylate America, Inc. 167. Steareth-4 Jeecol SA-4 59970-10-4 Jeen International Corporation 168. Laureth-4 Brij ® L4 5274-68-0 Croda, Inc. 169. Myreth-4 Homulgator 920G 39034-24-7 Grau Aromatics GmbH & Company KG 170. Ceteth-4 Procol CA-4 5274-63-5 Protameen Chemicals 171. Oleth-4 Chemal OA-4 5353-26-4 Chemax, Inc. 172. Oleth-4 Chemal OA-4 103622-85-1 Chemax, Inc. 173. Polyimide-1 Aquaflex ™ 497926-97-3 Chemwill XL-30 174. Polymethoxy Bicyclic Caswell No. 56709-13-8 Angene Chemical Oxazolidine 494CA 175. Hydroxymethyl Zoldine ™ ZT 6542-37-6 Angus Chemical Dioxoazabicyclooctane Company 176. Dihydro-7a- 5-Ethyl-1- 7747-35-5 Sigma Aldrich ethyloxazolo aza-3,7- (UK) [3,4-c]oxazole dioxabicyclo [3.3.0]octane 177. Dibenzylidene Disorbene ® 32647-67-9 Roquette Sorbitol America, Inc. 178. Dimethyldibenzylidene Millad ® 135861-56-2 Milliken Sorbitol 3988 Chemicals 179. Laureth-2 Alfonic 3055-93-4 Sasol North 1216CO-2 America, Inc. Ethoxylate 180. 2-(2-Butoxyethoxy) Piperonyl 51-03-6 Sigma-Aldrich ethyl Butoxide (UK) (6-propylpiperonyl) ether 181. Menthone Glycerin Frescolat ® 63187-91-7 Symrise Acetal MGA 182. Propylene Glycol Mackaderm 68332-79-6 Rhodia Inc. Caprylate PGC 183. Diethoxynonadiene SBB016951 67674-36-6 Ambinter 184 Menthoxypropanediol Coolact ® 10 87061-04-9 Takasago Alcohols International Corporation 185. 2-Diphenylmethoxy- Diphenhydramine 147-24-0 Sigma-Aldrich N,N-dimethylethylamine HCl (UK) hydrochloride 186. 3-((2- — 70445-33-9 — ethylhexyl)oxy) propane-1,2-diol 187. 3-((2- — — — propylheptyl)oxy) propane-1,2-diol 188. 1-amino-3-((2- — 99509-00-9 — ethylhexyl)oxy) propan-7-ol 189. 1-(1-Methyl-2- Di(propylene 29911-27-1 Sigma Aldrich propoxyethoxy)-2- glycol) propyl (UK) propanol ether

The compounds, as described above in Tables 4(a) and 4(b), act as a substantially non-odorous fragrance modulator of the overdosed perfume materials of the present invention. For example, the substantially non-odorous fragrance modulators, Without wishing to be bound by theory, it is believed that the substantially non-odorous fragrance modulators associate to the low-volatility fragrance materials to allow for high wt % (e.g., greater than 30 wt %) of the composition to allow the low-volatility fragrance materials to drive the perceived character of the fragrance, while mitigating or eliminating a perceived harshness of the composition by the user.

Volatile Solvents

The composition according to the present invention, can include a volatile solvent present in the amount of from about 20 wt % to about 99 wt % relative to the total weight of the composition, about 30 wt % to about 80 wt %, about 55 wt % to about 75 wt %, or less than, equal to, or greater than about 20 wt %, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, or about 99 wt %, and wherein the solvent is a branch or unbranched C₁ to C₁₀ alkyl, akenyl or alkynyl group having at least one alcohol moiety, preferably ethanol, or isopropanol, or other alcohols (e.g., methanol, propanol, isopropanol, butanol, and mixtures thereof) commonly found in commercial fine fragrance products.

Accordingly, ethanol may be present in any of the compositions of the present invention, and more specifically, it will form from about 5 wt % to about 95 wt %, or even from about 10 wt % to about 80 wt %, 25 wt % to about 75 wt % of the composition, or combinations thereof, relative to the total weight of the composition. Alternatively, ethanol may be present in an amount of from about 10 wt % or 25 wt % to about 75 wt % or 80 wt %, relative to the total weight of the composition. The ethanol useful in the present invention may be any acceptable quality of ethanol, compatible and safe for the specific intended use of the composition such as, for example, topical applications of fine fragrance or cosmetic compositions.

Water

In some examples (e.g., those including a volatile solvent), water may be present in any of the compositions of the present invention, and more specifically, it may not exceed about 95 wt % relative to the total weight of the composition, about 90 wt % or less, about 85 wt % or less, about 80 wt %, or less, about 75 wt % or less, about 70 wt % or less, about 65 wt % or less, about 60 wt % or less, about 55 wt % or less, about 50 wt % or less, about 45 wt % or less, about 40 wt % or less, about 35 wt % or less, about 30 wt % or less, about 20 wt % or less, about 10 wt %, or less than, equal to, or greater than about 95 wt %, 90, 85, 80, 75, 70, 65, 60, 55, 50, 45, 40, 30, 35, 30, 25, 20, 15, 10, or 5 wt/o. Alternatively, water may be present in an amount of from about 5 wt % or about 95 wt % When the composition is a cosmetic composition the level of water should not be so high that the product becomes cloudy thus negatively impacting the product aesthetics. It is understood that the amount of water present in the composition may be from the water present in the volatile solvent (e.g., ethanol) used in the composition, as the case may be.

Non-Volatile Solvents

The composition may comprise a non-volatile solvent or a mixture of non-volatile solvents. Non-limiting examples of non-volatile solvents include benzyl benzoate, diethyl phthalate, isopropyl myristate, propylene glycol, dipropylene glycol, triethyl citrate, and mixtures thereof. These solvents often are introduced to the product via the perfume oil as many perfume raw materials may be purchased as a dilution in one of these solvents. Where non-volatile solvents are present, introduced either with the perfume materials or separately, then for the purposes of calculating the proportion of fragrance component having a vapor pressure of less than 0.001 Torr (0.000133 kPa) at 25° C. the total fragrance components does not include non-volatile solvents. Where non-volatile solvents are present, introduced either with the perfume materials or separately, then for the purposes of calculating the total level of fragrance component this does not include non-volatile solvents. In addition, if present with cyclic oligosacchrides, the non-volatile solvent may be included at a weight ratio of the non-volatile solvent to the cyclic oligosaccharide of less than 1:1, less than 1:2, less than 1:10, or less than 1:100.

Entrapment Materials

In other examples, compositions of the present invention can include an entrapment material at a level such that the weight ratio of the entrapment material to the fragrance materials is in the range of from about 1:20 to about 20:1. in some examples, the composition may comprise an entrapment material present in the amount of from about 0.001 wt % to about 40 wt %, from about 0.1 wt % to about 25 wt %, from about 0.3 wt % to about 20 wt %, from about 0.5 wt % to about 10 wt %, or from about 0.75 wt % to about 5 wt %, relative to the total weight of the composition. The compositions disclosed herein may include from 0.001 wt % to 40%, from 0.1 wt % to 25 wt %/o, from 0.3 wt % to 20 wt %, from 0.5 wt % to 10 wt %/o or from 0.75 wt % to 5 wt %, relative to the total weight of the composition, of a cyclic oligosaccharide.

Suitable entrapment materials for use herein are selected from polymers; capsules, microcapsules and nanocapsules; liposomes, absorbents; cyclic oligosaccharides and mixtures thereof. Preferred are absorbents and cyclic oligosaccharides and mixtures thereof. Highly preferred are cyclic oligosaccharides (see PCT Publication Nos. WO2000/67721 (Procter & Gamble); and WO2000/67720 (Procter & Gamble); and U.S. Pat. No. 6,893,647 (Procter & Gamble)).

As used herein, the term “cyclic oligosaccharide” means a cyclic structure comprising six or more saccharide units. Preferred for use herein are cyclic oligosaccharides having six, seven or eight saccharide units and mixtures thereof, more preferably six or seven saccharide units and even more preferably seven saccharide units. It is common in the art to abbreviate six, seven and eight membered cyclic oligosaccharides to a, p and y respectively.

The cyclic oligosaccharide of the compositions used for the present invention may comprise any suitable saccharide or mixtures of saccharides. Examples of suitable saccharides include, but are not limited to, glucose, fructose, mannose, galactose, maltose and mixtures thereof. However, preferred for use herein are cyclic oligosaccharides of glucose. The preferred cyclic oligosaccharides for use herein are α-cyclodextrins or β-cyclodextrins, or mixtures thereof, and the most preferred cyclic oligosaccharides for use herein are β-cyclodextrins.

The cyclic oligosaccharide, or mixture of cyclic oligosaccharides, for use herein may be substituted by any suitable substituent or mixture of substituents. Herein the use of the term “mixture of substituents” means that two or more different suitable substituents can be substituted onto one cyclic oligosaccharide. The derivatives of cyclodextrins consist mainly of molecules wherein some of the OH groups have been substituted. Suitable substituents include, but are not limited to, alkyl groups; hydroxyalkyl groups; dihydroxyalkyl groups; (hydroxyalkyl)alkylenyl bridging groups such as cyclodextrin glycerol ethers; aryl groups; maltosyl groups; allyl groups; benzyl groups; alkanoyl groups; cationic cyclodextrins such as those containing 2-hydroxy-3-(dimethylamino) propyl ether; quaternary ammonium groups; anionic cyclodextrins such as carboxyalkyl groups, sulphobutylether groups, sulphate groups, and succinylates; amphoteric cyclodextrins; and mixtures thereof.

The substituents may be saturated or unsaturated, straight or branched chain. Preferred substituents include saturated and straight chain alkyl groups, hydroxyalkyl groups and mixtures thereof. Preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₈ alkyl or hydroxyalkyl groups or mixtures thereof, more preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₆ alkyl or hydroxyalkyl groups or mixtures thereof, even more preferred alkyl and hydroxyalkyl substituents are selected from C₁-C₄ alkyl or hydroxyalkyl groups and mixtures thereof. Especially preferred alkyl and hydroxyalkyl substituents are propyl, ethyl and methyl, more especially hydroxypropyl and methyl and even more preferably methyl.

Suitable cyclic oligosaccharides for use in the present invention are unsubstituted, or are substituted by only saturated straight chain alkyl, or hydroxyalkyl substituents. Therefore, preferred examples of cyclic oligosaccharides for use herein are α-cyclodextrin, β-cyclodextrin, methyl-α-cyclodextrin, methyl-β-cyclodextrin, hydroxypropyl-α-cyclodextrin and hydroxypropyl-β-cyclodextrin. Most preferred examples of cyclic oligosaccharides for use herein are methyl-α-cyclodextrin and methyl-β-cyclodextrin. These are available from Wacker-Chemie GmbH Hanns-Seidel-Platz 4, Munchen, DE under the tradename Alpha W6 M and Beta W7 M respectively.

The cyclic oligosaccharides of the compositions used for the present invention can be soluble in water, ethanol, or both water and ethanol. As used herein “soluble” means at least about 0.1 g of solute dissolves in 100 mL of solvent, at 25° C. and 1 standard atmospheric pressure (760 mmHg). The cyclic oligosaccharides for use herein have a solubility of at least about 1 g/100 mL, at 25° C. and 1 atm of pressure. In some examples, cyclic oligosaccharides are only present at levels up to their solubility limits in a given composition at room temperature. A person skilled in the art will recognize that the levels of cyclic oligosaccharides used in the present invention will also be dependent on the components of the composition and their levels, for example the solvents used or the exact fragrance oils, or combination of fragrance oils, present in the composition. Therefore, although the limits stated for the entrapment material are preferred, they are not exhaustive.

Propellants

The compositions described herein may include a propellant. Some examples of propellants include compressed air, nitrogen, inert gases, carbon dioxide, and mixtures thereof. Propellants may also include gaseous hydrocarbons like propane, n-butane, isobutene, cyclopropane, and mixtures thereof. Halogenated hydrocarbons like 1,1-difluoroethane may also be used as propellants. Some non-limiting examples of propellants include 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, trans-1,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro-2,2-trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), monochlorodifluoromethane, and mixtures thereof. Some other propellants suitable for use include, but are not limited to, A-46 (a mixture of isobutane, butane and propane), A-31 (isobutane), A-17 (n-butane), A-108 (propane), AP70 (a mixture of propane, isobutane and n-butane), AP40 (a mixture of propane, isobutene and n-butane), AP30 (a mixture of propane, isobutane and n-butane), and 152A (1,1 diflouroethane). The propellant may have a concentration from about 15%, 25%, 30%, 32%, 34%, 35%, 36%, 38%, 40%, or 42% to about 70%, 65%, 60%, 54%, 52%, 50%, 48%, 46%, 44%, or 42% by weight of the total fill of materials stored within the container.

Antiperspirant Active

The compositions described herein may be free of, substantially free of, or may include an antiperspirant active (e.g., any substance, mixture, or other material having antiperspirant activity). Examples of antiperspirant actives include astringent metallic salts, like the inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof. Such antiperspirant actives include, for example, the aluminum and zirconium salts, such as aluminum halides, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.

Other Ingredients

In yet another aspect, the composition consists essentially of the recited ingredients but may contain small amounts (not more than about 10 wt %, preferably no more than 5 wt %, or preferably no more than 2 wt % thereof, relative to the total weight of the composition) of other ingredients that do not impact on the fragrance profile, particularly the evaporation rate and release of the fragrance materials. For example, a fine fragrance composition may comprise stabilizing or anti-oxidant agents, UV filters or quenchers, or colouring agents, commonly used in perfumery. There are a number of other examples of additional ingredients that are suitable for inclusion in the present compositions, particularly in compositions for cosmetic use. These include, but are not limited to, alcohol denaturants such as denatonium benzoate; UV stabilizers such as benzophenone-2; antioxidants such as tocopheryl acetate; preservatives such as phenoxyethanol, benzyl alcohol, methyl paraben, and propyl paraben; dyes; pH adjusting agents such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, and sodium carbonate; deodorants and anti-microbials such as farnesol and zinc phenolsulphonate; humectants such as glycerine; oils; skin conditioning agents such as allantoin; cooling agents such as trimethyl isopropyl butanamide and menthol; silicones; solvents such as hexylene glycol; hair-hold polymers such as those described in PCT Publication No. WO94/08557 (Procter & Gamble); salts in general, such as potassium acetate and sodium chloride and mixtures thereof.

In yet another aspect, the composition of the present invention, depending on its intended use, is a mixture of fragrance materials possibly together with other ingredients such as, for example, perfume carriers. By the term “perfume carrier”, it is meant to include materials which are practically neutral from a perfumery point of view, e.g., which does not significantly alter the organoleptic properties of perfuming components. The perfume carrier may be a compatible liquid or solid fillers, diluents, and the like. The term “compatible”, as used herein, means that the components of the compositions of this invention are capable of being combined with the primary actives of the present invention, and with each other, in a manner such that there is no interaction which would substantially reduce the efficacy of the composition under ordinary use situations. The type of carrier utilized in the present invention depends on the type of product desired and may comprise, but are not limited to, solutions, aerosols, emulsions (including oil-in-water or water-in-oil), gels, and liposomes. Preferably, the carrier is a liquid and will be a solvent such as, for example, dipropyleneglycol, diethyl phthalate, isopropyl myristate, benzyl benzoate, 2-(2-ethoxyethoxy)-1-ethanol, or ethyl citrate (triethyl citrate).

In yet another aspect, the compositions for use in the present invention may take any form suitable for use, such as for perfumery or cosmetic use. These include, but are not limited to, vapor sprays, aerosols, emulsions, lotions, liquids, creams, gels, sticks, ointments, pastes, mousses, powders, granular products, substrates, cosmetics (e.g., semi-solid or liquid makeup, including foundations) and the like. In some examples, the compositions for use in the present invention take the form of a vapor spray. Compositions of the present invention can be further added as an ingredient to other compositions, preferably fine fragrance or cosmetic compositions, in which they are compatible. As such they can be used within solid composition or applied substrates etc. Examples of products including the composition can include a fabric care product, an air care product, a home care product, a beauty care product, or a mixture thereof. Specific examples of products can include a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray. The composition can be contacted with skin, hair, or a fabric.

Article of Manufacture

The composition may be included in an article of manufacture comprising a spray dispenser. The spray dispenser may comprise a vessel for containing the composition to be dispensed. The spray dispenser may comprise an aerosolized composition (e.g., a composition comprising a propellant) within the vessel as well. Other non-limiting examples of spray dispensers include non-aerosol dispensers (e.g., vapor sprays), manually activated dispensers, pump-spray dispensers, or any other suitable spray dispenser available in the art.

Methods of Using the Compositions

The composition of the present invention according to any embodiments described herein is a useful perfuming composition, which can be advantageously used as consumer products intended to perfume any suitable substrate. As used herein, the term “substrate” means any surface to which the composition of the present invention may be applied to without causing any undue adverse effect. For example, this can include a wide range of surfaces including human or animal skin or hair, paper (fragranced paper), air in a room (air freshener or aromatherapy composition), fabric, furnishings, dishes, hard surfaces and related materials. Preferred substrates include body surfaces such as, for example, hair and skin, most preferably skin.

The composition of the present invention may be used in a conventional manner for fragrancing a substrate. An effective amount of the composition, such as from about 1 μL to about 100 mL, preferably from about 10 μL to about 1,000 μL, more preferably from about 25 μL to about 500 μL, from about 50 μL to about 100 μL, from about 100 μL to about 20 mL, or combinations thereof, is applied to the suitable substrate. Alternatively, an effective amount of the composition of the present invention is less than, equal to, or greater than about 1 μL, 10 μL, 25 μL or 50 μL to about 100 μL, 500 μL, 1,000 μL, 10,000 μL, 10 mL, 20 mL, 25 mL, 30 mL, 40 mL, 50 mL, 60 mL, 70 mL, 80 mL, 90 mL, or 100 mL. The composition may be applied by hand or applied utilizing a delivery apparatus such as, for example, vaporizer or atomizer. Preferably, the composition is allowed to dry after its application to the substrate. The scope of the present invention should be considered to cover one or more distinct applications of the composition or the continuous release of a composition via a vaporizer or other type of atomizer.

The present disclosure provides a method for imparting, intensifying, or modifying an odor on human skin or human hair, comprising applying to human skin and/or human hair the composition of the present invention. Examples of notes or characters that can be enhanced include those chosen from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.

Preferably, the fragrance profile or character of the composition of the present invention is detectable by a panel of experts or professional evaluators or individual experts or professional evaluators at later time points such as, for example, 30 mins, 1 hour, 2 hours, 3 hours, 4 hours, 5 hours, 6 hours, 7 hours, 8 hours, 10 hours, and possibly all the way up to 24 hours after application of the composition to a substrate as compared to controls (e.g., those without modulators).

In another aspect, the present invention is also directed to a method of producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a composition of the present invention.

Test Methods

The following assays set forth must be used in order that the invention described and claimed herein may be more fully understood.

Test Method 1: Determining Vapor Pressure

In order to determine the vapor pressure for the fragrance materials, go to the website https://scifinder.cas.org/scifinder/view/scifinder/scifinderExplore.jsf and follow these steps to acquire the vapor pressure.

1. Input the CAS registry number for the particular fragrance material. 2. Select the vapor pressure from the search results. 103. Record the vapor pressure (given in Torr at 25° C.).

SciFinder uses Advanced Chemistry Development (ACD/Labs) Software Version 11.02. (©1994-2018). If the CAS number for the particular fragrance material is unknown or does not exist, you can utilize the ACD/Labs reference program to directly determine the vapor pressure. Vapor Pressure is expressed in 1 Torr, which is equal to 0.133 kilopascal (kPa).

Test Method 2a: Olfactory Tests a

In order to show the effect of the substantially non-odorous fragrance modulators and fragrance component of the present invention on the perception of fragrance profile in a composition of the present invention, test compositions are made, as described in the Example section, and given to expert panelists to evaluate.

At the testing facility, 50 μL samples of the compositions and the controls are applied to glass slides and placed on a hot plate at 32° C. to represent skin temperature for varying durations. It is important that glass slides of samples that are to be later compared are prepared at the same time. The panelists are asked to evaluate the perceived fragrance profile (intensity and/or character) of each glass slide sample at a given time point. Slides are presented coded so that their identity is not known by the panelists. Within a given time point panelists evaluate the slides in a random order and are able to revisit their assessment as they work through the slides at that time point. Their assessments are recorded. In the subsequent analysis, the data for strength and character comparisons are drawn from the independent assessments carried out at a given time point. Only when using the character difference scale below are any 2 products physically directly compared to each other. Panelists are selected from individuals who are either trained to evaluate fragrances according to the scales below or who have experience of fragrance evaluation in the industry. Typically, around 4-6 panelists are used to evaluate a given product and its control.

(a) Fragrance Intensity:

The panelists are asked to give a score on a scale of 0 to 5 for perceived fragrance intensity according to the odour intensity scale set out in Table 5 herein below.

TABLE 5 Odour Intensity Scale Score Fragrance Intensity 0 None 1 Very Weak 2 Weak 3 Moderate 4 Strong 5 Very Strong

(b) Fragrance Character:

The panelists are asked to assess the fragrance character in one of 2 ways:

-   i) a score on a scale of 0 to 3 for the dominance of particular     characters that are relevant to that particular fragrance, e.g.:     fresh, harsh, green, watery, floral, rose, muguet, fruity, apple,     berry, citrus, creamy, woody, balsamic, amber, musk just to name a     few, according to the odour grading scale set out in Table 6(i)     herein below; -   ii) a score on a scale of 1 to 5 for changes in the perceived     fragrance profile change for the test compositions versus the     controls according to the odour grading scale set out in Table 6(ii)     herein below.

TABLE 6(i) Character Dominance Odour Grading Scale Score Fragrance Character Dominance 0 Not noticeable 1 Slight presence of the character 2 Moderate presence of the character 3 Dominance of the character

TABLE 6(ii) Character Difference Odour Grading Scale Score Fragrance Profile Change 1 Fragrance profile is unchanged, i.e., no difference between the sample vs. the control. 2 Slight fragrance profile change when compared directly with the control. 3 Moderate fragrance profile but similar character to the control, 4 Large difference in fragrance profile from the control. 5 Total difference in the fragrance profile from the control.

The results of the panelists are averaged and if sufficient panelists are available, typically around 10, then the data can be analyzed using Analysis of Variance methods. The model treats the subject as a random effect and looks at the impact of product, time and the interaction between product and time. From the analysis the least square means for the product and time interaction are obtained. These means (as well as their confidence intervals) are then plotted to enable comparisons between products at each time point. It should be noted that the confidence levels plotted are intended as a guide, and not as a statistical comparison, as they do not take into account that multiple testing has been performed. As well as a graphical assessment, statistical comparisons between the two products at each of the time points are performed with a Sidak correction for multiple comparisons. The p-values for the product differences are obtained, with p-values <0.05 indicating a statistical difference between the two products at 5% significance (or 95% confidence). Typically for assessments by expert panelists of evaluators and perfumers there are 4-6 participants. In these cases a full statistical analysis is not possible and typically we observe that an average difference of 0.75 on the scales used considered to be meaningful, i.e.: 3 out of 4 experts gave the products a grade with a difference of 1.

Test Method 2b: Olfactory Tests b

In order to show the effect of the substantially non-odorous fragrance modulators and fragrance component on the perception of fragrance profile in a composition of the present invention, test compositions are made, as described in the Example section, and given to panelists to evaluate and describe.

At the testing facility, 20 μL samples of the compositions and the controls are applied to glass slides and placed on a hot plate at 32° C. to represent skin temperature for varying durations. Glass slides of samples that are to be later compared are prepared at the same time. The panelists are asked to evaluate the perceived fragrance profile (intensity and/or character) of each glass slide sample at a given time point. Slides are presented coded so that their identity is not known by the panelists. Within a given time point, panelists evaluate the slides in a random order and are able to revisit their assessment as they work through the slides at that time point. Their assessments are recorded. The experiments are run in duplicate on 2 different days and the data combined. In the subsequent analysis, the data for strength and character comparisons are drawn from the independent assessments carried out at a given time point.

Panelists are individuals who are specifically trained to evaluate fragrances according to the scale below using odour standards for calibration. Calibration standards are selected from perfume materials that represent specific families, for example, without being exhaustive, for the woody family panelists are calibrated with cedarwood, vetivert oil, patchouli oil, iso-E super, Norlimbanol and sandalwood or for harshness, for example, without being exhaustive, panelists are calibrated with pyrazines, Vertocitral, Aldehyde phenylacetic, Cedar Atlas and Cuminic aldehyde. Around 10-15 panelists are used to evaluate a given product and its control. Panelists assess the samples according to 2 scales:

(a) Fragrance Intensity:

The panelists give a score on a unlabeled continuous scale where 0 is no perceptible odour and 10 is very strong odour.

(b) Fragrance Character:

The panelists assess the fragrance character according to a number of pre-defined attributes e.g.: citrus, green, aromatic, floral, fruity, spicy, musk, woody, fresh, harsh just to name a few, scoring each one on unlabeled continuous scale where 0 is no perceptible odor and 10 is very strong odor.

The results of the panelists are analyzed using three-way analysis of variance (replicate/sample/panellist) with interaction followed by multiple comparisons with the best or control test (MCB) for example, the two-tailed Dunnett test. The p-values for the product differences are obtained, with p-values <0.05 indicating a statistical difference between products at 5% significance (or 95% confidence) and with p-values <0.10 indicating a statistical difference between products at 10% significance (or 90% confidence). The data is represented graphically in bar or line charts showing the average for each attribute at a given time point with 95% confidence intervals as error bars.

Data generated according to this method, particularly for the harshness attribute, is discussed below.

EXAMPLES Example 1—Fragrance Oils

Fragrance examples 1, 2, 3 and 4 3 are provided below in Tables 7-11, respectively, as non-limiting examples of formulations of fragrance materials intended to form the fragrance component of the compositions of the present invention.

The following fragrance formulations are made by mixing the listed ingredients in the listed proportions (wt %) at room temperature, wherein the wt % is relative to the total weight of the fragrance component.

TABLE 7 Fragrance Example 1 Parts Vapour (Weight %) Pressure CAS Number Perfume Material Example 1 (Torr at 25° C.) Volatility Natural Styrax Resoid 0.500-0.520 — High Natural Labdanum Cistus 0.4400-0.4700 3.48900 High Absolute 3681-71-8 cis-3-Hexenyl acetate 0.1000-0.1050 1.21900 High 928-96-1 BETA GAMMA 0.1000-0.1050 1.03900 High HEXENOL 68039-49-6 LIGUSTRAL OR TRIPLAL 0.2000-0.2080 0.57800 High Natural Cumin Oil 0.2000-0.2080 — High 88-41-5 Verdox 0.5000-0.5300 0.10300 High Natural Cade Oil 1.5490-1.5600 — Moderate 58567-11-6 BOISAMBRENE 5.1000-5.2000 0.00433 Moderate FORTE 65442-31-1 ISO BUTYL 0.1500-0.1600 0.00408 Moderate QUINOLINE 127-51-5 IONONE GAMMA 20.7000-20.7900 0.00282 Moderate METHYL 211299-54-6 AMBROCENIDE 0.0400-0.0450 0.00182 Moderate (add as 10% in DPG) 91-64-5 Coumarin 25.9000-26.0000 0.00130 Moderate Natural Cedarwood Texas Light 25.9000-26.0000 — Low Natural Cypriol Oil 10.3907 — Low 10.3000-10.4000 Natural Guaiacwood Oil 5.1000-5.2000 — Low 4707-47-5 LRG 201/Evernyl 2.5000-2.6000 0.00001 Low Total 100.00 Oil structure: 2.1% high volatile perfume materials; 53.7% moderate volatile perfume materials; 44.2% low volatile perfume materials.

TABLE 8 Fragrance Example 2 Parts Vapour CAS (Weight %) Pressure Number Perfume Material Example 2 (Torr at 25° C.) Volatility Natural Styrax Resoid 1.000-1.100 — High Natural Labdanum Absolute 0.900-0.950 — High 3681-71-8 cis-3-Hexenyl acetate 0.200-0.230 1.21900 High 928-96-1 BETA GAMMA HEXENOL 0.200-0.230 1.03900 High 68039-49-6 LIGUSTRAL OR TRIPLAL 0.400-0.420 0.57800 High Natural Cumin Oil 0.400-0.420 — High Natural Cade Oil (supplied at 0.01% DPG) 0.050-0.053 — High 88-41-5 Verdox 0.000-1.040 0.10300 High 22471-55-2 Thesaron 0.700-0.730 0.07670 Moderate 144-39-8 Linalyl Propionate 1.030-1.040 0.02630 Moderate 105-87-3 Geranyl Acetate 1.200-1.300 0.02560 Moderate 2785-89-9 4-Ethylguaiacol 0.200-0.230 0.02000 Moderate 54440-17-4 Safraleine 2.060-2.070 0.01260 Moderate 104-54-1 Cinnamic Alcohol 0.510-0.520 0.01170 Moderate 97-53-0 Eugenol 0.000-1.040 0.01040 Moderate 6790-58-5 Ambronat 6.100-6.300 0.00934 Moderate 104-61-0 NONALACTONE 0.700-0.800 0.00858 Moderate 18871-14-2 Jasmal 2.000-2.100 0.00434 Moderate 65442-31-1 ISO BUTYL QUINOLINE 0.500-0.530 0.00408 Moderate 107-75-5 HYDROXYCITRONELLAL 2.000-2.100 0.00318 Moderate 127-51-5 IONONE GAMMA METHYL 15.000-16.000 0.00282 Moderate 33704-61-9 Cashmeran 2.500-2.600 0.00269 Moderate 36306-87-3 Kephalis 5.100-5.200 0.00269 Moderate 77-54-3 Cedac/CEDRYL ACETATE S 7.700-7.800 0.00192 Moderate 91-64-5 Coumarin 2.500-2.600 0.00130 Moderate 24851-98-7 METHYL DIHYDRO 4.130-4.140 0.00071 Low JASMONATE 65113-99-7 Sandalore 5.100-5.190 0.00063 Low Natural Cedarwood Oil Rect 1.000-1.400 — Low Natural Vetivert Oil 2.000-2.100 — Low 77-53-2 Cedrol Crude 4.100-4.200 0.00057 Low 54464-57-2 Iso E Super 12.200-12.500 0.00054 Low Natural PATCHOULI OIL 6.100-6.300 — Low 65405-77-8 cis-3-Hexenyl salicylate 2.000-2.100 0.00025 Low 4940-11-8 ETHYL MALTOL (supplied at 0.150-0.160 0.00023 Low 10% in DPG) 4707-47-5 LRG 201/Evernyl 1.030-1.040 0.00001 Low 28645-51-4 Ambrettolide 5.100-5.120 0.000001 Low Total 100.00 Oil structure: 4.3% high volatile perfume materials; 52.1% moderate volatile perfume materials; 43.6% low volatile perfume materials.

TABLE 9 Fragrance Example 3 Parts Vapour CAS (Weight %) Pressure Number Perfume Material Example 3 (Torr at 25° C.) Volatility Natural Basil Oil 0.440-0.470 — High Natural Cardamom Oil 0.180-0.190 — High Natural Cypress Oil 0.225-0.235 — High Natural Ginger Oil India 0.180-0.190 — High Natural Bergamot Oil 4.600-4.670 — High Natural Lemon Oil 4.100-4.180 — High Natural Violet Leaves Absolute 0.040-0.050 — High 39255-32-8 Manzanate 0.040-0.050 2.90600 High 3681-71-8 cis-3-Hexenyl acetate 0.040-0.050 1.21900 High 928-96-1 BETA GAMMA HEXENOL 0.130-0.142 1.03900 High 67633-96-9 Liffarome 0.090-0.100 0.72100 High 68039-49-6 LIGUSTRAL OR TRIPLAL 0.040-0.050 0.57800 High 18479-58-8 DIHYDRO MYRCENOL 9.350-9.500 0.16600 High 88-41-5 verdox 0.900-8.100 0.10300 High Natural Rose Oil 0.040-0.050 — Moderate Natural Lavandin Oil 0.690-0.700 — Moderate Natural Geranium Oil 0.090-0.100 — Moderate Natural Cedar Atlas 5.075-5.095 — Moderate 78-70-6 Linalool 1.600-1.650 0.09050 Moderate 60-12-8 Phenyl Ethyl Alcohol 0.200-0.250 0.07410 Moderate 67634-00-8 Allyl Amyl Glycolate 0.400-0.430 0.04000 Moderate 125109-85-5 Florhydral 0.265-0.280 0.02000 Moderate 134-20-3 methyl Anthranilate 0.040-0.050 0.01580 Moderate 150-84-5 Citronellyl acetate 0.040-0.050 0.01370 Moderate 68845-00-1 Boisiris 3.690-3.710 0.01350 Moderate 106-24-1 geraniol 0.900-0.950 0.01330 Moderate 19870-74-7 CEDRYL METHYL ETHER 5.070-5.095 0.01280 Moderate 120-57-0 heliotropin 0.040-0.050 0.01040 Moderate 3025-30-7 Ethyl, 2 4-Decadienoate 0.130-0.141 0.00954 Moderate 6790-58-5 Ambronat 0.680-0.700 0.00930 Moderate 2705-87-5 Allyl Cyclohexane Propionate 0.210-0.240 0.00925 Moderate 56973-85-4 Neobutenone, α 0.130-0.140 0.00763 Moderate 63500-71-0 florol 2.200-2.350 0.00557 Moderate 10339-55-6 Ethyl Linalool 10.560-10.600 0.00520 Moderate 23696-85-7 Damascenone 0.077-0.081 0.00503 Moderate 58567-11-6 BOISAMBRENE FORTE 3.650-3.750 0.00433 Moderate 93-29-8 Iso Eugenol Acetate 0.085-0.095 0.00324 Moderate 476332-65-7 AMBER XTREME (supplied at 0.008-0.010 0.00323 Moderate 10% in DPG) 68901-15-5 Cyclo Galbanate 0.220-0.240 0.00323 Moderate 127-51-5 IONONE GAMMA METHYL 0.900-0.990 0.00282 Moderate 1205-17-0 helional 1.800-1.900 0.00270 Moderate 33704-61-9 Cashmeran 0.900-0.950 0.00269 Moderate 141-13-9 Adoxal 0.200-0.250 0.00257 Moderate 121-33-5 vanillin 0.400-0.480 0.00194 Moderate 91-64-5 Coumarin 1.150-1.160 0.00130 Moderate Natural Vetivert Oil 1.800-1.900 — Low 28940-11-6 Calone 0.040-0.050 0.00083 Low 70788-30-6 Norlimbanol 0.680-0.700 0.00047 Low 1222-05-5 Galaxolide 11.300-11.500 0.00041 Low 65405-77-8 cis-3-Hexenyl salicylate 2.300-2.350 0.00025 Low 107898-54-4 Polysantol 3.200-3.300 0.00012 Low 82356-51-2 delta muscenone 0.900-0.930 0.00005 Low 21145-77-7 Tonalid 0.900-0.930 0.00003 Low 4707-47-5 LRG 201/Evernyl 0.300-0.340 0.00001 Low Total 100.00 Oil structure: 27.8% high volatile perfume materials; 42.1% moderate volatile perfume materials; 30.1% low volatile perfume materials.

TABLE 10 Fragrance Example 4 Vapour CAS Parts Pressure Number Perfume Material (Weight %) (Torr at 25° C.) Volatility Natural Elemi Coeur Oil 1.250-1.750 High 928-96-1 BETA GAMMA HEXENOL 0.0500-0.1500 1.03900 High 68039-49-6 LIGUSTRAL OR TRIPLAL 0.0500-0.1500 0.57800 High Natural Cinnamon Bark Oil 3.500-4.500 Moderate 6790-58-5 Ambronat 4.500-5.500 0.00934 Moderate 24720-09-0 ALPHA DAMASCONE 0.500-1.500 0.00830 Moderate Natural Cedar Atlas Oil 47.000-49.000 Moderate Natural Ginger Oil Fresh Madagascar 2.500-3.500 Moderate 77-53-2 Cedrol Crude 14.000-16.000 0.00057 Low 70788-30-6 Norlimbanol 2.800-3.200 0.00047 Low 95962-14-4 Nectaryl 7.000-7.500 0.00037 Low 82356-51-2 Delta Muscenone 11.000-13.000 0.00005 Low Oil structure: 1.7% high volatile perfume materials; 61.0% moderate volatile perfume materials; 37.3% low volatile perfume materials.

Example 2—Compositions Comprising Fragrance Oils and Substantially Non-Odorous Fragrance Modulators

Compositions A1, C₁, E1, G1, I1 and A2, C₂, E2, G2 and I2 are examples of fragrance compositions according to the present invention, made with any one of fragrance oil examples 1-4 respectively. In parallel, control compositions B1, D1, F1, H1, J1 and B2, D2, F2, H2, J2 are prepared by replacing the different substantially non-odorous fragrance modulators by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 11 and 12 in the proportions indicated.

TABLE 11 Fragrance Compositions Fragrance Composition (wt %)¹ Ingredients A1 B1 C1 D1 E1 F1 G1 H1 I1 J1 Bottom heavy 5-10 5-10 0.01-2 0.01-2 3-10 3-10 5-10 5-10 0.1-5 0.1-5 fragrance oil² Ethanol 60-99.9 Butylated 0-0.07 Hydroxy Toluene Modulator A³ 2-20 — — — — — — — — — Modulator B⁴ — — 0.1 — — — — — — — Modulator C⁵ — — — — 0.1-5 — — — — — Modulator D⁶ — — — — — — 2-10 — — — Modulator E⁷ — — — — — — — — 0.1-3 — Deionized water to 100.00 ¹Wt % is relative to the total weight of the composition. ²Can be any one of fragrance examples 1-4 ³Can be any one of the substantially non-odorous fragrance modulators examples: sucrose laurate; sucrose dilaurate, sucrose myristate, sucrose palmitate, sucrose sterate; sucrose 5 distearate; or sucrose tristearate. ⁴Substantially non-odorous fragrance modulator is (E)-1-2,6-trimethylcyclohexyl)oct-1-en-3-one. ⁵Can be any one of the substantially non-odorous fragrance modulators examples: 2-(1-menthoxy) ethane-1-ol; 1-(1-menthoxy) propane-2-ol; 3-(1-menthoxy) propane-1-ol; 3(1-10 menthoxy) propane-1,2-diol; 2-methyl-3-(1-menthoxy)propane-1,2-diol; or 4-(1-menthoxy) butane-1-ol. ⁶Substantially non-odorous fragrance modulator is Hydroquinone beta-D-glycoside. ⁷Substantially non-odorous fragrance modulator is Hyaluronic acid disaccharide sodium salt or Sodium Hyaluronate (20-50 kDa).

TABLE 12 Fragrance Compositions Fragrance Composition (wt %)¹ Ingredients A2 B2 C2 D2 E2 F2 G2 H2 I2 J2 Bottom heavy 5-10 5-10 5-15 5-15 2.5-10 2.5-10 5-20 5-20 0.1-20 0.1-20 fragrance oil² Ethanol 60-99.9 Butylated 0-0.07 Hydroxy Toluene Modulator A³ 5-20 — — — — — — — — — Modulator B⁴ — — 0.5-5 — — — — — — — Modulator C⁵ — — — — 0.1-3.0 — — — — — Modulator D⁶ — — — — — — 2.5-15 — — — Modulator E⁷ — — — — — — — — 0.1-20 — Deionized water to 100.00 ¹Wt % is relative to the total weight of the composition. ²Can be any one of fragrance examples 1-4? ³Can be any one of the substantially non-odorous fragrance modulators examples: Propylene Glycol Propyl Ether, Hexaethylene glycol monododecyl ether, Panthenol Ethyl Ether, DL-Panthenol, Diisobutyl Adipate, or Diisoamyl Adipate. ⁴Neopentyl Glycol Diisononanoate. ⁵2-ethylhexyloxypropanediol. ⁶PPG-11 Stealyl Ether. ⁷Can be any one of the substantially non-odorous fragrance modulators examples: Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5; Isoceteth-7, Isoceteth-10; Iscoeteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether; or Cetearyl Ethylhexnoate.

Composition A3 is an example of a fragrance composition according to the present invention, made with any of the fragrance examples 1-4, respectively. In parallel, a control composition B3 is prepared by replacing the different substantially non-odorous fragrance fixative by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 13 in the proportions indicated.

TABLE 13 Fragrance Composition Fragrance Composition (wt %) ¹ Ingredients A3 B3 Bottom heavy fragrance oil²   2-15 2-15 Ethanol 60-99.99 Butylated Hydroxy Toluene 0-0.07 Modulator A ³ 0.1-20 — Deionized water to 100.00 ¹ Wt % is relative to the total weight of the composition. ²Can be any one of fragrance examples 1-4 ³ Can be any one of the substantially non-odorous fragrance modulator as disclosed in Table 4(a) and 4(b).

Compositions A4, C4, E4, and G4 are examples of fragrance compositions according to the present invention, made with any one of fragrance oil examples 1-4, respectively. In parallel, control compositions B4, D4, F4, and H4 are prepared by replacing the different substantially non-odorous fragrance modulators by the same amount of deionized water. All of the compositions are prepared by admixture of the components described in Table 14 in the proportions indicated.

TABLE 14 Fragrance Compositions Fragrance Composition (wt %)¹ Ingredients A4 B4 C4 C4 E4 F4 G4 H4 Bottom heavy 5-9 5-9 5-9 5-9 5-9 5-9 5-9 5-9 fragrance oil² Ethanol 75 Butylated Hydroxy 0-0.07 Toluene PPG-20 Methyl 13-17 0 — — — — — — Glucose Ether³ Caprytyl/Capryl — — 13-17 0 — — — — Glucoside⁴ Undecyl Glucoside⁵ 5 — — — — 13-17 0 — Isocetyl Aclohol⁶ — — — — — — 13-17 0 Deionized water to 100.00 ¹Wt % is relative to the total weight of the composition. ²Can be any one of fragrance examples 1-4. ³Available as GLUCAM ™ P-20. ³Available as Plantacare ® 810 UP. ³Available as Simulsol ® SL 11W. ⁶Available as Ceraphy ® ICA.

Example 3—Exemplary Product Compositions

Compositions I, II, III and IV are examples of body spray compositions according to the present invention. They are prepared by admixture of the components described in Table 15, in the proportions indicated.

TABLE 15 Body Spray Compositions Compositions (wt % 1) Ingredients CAS Number I II III IV Denatured Ethanol 64-17-5 38.00-40.00 58.00-60.00 38.00-40.00 38.00-40.00 Water 7732-18-5 — 0.50-0.80 — — Dipropylene Glycol 25265-71-8 13.00-17.00 — 13.00-17.00 13.00-17.00 Isopropyl Myristate 110-27-0 0.50-1.50 — 0.50-1.50 0.50-1.50 Zinc Phenosulphonate 127-82-2 0.25-0.75 — 0.25-0.75 0.25-0.75 Cayasol ® W7 methylated Beta- 128446-36-6 — 0.50-1.50 — — cyclodextrin Fragrance ² — 1.10-1.30 1.10-1.30 1.10-1.30  11.10-1.3020 Fragrance Modulator ³ — 2.40-2.80 2.40-2.80 2.40-2.80 2.40-2.80 Propane 74-98-6 4.70-4.90 — 4.70-4.90 4.70-4.90 Isobutane 72-28-5 26.00-28.00 — 26.00-28.00 26.00-28.00 1,1-Difluoroethane (HFC-152a) 75-37-6 7.00-9.00 33.00-37.00 7.00-9.00 7.00-9.00 Total 100.00 100.00 100.00 100.00 ¹ wt % relative to the total weight of the composition. ² Can be any one of Fragrances Examples 1-4. ³ Can be any one of the substantially non-odorous fragrance modulators disclosed in Tables 4(a) and 4(b).

Composition V, VI and VII are examples of body lotion compositions according to the present invention. They are prepared by admixture of the components as described in Table 16, in the proportions indicated.

TABLE 16 Body Lotion Composition Compositions (wt % ¹) Ingredients CAS Number V VI VII Water 7732-18-5 qsp 100% qsp 100% qsp 100% Trilon ® B 64-02-8 0.02-0.07 0.02-0.07 0.02-0.07 Carbopol ® ETD 9003-01-4 0.1-0.3 0.1-0.3 0.1-0.3 2050 Pemulen ™ TR1 9063-87-0 0.1-0.3 0.1-0.3 0.1-0.3 Nexbase ® 2008 68037-01-4 7-9 7-9 7-9 Silicone V100 63148-62-9 5-7 5-7 5-7 Fragrance — 2-4 2-4 2-4 Modulator ³ Tris Amino ™ 102-71-6 0.2-0.6 0.2-0.6 0.2-0.6 Ultra Pur Fragrance ² — 2-4 2-4 2-4 Preservatives — qs qs qs Total 100.00 100.00 100.00 ¹ wt % relative to the total weight of the composition. ² Can be any one of the Fragrances Examples 1-4. ³ Can be any one of the substantially non-odorous fragrance modulators disclosed in Tables 4(a) and 4(b).

Example 5: Results from Test Method 2a

Data obtained for fragrance constructions that include Glucam P-20 modulator as well corresponding fragrance constructions that are free of a modulator is presented in FIGS. 1-5.

As shown in FIG. 1, in Fragrance Composition A4 including Oil Example 1 (denoted by “Glucam”) the inclusion of Glucam P-20 reduces the harshness, the unpleasant solvent and earthy green notes associated with the overdose of powerful perfume materials as compared to Fragrance Composition B4 including Oil Example 1 (denoted by “NIL”).

As shown in FIG. 2, in Fragrance Composition A4 including Oil Example 1 (denoted by “Glucam”) the inclusion of Glucam P-20 increases the perception of base note characters of woody, smoky, leather and spicy notes as compared to Fragrance Composition B4 including Oil Example 1 (denoted by “NIL”).

As shown in FIGS. 3-5, in Fragrance Composition A4 including Oil Example 2 (denoted by “Glucam”) the inclusion of Glucam P-20 reduces the initial and 1 hour perceived harshness due to the overdose of powerful fragrance materials. Inclusion of Glucam P-20 also maintains the earth and green notes over time creating a more complex base note character as compared to corresponding Fragrance Composition B4 including Oil Example 2 (denoted by “Nil Modulator”) that is free of Glucam P-20 or any modulator. FIG. 3 shows harshness, FIG. 4 shows earthy character, and FIG. 5 shows green character.

As shown in FIGS. 6-7, the inclusion of Glucam P-20 in Fragrance Composition A4 including Oil Example 3 (denoted by “Glucam”) can help to present a strong initial perception of a complex blend of floral, aromatic, and green notes. This is shown in FIG. 6. FIG. 7 shows the character of the fragrance that is free of Glucam P-20 or any modulator which is initially dominated by mainly aromatic notes. Over time the floral and aromatic notes are maintained with the inclusion of Glucam P-20 but in the corresponding Fragrance Composition B4 including Oil Example 3 (denoted by “Nil Modulator”) that is free of Glucam P-20 or any modulator the floral and aromatic notes are not maintained to the same extent and the character is dominated by musk notes.

As shown in FIG. 8, the inclusion of Glucam P-20 in Fragrance Composition A4 including Oil Example 4 (denoted by “Glucam”) reduces the perceived harshness of the fragrance initially and for up to 3 hours, as compared to the corresponding Fragrance Composition B4 including Oil Example 2 (denoted by “Nil Modulator”) that is free of Glucam P-20 or any modulator. With the inclusion of Glucam P-20 the fragrance has a more pleasant warm scent whilst in the absence of the modulator is it a more unpleasant dry scent.

Example 6: Results from Test Method 2b

FIG. 9 shows that harshness in Example A3, is significantly decreased over time using modulators other than Glucam compared to Example B3 without modulators. BF1 includes Oil Example 1 and no modulator; BF3 includes Oil Example 1 and ICA (isocetyl alcohol) as the modulator. BF5 includes Oil Example 1 and Kolliphor EL (propyl[{4-[2-(diethyl amino)-2-oxoethoxy]-3-methoxyphenyl}acetate) as the modulator. BF3 is significantly lower at 90% confidence than BF1 at 5 mins (p-value=0.083), 2 hours (p-value=0.073) and 4 hours (p-value=0.067) and BF5 is significantly lower at 95% confidence than BF1 at 4 hours (p-value=0.004).

FIG. 10 shows that harshness is reduced significantly in Example A3 by Kolliphor EL and Schercemol NGDO modulators with some reduction in harshness using ICA compared to Example B3 with no modulators. BH1 includes Oil Example 3 with no modulator. BH3 includes Oil Example 3 and isocetyl alcohol as the modulator. BH4 includes Oil Example 3 and Kolliphor EL (propyl[{4-[2-(diethyl amino)-2-oxoethoxy]-3-methoxyphenyl}acetate) as the modulator. BH5 includes Oil Example 3 and Schercemol NGDO (Neopentyl Glycol Diethylhexanoate) as the modulator. BH4 is significantly lower at 95% confidence than BH1 at 6 hours (p-value=0.030) and BH5 is significantly lower at 95% confidence than BH1 at 6 hours (p-value=0.033).

Additional Embodiments

The following exemplary embodiments are provided, the numbering of which is not to be construed as designating levels of importance:

Embodiment 1 provides a composition comprising:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount greater than 30 wt %, relative to the total weight         of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 70 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount of from about 0.1 wt % to about 30 wt % relative to         the total weight of the fragrance component;

at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 2 provides the composition of Embodiment 1, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 3 provides the composition of any one of Embodiments 1 or 2, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt %/o to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 4 provides the composition of any one of Embodiments 1-3, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 5 provides the composition of any one of Embodiments 1-4, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 6 provides the composition of any one of Embodiments 1-5, wherein the low volatile fragrance material is chosen from chosen from any of the materials or combinations of materials listed in any one of Tables 1A and 1B.

Embodiment 7 provides the composition of any one of Embodiments 1-6, wherein the at least one substantially non-odorous fragrance modulator is chosen from methyl glucoside polol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof.

Embodiment 8 provides the composition of any one of Embodiments 1-7, wherein the at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, and mixtures thereof.

Embodiment 9 provides the composition of any one of Embodiments 1-8, wherein the composition is substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.

Embodiment 10. The composition of any one of Embodiments 1-9, wherein the at least one substantially non-odorous fragrance modulator is chosen from:

a compound of formula (I):

wherein:

-   -   R¹ is hydrogen, alkyl, alkenyl or alkynyl;     -   R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl,         (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)0]_(w)R⁹, wherein w is from 1 to 10,         preferably 2 to 9;     -   R³ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]yR⁹, wherein y is         from 1 to 10 or 2 to 9;     -   R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;     -   R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶0 R⁹,         —R⁶0 [R⁶R⁷(R⁸)0]zR⁹,     -   wherein z is from 1 to 10, preferably 2 to 9;     -   each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene,         (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and     -   each R⁸ and R⁹ is independently selected from hydrogen or alkyl,

a compound of formula (II):

wherein:

-   -   R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or         (C₂-C₂₀)alkynyl;     -   each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;     -   each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene,         or (C₂-C₂₀)alkynylene; and     -   R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)         alkynyl; wherein tis 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and         -   is a saturated or unsaturated carbon-carbon bond;

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   R^(1b) is hydrogen or methyl; and         R^(2b) is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)—(OR^(1c))  (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from         6 to 9, and m is     -   an integer from 1 to 4;     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)  (VII).

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is     -   an integer from 1 to 5;     -   z is an integer from 1 to 5; and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8,     -   and d is an integer from 1 to 3;     -   e is an integer from 2 to 4;     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4;     -   h is an integer from 2 to 5;     -   and R^(1f) is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)COOR^(3i)  (X).

wherein:

-   -   R^(1g) is selected from the group consisting of: (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)  (XII).

wherein:

-   -   Rh is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and

Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H  (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and         their mixtures; Tricyclodecane Amide derivatives selected from         the group consisting of:     -   the compounds of formula (XIV):

-   -   wherein:         -   X is selected from:

t is 1 to 8;

-   -   Y is hydrogen, or a halogen; and     -   each R^(1j) is independently selected from a hydrogen, or C₁-C₄         alkyl; the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈     -   alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that         both R^(2e) groups are not hydrogen; and         mixtures of the compounds of formulae (XII) and (XIII); and         mixtures thereof.

Embodiment 11 provides the composition according to any one of Embodiments 1-10, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.

Embodiment 12 provides a method of using the composition of any one of Embodiments 1-11, comprising contacting the fragrance component with at least one of skin, hair, and fabric.

Embodiment 13 provides the method of Embodiment 12, comprising contacting the fragrance with skin.

Embodiment 14 provides a method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a composition of any one of Embodiments 1-13.

Embodiment 15 provides the fragrance component of any one of Embodiments 1-14, wherein the fragrance material is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, juniper-type notes, fruity-type notes, peachy-type notes, lactonic-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, suede-type notes, sappy-type notes, earthy-type notes, rooty-type notes, birch-type notes, leather-type note, smoky-type note, animalic-type notes, balsamic-type notes, musk-type notes, and mixtures thereof.

Embodiment 16 provides a method for producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a fragrance composition according to any one of Embodiments 1-15.

Embodiment 17 provides a perfuming consumer product or article comprising a fragrance composition according to any one of Embodiments 1-16 wherein the perfuming consumer product is chosen from a fabric care product, an air care product, a home care product, a beauty care product or a mixture thereof.

Embodiment 18 provides a method of modifying or enhancing the odor properties of a body surface, comprising contacting or treating the body surface with a composition according to any one of Embodiments 1-17.

Embodiment 19 provides the composition of any one of Embodiments 1-18, further comprising:

a volatile solvent present in an amount of from about 50 wt % to about 80 wt %, relative to the total weight of the composition; and

optionally water.

Embodiment 20 provides a composition comprising: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount greater than 30 wt %, relative to the total weight         of the fragrance component, wherein the low volatile fragrance         material is chosen from any of the materials or combinations of         materials listed in any one of Tables 1A and 1B;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 70 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount of from about 0.1 wt % to about 30 wt % relative to         the total weight of the fragrance component;

at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 21 provides the composition of Embodiment 20, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 22 provides the composition of any one of Embodiments 20 or 21, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 23 provides the composition of any one of Embodiments 20-22, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 24 provides the composition of any one of Embodiments 20-23, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 25 provides the composition of any one of Embodiments 20-24, wherein the at least one substantially non-odorous fragrance modulator is chosen from methyl glucoside polol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof.

Embodiment 26 provides the composition of any one of Embodiments 20-25, wherein the at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, and mixtures thereof.

Embodiment 27 provides the composition of any one of Embodiments 20-26, wherein the composition is substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.

Embodiment 28 provides the composition of any one of Embodiments 20-27, wherein the at least one substantially non-odorous fragrance modulator is chosen from:

a compound of formula (I):

wherein:

-   -   R¹ is hydrogen, alkyl, alkenyl or alkynyl;     -   R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl,         (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)0]_(w)R⁹, wherein w is from 1 to 10,         preferably 2 to 9;     -   R³ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]yR⁹, wherein y is         from 1 to 10 or 2 to 9;     -   R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;     -   R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶0 R⁹,         —R⁶0 [R⁶R⁷(R⁸)0]zR⁹,     -   wherein z is from 1 to 10, preferably 2 to 9;     -   each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene,         (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and     -   each R⁸ and R⁹ is independently selected from hydrogen or alkyl,

a compound of formula (II):

wherein:

-   -   R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or         (C₂-C₂₀)alkynyl;     -   each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;     -   each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene,         or (C₂-C₂₀)alkynylene; and     -   R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)         alkynyl; wherein t is 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and         -   is a saturated or unsaturated carbon-carbon bond;

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   R^(1b) is hydrogen or methyl; and         R^(2b) is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)(OR^(1c))_(n)  (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein/is an integer from 6         to 9, and m is     -   an integer from 1 to 4;     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)  (VII)

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is an integer from 1 to 5;     -   z is an integer from 1 to 5; and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8,     -   and d is an integer from 1 to 3;     -   e is an integer from 2 to 4:     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4;     -   h is an integer from 2 to 5;     -   and R¹ is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)COOR^(3i)  (X).

wherein:

-   -   R^(1g) is selected from the group consisting of: (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5; Isoceteth-7, Isoceteth-10; Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)  (XII).

wherein:

-   -   R^(1i) is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and

Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H  (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and         their mixtures; Tricyclodecane Amide derivatives selected from         the group consisting of:     -   the compounds of formula (XIV):

-   -   wherein:         -   X is selected from:

t is 1 to 8;

-   -   Y is hydrogen, or a halogen; and     -   each R^(1j) is independently selected from a hydrogen, or C₁-C₄         alkyl; the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈ alkyl, cycloalkyl or cycloheteroalkyl, with the         proviso that both R^(2e) groups are not hydrogen; and         mixtures of the compounds of formulae (XII) and (XIII); and         mixtures thereof.

Embodiment 29 provides the composition according to any one of Embodiments 20-28, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.

Embodiment 30 provides a method of using the composition of any one of Embodiments 20-29, comprising contacting the fragrance component with at least one of skin, hair, and fabric.

Embodiment 31 provides a method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a composition of any one of Embodiments 20-30.

Embodiment 32 provides the fragrance component of any one of Embodiments 20-31, wherein the fragrance material is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.

Embodiment 33 provides a perfuming consumer product or article comprising a fragrance composition according to any one of Embodiments 20-32 wherein the perfuming consumer product is chosen from a fabric care product, an air care product, a home care product, a beauty care product or a mixture thereof. Embodiment 34 provides a method for producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a fragrance composition according to any one of Embodiments 20-33.

Embodiment 35 provides a composition comprising:

a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises:

-   -   at least one low volatile fragrance material having a vapor         pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present         in an amount greater than 30 wt %, relative to the total weight         of the fragrance component;     -   at least one moderate volatile fragrance material having a vapor         pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to         0.000133 kPa) at 25° C. present in an amount of from about 30 wt         % to about 70 wt %, relative to the total weight of the         fragrance component; and     -   at least one high volatile fragrance material having a vapor         pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in         an amount of from about 0.1 wt % to about 30 wt % relative to         the total weight of the fragrance component; and

at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, and polypropylene glycol-20 methyl glucose ether, present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.

Embodiment 36 provides the composition of Embodiment 35, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 37 provides the composition of any one of Embodiments 35 or 36, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 38 provides the composition of any one of Embodiments 35-37, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 39 provides the composition of any one of Embodiments 35-38, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 40 provides the composition of any one of Embodiments 35-39, wherein the low volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 1A and 1B.

Embodiment 41 provides the composition of any one of Embodiments 35-40, wherein the composition is substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.

Embodiment 42 provides the composition according to any one of Embodiments 35-41, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.

Embodiment 43 provides a method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a composition of any one of Embodiments 35-42.

Embodiment 44 provides the fragrance component of any one of Embodiments 35-43, wherein the fragrance material is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.

Embodiment 45 provides a method for producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a fragrance composition according to any one of Embodiments 35-44.

Embodiment 46 provides a perfuming consumer product or article comprising a fragrance composition according to any one of Embodiments 35-45, wherein the perfuming consumer product is chosen from a fabric care product, an air care product, a home care product, a beauty care product, or a mixture thereof.

Embodiment 47 provides a method of modifying or enhancing the odor properties of a body surface, comprising contacting or treating the body surface with a composition according to any one of Embodiments 35-46.

Embodiment 48 provides the composition of any one of Embodiments 35-47, further comprising:

a volatile solvent present in an amount of from about 50 wt % % to about 80 wt %, relative to the total weight of the composition; and

optionally water.

Embodiment 49 provides a composition comprising:

-   -   a fragrance component present in an amount of from about 0.04 wt         % to about 30 wt %, relative to the total weight of the         composition, and wherein the fragrance component comprises:         -   at least one low volatile fragrance material having a vapor             pressure less than 0.001 Torr (0.000133 kPa) at 25° C.             present in an amount greater than 30 wt %/o, relative to the             total weight of the fragrance component;         -   at least one moderate volatile fragrance material having a             vapor pressure in the range of 0.1 Torr to 0.001 Torr             (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount             of from about 30 wt % to about 70 wt %, relative to the             total weight of the fragrance component; and         -   at least one high volatile fragrance material having a vapor             pressure greater than 0.1 Torr (0.0133 kPa) at 25° C.             present in an amount of from about 0.1 wt % to about 30 wt %             relative to the total weight of the fragrance component; and     -   at least one substantially non-odorous fragrance modulator         present in the amount of from about 0.1 wt % to about 20 wt %,         relative to the total weight of the composition;     -   wherein at least one of the low volatile fragrance material, the         moderate volatile fragrance material, and the high volatile         fragrance material is present in the fragrance component for a         period of time that is longer than a corresponding fragrance         component that is free of the substantially non-odorous         fragrance modulator.

Embodiment 50 provides the composition of Embodiment 49, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.

Embodiment 51 provides the composition of any one of Embodiments 49 or 50, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 52 provides the composition of any one of Embodiments 49-51, wherein the at least one low volatile fragrance material is present in an amount of from about 31 wt % to about 60 wt % relative to the total weight of the fragrance material.

Embodiment 53 provides the composition of any one of Embodiments 49-52, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.

Embodiment 54 provides the composition of any one of Embodiments 49-53, wherein the low volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 1A and 1B.

Embodiment 55 provides the composition of any one of Embodiments 49-54, wherein the at least one substantially non-odorous fragrance modulator is chosen from methyl glucoside polol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof.

Embodiment 56 provides the composition of any one of Embodiments 49-55, wherein the at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, and mixtures thereof.

Embodiment 57 provides the composition of any one of Embodiments 49-56, wherein the composition is substantially

free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethylhexanoate, polypropylene glycol-3 myristyl ether, neopentyl glycol diethylhexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof.

Embodiment 58 provides the composition of any one of Embodiments 49-57, wherein the at least one substantially non-odorous fragrance modulator is chosen from:

a compound of formula (I):

wherein:

-   -   R¹ is hydrogen, alkyl, alkenyl or alkynyl;     -   R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl,         (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)0]_(w)R⁹, wherein w is from 1 to 10,         preferably 2 to 9;     -   R³ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]yR⁹, wherein y is from 1 to 10 or 2 to 9;     -   R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl,         —[R⁶R\R⁸)0]xR⁹, wherein x is from 1 to 10, preferably 2 to 9;     -   R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶0 R⁹,         —R⁶0 [R⁶R⁷(R⁸)0]zR⁹,     -   wherein z is from 1 to 10, preferably 2 to 9;     -   each R⁶ and R⁷ are independently selected from (C₂-C₂)alkylene,         (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and     -   each R⁸ and R⁹ is independently selected from hydrogen or alkyl,         a compound of formula (II):

wherein:

-   -   R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or         (C₂-C₂₀)alkynyl;     -   each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl;     -   each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl,         (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl;     -   each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene,         or (C₂-C₂₀)alkynylene; and     -   R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)         alkynyl; wherein tis 5 or less, preferably 1, 2 or 3;

Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures;

Trimethylcyclohexane derivatives having the formula (III):

wherein:

-   -   n is 0, 1 or 2;     -   A is C═O or CH—OH;     -   R^(1a) is hydrogen or methyl;     -   R^(2a) is a C₂-C₁₀ hydrocarbon group; and         -   is a saturated or unsaturated carbon-carbon bond;

L-menthoxy ether derivatives having the formula (IV):

wherein:

-   -   m is 0, 1 or 2;     -   B is hydrogen or OH;     -   and C is hydrogen or     -   methyl;

Tetra-hydronaphthalene derivatives having the formula (V):

wherein:

-   -   Rib is hydrogen or methyl; and         R^(2b) is alkyl;         140

Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures;

Ether derivatives having the formula (VI) or formula (VII):

C₅H_(l)O_(m)—(OR^(1c))_(n)  (VI).

wherein:

-   -   C₅H_(l)O_(m) is a pentose residue, wherein l is an integer from         6 to 9, and m is an integer from 1 to 4;     -   n is an integer from 1 to 4; and     -   R^(1c) is C₄-C₂₀ hydrocarbon group; and

C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)  (VII).

wherein:

-   -   C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7         to 11, and y is an integer from 1 to 5;     -   z is an integer from 1 to 5; and     -   R^(1d) is C₄-C₂₀ hydrocarbon group; and

Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein:

-   -   C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from         6 to 8, and d is an integer from 1 to 3;     -   e is an integer from 2 to 4:     -   and R^(1e) is C₁-C₆ alkyl     -   group; and

wherein:

-   -   C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7         to 10, and g is an integer from 1 to 4:     -   h is an integer from 2 to 5;     -   and R^(1f) is C₁-C₆ alkyl     -   group;     -   Hydroquinone Glycoside derivatives having the formula (X):

R^(1i)OCO^(R2i)COOR^(3i)  (X).

wherein:

-   -   R^(1g) is selected from the group consisting of; (i) pentose         residue, hexose residue, aminosaccharide residue, uronic acid         residue and their mixtures; (ii) methylated versions of group         (i); and (iii) mixtures of groups (i) and (ii); and Propylene         Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers;         Isoceteth-5: Isoceteth-7, Isoceteth-10: Isoceteth-12;         Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium         Lauroamphodipropionate; Hexaethylene glycol monododecyl ether;         and their mixtures;

Glyceryl Ether derivatives having the formula (XI):

wherein:

-   -   R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group;

Panthenol Ethyl Ether, DL-Panthenol and their mixtures;

Aliphatic Dibasic Acid Diester derivatives having the formula (XII):

R^(1i)OCO^(R2i)COOR^(3i)  (XII).

wherein:

-   -   R¹ is C₄-C₅ alkyl;     -   R^(2i) is C₄ alkylene;     -   and R^(3i) is C₄-C₅     -   alkyl; and

Aliphatic Ether derivatives having the formula (XIII):

R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H  (XIII).

wherein:

-   -   a and b are integers such that the sum of a and b is from 1 to         4;     -   and R^(4i) is an aliphatic chain comprising from 8 to 18         carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and         their mixtures; Tricyclodecane Amide derivatives selected from         the group consisting of:     -   the compounds of formula (XIV):

-   -   wherein:         -   X is selected from:

t is 1 to 8;

-   -   Y is hydrogen, or a halogen; and     -   each R^(1i) is independently selected from a hydrogen, or C₁-C₄         alkyl; the compounds of formula (XV):

wherein:

-   -   each R^(2j) is independently selected from a hydrogen, methyl,         ethyl or C₃-C₁₈     -   alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that         both R^(2e) groups are not hydrogen; and mixtures of the         compounds of formulae (XII) and (XIII); and mixtures thereof.

Embodiment 59 provides the composition according to any one of Embodiments 49-58, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.

Embodiment 60 provides a method of using the composition of any one of Embodiments 49-59, comprising contacting the fragrance component with at least one of skin, hair, and fabric.

Embodiment 61 provides a method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a composition of any one of Embodiments 49-60.

Embodiment 62 provides the fragrance component of any one of Embodiments 49-61, wherein the fragrance material is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.

Embodiment 63 provides a method for producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a fragrance composition according to any one of Embodiments 49-62.

Embodiment 64 provides a perfuming consumer product or article comprising a fragrance composition according to any one of Embodiments 49-63 wherein the perfuming consumer product is chosen from a fabric care product, an air care product, a home care product, a beauty care product, or a mixture thereof.

Embodiment 65 provides a method of modifying or enhancing the odor properties of a body surface, comprising contacting or treating the body surface with a composition according to any one of Embodiments 49-64.

Embodiment 66 provides the composition of any one of Embodiments 49-65, further comprising: a volatile solvent present in an amount of from about 50 wt % to about 80 wt %, relative to the total weight of the composition; and optionally water. 

1-25. (canceled)
 26. A composition comprising: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises: at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component; at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % to about 70 wt %, relative to the total weight of the fragrance component; and at least one high volatile fragrance material having a vapor pressure greater than 0.1 Tory (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component; at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.
 27. The composition of claim 26, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.
 28. The composition of claim 26, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.
 29. The composition of claim 26, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material.
 30. The composition of claim 26, wherein the at least one substantially non-odorous fragrance modulator is chosen from: a compound of formula (I):

wherein: R¹ is hydrogen, alkyl, alkenyl or alkynyl; R² is selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl, —[R⁶R⁷(R⁸)0]_(w)R⁹, wherein w is from 1 to 10, preferably 2 to 9; R³ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)0]yR⁹, wherein y is from 1 to 10 or 2 to 9; R⁴ is selected from hydrogen, alkyl, alkenyl, alkynyl, —[R⁶R\R⁸)0]xR⁹, wherein x is from 1 to 10, preferably 2 to 9; R⁵ is selected from hydrogen, alkyl, alkenyl, alkynyl, —R⁶0 R⁹, —R⁶0 [R⁶R⁷(R⁸)0]zR⁹, wherein z is from 1 to 10, preferably 2 to 9; each R⁶ and R⁷ are independently selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and each R⁸ and R⁹ is independently selected from hydrogen or alkyl, a compound of formula (II):

wherein: R¹⁰ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀)alkynyl; each R¹¹ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, (C₂-C₂₀)alkynyl; each R¹² is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl; each R¹³ is independently selected from hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl, or (C₂-C₂₀)alkynyl; each R¹⁴ is selected from (C₂-C₂₀)alkylene, (C₂-C₂₀)alkenylene, or (C₂-C₂₀)alkynylene; and R¹⁵ is hydrogen, (C₂-C₂₀)alkyl, (C₂-C₂₀)alkenyl or (C₂-C₂₀) alkynyl; wherein t is 5 or less, preferably 1, 2 or 3; Sucrose Laurate, Sucrose Dilaurate, Sucrose Myristate, Sucrose Palmitate, Sucrose Stearate, Sucrose Distearate, Sucrose Tristearate, and their mixtures; Trimethylcyclohexane derivatives having the formula (II):

wherein: n is 0, 1 or 2; A is C═O or CH—OH; R^(1a) is hydrogen or methyl; R^(2a) is a C₂-C₁₀ hydrocarbon group; and is a saturated or unsaturated carbon-carbon bond; L-menthoxy ether derivatives having the formula (IV):

wherein: m is 0, 1 or 2; B is hydrogen or OH; and C is hydrogen or methyl; Tetra-hydronaphthalene derivatives having the formula (V):

wherein: R^(1b) is hydrogen or methyl; and R^(2b) is alkyl; 140 Hyaluronic acid disaccharide sodium salt, sodium hyaluronate and their mixtures; Ether derivatives having the formula (VI) or formula (VII): C₅H_(l)O_(m)—(OR^(1c))_(n)  (VI). wherein: C₅H_(l)O_(m) is a pentose residue, wherein 1 is an integer from 6 to 9, and m is an integer from 1 to 4; n is an integer from 1 to 4; and R^(1c) is C₄-C₂₀ hydrocarbon group; and C₅H_(c)O_(d)—(OCH₂CH₂—O—CH₂CH₂—O—R^(1e))_(e)  (VII). wherein: C₆H_(x)O_(y) is a hexose residue, wherein x is an integer from 7 to 11, and y is an integer from 1 to 5; z is an integer from 1 to 5; and R^(1d) is C₄-C₂₀ hydrocarbon group; and Diethylene Glycol Ether derivatives having the formula (VIII) or formula (IX):

wherein: C₅H_(c)O_(d) is a pentose residue, wherein c is an integer from 6 to 8, and d is an integer from 1 to 3; e is an integer from 2 to 4; and R^(1e) is C₁-C₆ alkyl group; and

wherein: C₆H_(f)O_(g) is a hexose residue, wherein f is an integer from 7 to 10, and g is an integer from 1 to 4; h is an integer from 2 to 5; and R^(1f) is C₁-C₆ alkyl group; Hydroquinone Glycoside derivatives having the formula (X): R^(1i)OCO^(R2i)COOR^(3i)  (X). wherein: R^(1g) is selected from the group consisting of: (i) pentose residue, hexose residue, aminosaccharide residue, uronic acid residue and their mixtures; (ii) methylated versions of group (i); and (iii) mixtures of groups (i) and (ii); and Propylene Glycol Propyl Ether; Dicetyl Ether; Polyglycerin-4 Ethers; Isoceteth-5: Isoceteth-7, Isoceteth-10; Isoceteth-12; Isoceteth-15; Isoceteth-20; Isoceteth-25; Isoceteth-30; Disodium Lauroamphodipropionate; Hexaethylene glycol monododecyl ether; and their mixtures; Glyceryl Ether derivatives having the formula (XI):

wherein: R^(1h) is C₄-C₁₂ aliphatic hydrocarbon group; Panthenol Ethyl Ether, DL-Panthenol and their mixtures; Aliphatic Dibasic Acid Diester derivatives having the formula (XII): R^(1i)OCO^(R2i)COOR^(3i)  (XII). wherein: R^(1i) is C₄-C₅ alkyl; R^(2i) is C₄ alkylene; and R^(3i) is C₄-C₅ alkyl; and Aliphatic Ether derivatives having the formula (XIII): R^(4i)—O—(CH(CH₃)—CH₂O)_(a)—(CH₂—CH₂O)_(b)—H  (XIII). wherein: a and b are integers such that the sum of a and b is from 1 to 4; and R^(4i) is an aliphatic chain comprising from 8 to 18 carbons; N-hexadecyl n-nonanoate, Noctadecyl n-nonanoate and their mixtures; Tricyclodecane Amide derivatives selected from the group consisting of: the compounds of formula (XIV):

wherein: X is selected from:

t is 1 to 8; Y is hydrogen, or a halogen; and each R^(1j) is independently selected from a hydrogen, or C₁-C₄ alkyl; the compounds of formula (XV):

wherein: each R^(2j) is independently selected from a hydrogen, methyl, ethyl or C₃-C₁₈ alkyl, cycloalkyl or cycloheteroalkyl, with the proviso that both R^(2e) groups are not hydrogen; and mixtures of the compounds of formulae (XII) and (XIII); and mixtures thereof.
 31. The composition of claim 26, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.
 32. The composition of claim 26, wherein the fragrance component is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, juniper-type notes, fruity-type notes, peachy-type notes, lactonic-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, suede-type notes, sappy-type notes, earthy-type notes, rooty-type notes, birch-type notes, leather-type note, smoky-type note, animalic-type notes, balsamic-type notes, musk-type notes, and mixtures thereof.
 33. A method for producing a consumer product comprising bringing into contact or mixing into the product an organoleptically active quantity of a composition of claim
 26. 34. A composition comprising: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises: at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component, wherein the low volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 1A and 1B; at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt %/o to about 70 wt %, relative to the total weight of the fragrance component; and at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component; at least one substantially non-odorous fragrance modulator present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.
 35. The composition of claim 34, wherein the high volatile fragrance material is chosen from any of the materials or combinations of materials listed in any one of Tables 3A and 3B.
 36. The composition of claim 34, wherein the at least one substantially non-odorous fragrance modulator is chosen from methyl glucoside polol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof.
 37. The composition of claim 34, wherein the at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, and mixtures thereof.
 38. The composition of claim 34, in the form of a perfume, an eau de toilette, an eau de parfum, a cologne, a body splash, a lotion, a cream, a shampoo, a conditioner, a hair mist, a body oil, a deodorant, a solid fragrance, or a body spray.
 39. A method of using the composition of claim 34, comprising contacting the fragrance component with at least one of skin, hair, and fabric.
 40. A method to enhance the fragrance profile of a composition or improve the longevity of an aroma, comprising bringing into contact or mixing at least one non-odorous fragrance modulator with at least one low volatile fragrance material, high volatile fragrance material, and moderate volatile fragrance material according to a composition of claim
 34. 41. The fragrance component of claim 34, wherein the fragrance material is selected from a citrus-type note, green-type note, spicy-type note, cinnamon-type notes, pepper-type notes, cumin-type notes, ginger-type notes, floral-type notes, woody-type notes, cedarwoood-type notes, sandalwood type notes, vetyver-type notes, leather-type note, smoky-type note, musk-type notes, and mixtures thereof.
 42. A composition comprising: a fragrance component present in an amount of from about 0.04 wt % to about 30 wt %, relative to the total weight of the composition, and wherein the fragrance component comprises: at least one low volatile fragrance material having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25° C. present in an amount greater than 30 wt %, relative to the total weight of the fragrance component; at least one moderate volatile fragrance material having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25° C. present in an amount of from about 30 wt % % to about 70 wt %, relative to the total weight of the fragrance component; and at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25° C. present in an amount of from about 0.1 wt % to about 30 wt % relative to the total weight of the fragrance component; and at least one substantially non-odorous fragrance modulator is chosen from polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, and polypropylene glycol-20 methyl glucose ether, present in the amount of from about 0.1 wt % to about 20 wt %, relative to the total weight of the composition.
 43. The composition of claim 42, wherein the at least one low volatile fragrance material is present in an amount of from 31 wt % to about 60 wt % relative to the total weight of the fragrance material.
 44. The composition of claim 42, wherein the at least one moderate volatile fragrance material is present in an amount of from about 35 wt % to about 60 wt % relative to the total weight of the fragrance material.
 45. The composition of claim 42, wherein the at least one high volatile fragrance material is present in an amount of from about 1 wt % to about 30 wt % relative to the total weight of the fragrance material. 